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1,2,4-트라이클로로벤젠

1,2,4-트라이클로로벤젠 구조식 이미지

카스 번호:: 120-82-1

한글명:: 1,2,4-트라이클로로벤젠

동의어(한글):: 1,2,4-트라이클로로벤젠;1,2,4-트라이클로로벤젠(1,2,4-트리클로로벤젠);1,2,4-트리클로로벤젠;1,2,4-트라이클로로벤졸;1,2,5-트라이클로로벤젠;1,3,4-트라이클로로벤젠;unsym-트라이클로로벤젠;벤젠, 1,2,4-트라이클로로-;클로리네이티드 벤젠

상품명:: 1,2,4-Trichlorobenzene

동의어(영문):: 1,2,4-Trichlorbenzol;TRICHLOROBENZENE124-,,;1,2,4-TRICHLOROBENZENE SINGLE COMPONENT STANDARD FOR EPA;ai3-07775;1.2.4-Tric;Hipochem GM;1,2,4TrichL;hostetexl-pec;Hostetex l-pec;Trojchlorobenzen

CBNumber:: CB8852926

분자식:: C6H3Cl3

포뮬러 무게:: 181.45

MOL 파일:: 120-82-1.mol

MSDS 파일:: SDS

속성

안전

MSDS

용도

공급 업체 365

1,2,4-트라이클로로벤젠 속성

녹는점: 16 °C(lit.)

끓는 점: 214 °C(lit.)

밀도: 1.454 g/mL at 25 °C(lit.)

증기 밀도: >6 (vs air)

증기압: 1 mm Hg ( 40 °C)

굴절률: n20/D 1.571(lit.)

인화점: >230 °F

저장 조건: 2-8°C

용해도: 물: 불용성

물리적 상태: 액체

색상: 투명한

냄새: 독특한 향기로운 냄새

폭발한계: 6.6%, 150°F

수용성: 불용성

최대 파장(λmax): λ: 308 nm Amax: 1.00
λ: 310 nm Amax: 0.50
λ: 350 nm Amax: 0.05
λ: 375-400 nm Amax: 0.01

Merck: 14,9631

BRN: 956819

Henry's Law Constant: 0.997 at 20.0 °C (wetted-wall column, ten Hulscher et al., 1992) 1.24, 2.27, 2.58, 3.06, and 3.90 at 2.0, 6.0, 10.0, 18.0, and 25.0 °C, respectively (EPICS-SPME, Dewulf et al., 1999)

노출 한도: NIOSH REL: TWA ceiling 5 ppm (40 mg/m³); ACGIH TLV: ceiling 5 ppm (adopted).

Dielectric constant: 2.2400000000000002

안정성: 안정적인. 강한 산화제와 호환되지 않습니다. 타기 쉬운.

LogP: 4.28

CAS 데이터베이스: 120-82-1(CAS DataBase Reference)

NIST: Benzene, 1,2,4-trichloro-(120-82-1)

EPA: 1,2,4-Trichlorobenzene (120-82-1)

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험품 표기	Xn,N,Xi,T,F
위험 카페고리 넘버	22-38-50/53-52/53-39/23/24/25-23/24/25-11-51/53
안전지침서	23-37/39-60-61-45-36/37-16-7
유엔번호(UN No.)	UN 2321 6.1/PG 3
WGK 독일	3
RTECS 번호	DC2100000
자연 발화 온도	571 °C
위험 참고 사항	Irritant
TSCA	Yes
위험 등급	6.1
포장분류	III
HS 번호	29036990
유해 물질 데이터	120-82-1(Hazardous Substances Data)
독성	LD50 orally in Rabbit: 550 mg/kg LD50 dermal Rat 6139 mg/kg
기존화학 물질	KE-34063

그림문자(GHS):

신호 어:

Warning

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	P- 코드
H302	삼키면 유해함	급성 독성 물질 - 경구	구분 4	경고	P264, P270, P301+P312, P330, P501
H315	피부에 자극을 일으킴	피부부식성 또는 자극성물질	구분 2	경고	P264, P280, P302+P352, P321,P332+P313, P362
H410	장기적 영향에 의해 수생생물에 매우 유독함	수생 환경유해성 물질 - 만성	구분 1	경고	P273, P391, P501

예방조치문구:

P264	취급 후에는 손을 철저히 씻으시오.
P264	취급 후에는 손을 철저히 씻으시오.
P270	이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P273	환경으로 배출하지 마시오.
P280	보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312	삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P302+P352	피부에 묻으면 다량의 물로 씻으시오.

NFPA 704

	1
2		0

1,2,4-트라이클로로벤젠 MSDS

1,2,4-Trichlorobenzene

1,2,4-트라이클로로벤젠 C화학적 특성, 용도, 생산

개요

Trichlorobenzenes (TCBs) are synthetic chemicals that occur in three different isomeric forms. The three chlorinated cyclic aromatic isomers are 1,2,3-trichlorobenzene (1,2,3-TCB), 1,2,4-trichlorobenzene (1,2,4-TCB), and 1,3,5-trichlorobenzene (1,3,5-TCB). 1,2,4-TCB is one of the 188 chemicals designated as a hazardous air pollutant under the Clean Air Act.

화학적 성질

1,2,4-Trichlorobenzene is a low-melting solid or liquid with a pleasant, aromatic odor. The Odor Threshold is 1.4 ppm.

물리적 성질

Colorless liquid with an odor similar to o-dichlorobenzene. Odor threshold concentration is 1.4 (quoted, Amoore and Hautala, 1983). Miscible with most organic solvents and oils; insoluble in water. Combustible.

정의

ChEBI: 1,2,4-trichlorobenzene is a trichlorobenzene with chloro substituents at positions 1, 2 and 4. It is a solvent in various organic chemical reactions.

주요 응용

Trichlorobenzenes are primarily used as solvents in chemical manufacturing industries. 1,2,4-Trichlorobenzene is economically the most important isomer. It is used as a solvent in chemical reactions to dissolve oils, waxes, and resins. Furthermore, it is also used as a dye carrier. 1,2,4-Trichlorobenzene is a highly chlorinated aromatic solvent. It may be used as a solvent to prepare:
dimethylketene β-lactone dimer from tetramethyl-1,3-cyclobutanedione
salicyl-o-toluide by the reaction of phenyl salicylate and o-toluidine

일반 설명

Colorless liquid or white solid with a sharp chlorobenzene odor. Melting point 16.95°C (62.5°F) .

반응 프로필

1,2,4-Trichlorobenzene can react vigorously with oxidizing materials . Yields hydrogen chloride and phosgene when heated to decomposition [USCG, 1999].

건강위험

Exposures to high concentrations via inhalation are potentially hazardous to the lungs, kidneys and liver. Prolonged or repeated exposures or short exposure to high concentrations via inhalation are potentially hazardous to the lungs, kidneys and liver. Prolonged or repeated exposure to the eyes is likely to result in moderate pain and transient irritation. Prolonged or repeated contact with the skin may result in moderate irritation and possible systemic effects. Ingestion: May cause kidney and liver damage.

Safety Profile

Poison by ingestion. Moderately toxic by intraperitoneal route. An experimental teratogen. Experimental reproductive effects. Mutation data reported. A slan irritant. Combustible when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS, AROMATIC.

잠재적 노출

1,2,4-Trichlorobenzene is used as a dye carrier, herbicide intermediate; a heat transfer medium; a dielectric fluid in transformers; a degreaser; a lubricant; as an industrial chemical; solvent, emulsifier, and as a potential insecticide against termites. The other trichlorobenzene isomers are not used in any quantity.

운송 방법

UN2321 Trichlorobenzenes, liquid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Separate it from a mixture of isomers by washing with fuming H2SO4, then water, drying with CaSO4 and slowly fractionally distilling. [Jensen et al. J Am Chem Soc 81 3303 1959, Beilstein 5 IV 664.]

비 호환성

Reacts violently with oxidants, acids, acid fumes; steam.

폐기물 처리

Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced.

1,2,4-트라이클로로벤젠 준비 용품 및 원자재

원자재

석회석 1,2,3-트라이클로로벤젠 수산화나트륨 헤로인 1,3,5-트리클로로벤젠 수산화칼슘

준비 용품

1,2,4-Trichloro-5-nitrobenzene Trichloroacetyl isocyanate (Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐 디메틸 인산염 4-클로로페닐 2,4,5-트라이클로로페닐 설폰 2,4,5-트리클로로아닐린 헥사클로로벤젠 안트라퀴논 Naphthionic acid N-propyl-N-[2-(2，4，6-trichloro phenoxy ethyl)carbamyl chloride] 구리 프탈로시아닌 2,5-Dichlorobenzoic acid 1,2,3-트라이클로로벤젠 1,2-NAPHTHALIC ANHYDRIDE 1,3,5-트리클로로벤젠 구리 폴리클로로프탈로시아닌 녹색 1-BROMO-2,4-DICHLOROBENZENE 2,2',3,4,4',5,5'-헵타클로로-1,1'-바이페닐 2,4,5-트리클로로요오드벤젠

1,2,4-트라이클로로벤젠 공급 업체

글로벌( 365)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	6000	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	18229	58
Shanghai Xin Cheng Yue Chemical Co.,Ltd	+86-021-57806787 +86-17701820076	wuziwei@xinyuefirm.com	China	31	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21689	55
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +86-18949832763	info@tnjchem.com	China	2989	55
NINGBO INNO PHARMCHEM CO., LTD.	13867897135	sales@nbinno.com	CHINA	925	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Hebei Guanlang Biotechnology Co., Ltd.	+86-19930503282	alice@crovellbio.com	China	8822	58
Xiamen AmoyChem Co., Ltd	+86-592-6051114 +8618959220845	sales@amoychem.com	China	6387	58
Xi'an Kono chem co., Ltd.,	029-86107037 13289246953	info@konochemical.com	China	2995	58

1,2,4-트라이클로로벤젠 관련 검색:

o-클로로벤즈알데히드 2,2',4,4',6,6'-헥사나이트로다이페닐아민 말레인산클로로페니라민 1,3,5-트리클로로벤젠 1,2-디클로로벤젠 1,2,3-트라이클로로벤젠 m-디클로로벨젠 헥사클로로벤젠 펜타클로로페놀 2,4,6-트리클로로페놀 벤조트리클로라이드 프로클로라즈 1,2,4,5-사염화벤젠 2,4,5-트리클로로페놀 1,2,4-트라이클로로벤젠 2,4,6-Trichlorobenzoic acid 2,2',4'-Trichloroacetophenone 2,4,5,6-TETRACHLORO-M-XYLENE