Bis(triphenylphosphine)palladium(II) Dichloride
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Bis(triphenylphosphine)palladium(II) Dichloride 속성
- 녹는점
- 260°C
- 증기압
- 0Pa at 25℃
- RTECS 번호
- RT3578000
- 저장 조건
- Store below +30°C.
- 용해도
- 클로로포름(약간 용해됨), 디클로로메탄(약간 용해됨, 가열), 메탄올(약간 용해됨)
- 물리적 상태
- 가루
- 색상
- 노란색
- 수용성
- 물에 불용성. 벤젠, 톨루엔에 용해됩니다.
- 감도
- Hygroscopic
- BRN
- 4935975
- InChI
- InChI=1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
- InChIKey
- ILBDOZRDKNIJBS-UHFFFAOYSA-N
- SMILES
- P(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Pd](Cl)Cl
- LogP
- 5.69 at 20℃
- CAS 데이터베이스
- 13965-03-2(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xn | ||
---|---|---|---|
위험 카페고리 넘버 | 36/37/38-22-40-19 | ||
안전지침서 | 37/39-26-36/37 | ||
WGK 독일 | 3 | ||
F 고인화성물질 | 3-10-21 | ||
TSCA | No | ||
HS 번호 | 28439090 |
Bis(triphenylphosphine)palladium(II) Dichloride C화학적 특성, 용도, 생산
화학적 성질
Bis(triphenylphosphine)palladium chloride is a coordination compound of palladium containing two triphenylphosphine and two chloride ligands. This yellow solid is insoluble in water but can dissolve in some organic solvents, such as toluene and benzene, and is slightly soluble in acetone and chloroform. It is used for palladium-catalyzed coupling reactions, e.g. the Sonogashira–Hagihara reaction. The complex adopts a square planar geometry and numerous similar complexes are known, with different phosphine ligands.용도
Bis(triphenylphosphine)palladium(II) chloride is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of me tallacyclic complexes which show antiinflammatory and antifungal properties.Synthesis
The synthesis of Bis(triphenylphosphine)palladium(II) chloride can be achieved by the reaction of palladium(II) chloride with triphenylphosphine, resulting in the formation of Bis(triphenylphosphine)palladium(II) chloride. This chemical process is represented by the balanced equation: PdCl2 + 2 PPh3 → PdCl2(PPh3)2.일반 설명
Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction. Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium.Bis(triphenylphosphine)palladium(II) Dichloride 준비 용품 및 원자재
원자재
아세토나이트릴
에틸알코올
톨루엔
하이드라진, 모노수화물
팔라듐 염화물
초산에틸
트리페닐포스핀
4-METHOXYPHENYL ISOCYANIDE
테트라 키스 (트리 페닐 포스 핀) 팔라듐 (0)
팔라듐
1-Butyl nitrite
준비 용품
Bis(triphenylphosphine)palladium(II) Dichloride 공급 업체
글로벌( 637)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Shaoxin Catsyn Co., Ltd. | +undefined-0575-82040869 +86-0575-82040869; |
sales@catsyn.com | China | 6116 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 |
peter@yan-xi.com | China | 6011 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 18225 | 58 |
Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 |
info@spring-chem.com | China | 2068 | 57 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
forrest.lee@dakenchem.com | China | 15956 | 58 |
Beijing Cooperate Pharmaceutical Co.,Ltd | 010-60279497 |
sales01@cooperate-pharm.com | CHINA | 1811 | 55 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21689 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9341 | 55 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 |
product@chemlin.com.cn | CHINA | 3012 | 60 |
Bis(triphenylphosphine)palladium(II) Dichloride 관련 검색:
팔라듐 염화물 염화칼슘 염화 코발트 염화콜린 염화 암모늄 팔라듐 염화 폴리비닐 염화나트륨 트리페닐포스핀 염화칼륨 테트라 키스 (트리 페닐 포스 핀) 팔라듐 (0) (트리페닐포스포라닐리덴)아세트알데히드 디클로로 [비스 (2- (디 페닐 포스 피노) 페닐) 에테르] 팔라듐 (II) 디클로로 [(R) - (+) - 2,2'- 비스 (디 페닐 포스 피노) -1,1'- 바이 나프 틸] 팔라듐 (II)
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