Identification | More | [Name]
Cinnamoyl chloride | [CAS]
102-92-1 | [Synonyms]
2-PROPENOYL CHLORIDE, 3-PHENYL- 3-PHENYL-2-PROPENOYL CHLORIDE 3-PHENYLACRYLYL CHLORIDE 3-PHENYLPROPENOYL CHLORIDE AKOS BBS-00003908 CINNAMIC ACID CHLORIDE CINNAMOYL CHLORIDE TRANS-3-PHENYLACRYLOYL CHLORIDE TRANS-3-PHENYLACRYLOYL PROPENOYL CHLORIDE TRANS-CINNAMOYL CHLORIDE (2E)-3-Phenyl-2-propenoyl chloride 3-phenyl-2-propenoylchlorid 3-phenyl-acryloylchloride beta-Phenylacryloyl chloride Cinnamic chloride Phenylacrylchloride Phenylacrylyl chloride CINNAMOYL CHLORIDE PREDOMINANTLY TRANS Cinnamoyl chloride, 98%, predominantly trans CINNAMOYL CHLOCIDE | [EINECS(EC#)]
203-065-5 | [Molecular Formula]
C9H7ClO | [MDL Number]
MFCD00000732 | [Molecular Weight]
166.6 | [MOL File]
102-92-1.mol |
Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S25:Avoid contact with eyes . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29163990 |
Hazard Information | Back Directory | [Hazard]
Skin irritant. | [Chemical Properties]
white to yellowish crystalline solid | [Uses]
Titrimetric determination of small amounts of water. | [Synthesis Reference(s)]
Organic Syntheses, Coll. Vol. 3, p. 714, 1955 Tetrahedron Letters, 14, p. 5121, 1973 DOI: 10.1016/S0040-4039(01)87403-7 | [Purification Methods]
Refractionate it in a vacuum until the distillate solidifies on cooling, and recrystallise it from pet ether. The trans-amide has m 145-150o (from H2O) [Beilstein 9 III 2711]. [Adams & Ulich J Am Chem Soc 42 605 1920, Bergmann et al. J Chem Soc 2524 1952, Beilstein 9 H 587, 9 I 233, 9 II 390, 9 III 2710, 9 IV 2020.] |
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