ChemicalBook--->CAS DataBase List--->102308-32-7

102308-32-7

102308-32-7 Structure

102308-32-7 Structure
IdentificationMore
[Name]

(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
[CAS]

102308-32-7
[Synonyms]

1,1-DIMETHYLETHYL-(S)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINE CARBOXYLATE
GARNER'S ALDEHYDE
(S)-(-)-3-BOC-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
(S)-3-BOC-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
(S)-4-FORMYL-2,2-DIMETHYL-OXAZOLIDINE-3-CARBOXYLIC ACID TERT-BUTYL ESTER
(S)-N-BOC-2,2-DIMETHYLOXAZOLINDINE-4-CARBOXALDEHYDE
TERT-BUTYL (S)-(-)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE
TERT-BUTYL (S)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE
(S)-(-)-3-tert-Butoxycarbonyl-4-formyl-2,2-dimethyl
(S)-4-Formyl-2,2-dimethyl-oxazolidine-3-carboxylictert-butylester
(-)-n-boc-n,o-isopropylidene-l-serinal
(s)-(-)-3-boc-2,2-dimethyloxazolidine-4-carboxaldehyde
(s)-(-)-3-tert-butoxycarbonyl-4-formyl-2,2-
1,1-dimethylethyl-(S)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate, 95 %
(S)-tert-butyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate
Garners aldehyde, (-)-N-Boc-N,O-isopropylidene-L-serinal, tert-Butyl (S)-(-)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate
(4S)-2,2-Dimethyl-3-(tert-butoxycarbonyl)oxazolidine-4-carbaldehyde
(4S)-2,2-Dimethyl-4α-formyl-3-oxazolidinecarboxylic acid tert-butyl ester
(4S)-3-(tert-Butoxycarbonyl)-2,2-dimethyl-1,3-oxazolidine-4-carbaldehyde
[Molecular Formula]

C11H19NO4
[MDL Number]

MFCD00209557
[Molecular Weight]

229.27
[MOL File]

102308-32-7.mol
Chemical PropertiesBack Directory
[Appearance]

Clear colorless to yellow oil
[alpha ]

D -91.7° (c = 1.34 in CHCl3)
[Boiling point ]

83-88 °C1 mm Hg(lit.)
[density ]

1.06 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.445(lit.)
[Fp ]

226 °F
[storage temp. ]

Inert atmosphere,2-8°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Oil
[pka]

-3.26±0.60(Predicted)
[color ]

Clear colorless to yellow
[optical activity]

[α]20/D 90°, c = 1 in chloroform
[Water Solubility ]

Slightly soluble in water.
[Sensitive ]

Air Sensitive
[BRN ]

3591324
[CAS DataBase Reference]

102308-32-7(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[HS Code ]

29349990
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless to yellow oil
[Uses]

Widely utilized in the asymmetric synthesis of natural products.
[Uses]

Chiral, non-racemic synthon for asymmetric synthesis of amino sugars and other nitrogen-containing targets.
Spectrum DetailBack Directory
[Spectrum Detail]

(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE(102308-32-7)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

tert-Butyl (S)-(-)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate, 95%(102308-32-7)
[Sigma Aldrich]

102308-32-7(sigmaaldrich)
[TCI AMERICA]

(S)-(-)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyl-1,3-oxazolidine,>95.0%(GC)(102308-32-7)
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