(2S)-Bornane-10,2-sultam
|
|
- CAS-Nr.
- 108448-77-7
- Englisch Name:
- (2S)-Bornane-10,2-sultam
- Synonyma:
- (7aS)-8,8-Dimethylhexahydro-1H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide;2-sultaM;L-SultaM;(2S)-Bornane-10;L-2,10-amphorsultam;D-(-)-CAMPHOR SULTAM;(+)-10,2-CAMPHORSULTAM;(+)-2,10-CAMPHORSULTAM;(1R)-(+)-Camphorsultam;(2S)-Borne-10,2-sultam
- CBNumber:
- CB2411257
- Summenformel:
- C10H17NO2S
- Molgewicht:
- 215.31
- MOL-Datei:
- 108448-77-7.mol
|
(2S)-Bornane-10,2-sultam Eigenschaften
- Schmelzpunkt:
- 185-187 °C(lit.)
- alpha
- 33 º (c=4.9, CHCl3)
- Siedepunkt:
- 324.8±25.0 °C(Predicted)
- Dichte
- 1.1469 (rough estimate)
- Brechungsindex
- 31 ° (C=1, CHCl3)
- storage temp.
- Sealed in dry,Room Temperature
- Löslichkeit
- almost transparency in Chloroform
- Aggregatzustand
- powder to crystal
- pka
- 11.05±0.40(Predicted)
- Farbe
- White to Almost white
- Optische Aktivität
- [α]20/D +32°, c = 5 in chloroform
- BRN
- 4675755
- InChIKey
- DPJYJNYYDJOJNO-CFGJQEBVSA-N
- CAS Datenbank
- 108448-77-7(CAS DataBase Reference)
(2S)-Bornane-10,2-sultam Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
Chemische Eigenschaften
white to light yellow crystal powde
Verwenden
(1R)-(+)-2,10-Camphorsultam has been used as a reactant in the synthesis of pyrrolidine acid analogs as potent dual PPARα/γ agonists.
läuterung methode
The (-)-enantiomer is recrystallised from 95% EtOH and dried in a vacuum desiccator. It dissolves in dilute aqueous NaOH and can be precipitated without hydrolysis by acidifying. It forms the N-Na salt in EtOH (by addition of Na to the EtOH solution), and the salt can be methylated with MeI to give the (-)-N-Me lactam with m 80o after recrystallisation from hot H2O and has []D -59.6o (c 5, CHCl3) [Shriner et al. J Am Chem Soc 60 2794 1938]. [Oppolzer et al. Helv Chim Acta 69 1142 1986, Weismiller et al. Org Synth 69 154 1955, Beilstein 27 III/IV 1007.]
(2S)-Bornane-10,2-sultam Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(2S)-Bornane-10,2-sultam Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 273)Lieferanten
108448-77-7()Verwandte Suche:
- L-2,10-Camphorsultam,99%e.e.
- (2S)-BORNANE-10,2-SULTAM
- (1R)-(+)-2,10-CAMPHORSULTAM
- (1R)-2,10-CAMPHORSULTAM
- (1R,2S)-(+)-2,10-CAMPHORSULTAM
- (1R,5S)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.01,5]DECANE 3,3-DIOXIDE
- (+)-2,10-CAMPHORSULTAM
- (+)-10,2-CAMPHORSULTAM
- (IR)-(+)-2,10-Camphorsultam
- (1R)-(+)-2,10-camphorsultam ,98%
- L-2,10-amphorsultam
- (2S)-Bornane-10
- 2-sultaM
- (2S)-Bornane-1,2-sultaM
- L-SultaM
- (2S)-Bornane-10,2-sultam
(1R,5S)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.0(1,5)]decane 3,3-Dioxide
- (1R)-(+)-2,10-Camphorsultam
- (5S,7S)-10,10-dimethyl-3λ-thia-4-azatricyclo[5.2.1.01,]decane-3,3-dione
- (2S)-Bornane-10,2-sultam
(1R)-(+)-2,10-Camphorsultam
- [3AR-(3A-ALPHA,6-ALPHA,7A-BETA)]-HEXAHYDRO-8,8-DIMETHYL-2,2-DIOXIDE-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE
- [3aR-(3aalpha,6alpha,7abeta)]-Hexahydro-8,8-dimethyl-2,2-dioxide-3H-3a,6-methano-2,1-benzisothiazole
- (+)-EXO-10,2-BORNANESULTAM
- (+)-L-2,10-CAMPHORSULTAM
- L(+)-10,2-CAMPHORSULTAME
- D-(-)-CAMPHOR SULTAM
- (+)-2,10-CAMPHORSULTAM 99%
- (2S)-Bornane-10,2-sultam,99+%, (99+% ee)
- (2S)-Bornane-10,2-sultam,98%
- (+)-exo-10,2-Bornanesultam, (1R,5S)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide
- (+)-10,2-Camphorsultam, (+)-exo-10,2-Bornanesultam, L-2,10-Camphorsultam, (1R,5S)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide
- (1β,5α,7β)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane3,3-dioxide
- (3aR)-1,4,5,6,7,7aβ-Hexahydro-8,8-dimethyl-3H-3aα,6α-methano-2,1-benzisothiazole 2,2-dioxide
- (3aR,3aα,6α,7aβ)-8,8-Dimethyl-3a,6-methanooctahydro-2,1-benzisothiazole 2,2-dioxide
- [3aR,7aβ,(+)]-Hexahydro-8,8-dimethyl-3H-3aα,6α-methano-2,1-benzisothiazole 2,2-dioxide
- (1R)-(+)-Camphorsultam
- (1R,2S)-(+)-10,2-Camphorsultam
- (2S)-Borne-10,2-sultam
- (1R,2S)-(+)-10,2-CamphorsuL
- 3H-3a,6-Methano-2,1-benzisothiazole, hexahydro-8,8-dimethyl-, 2,2-dioxide, (3aR,6S,7aS)-
- (3aR)-8,8-dimethylhexahydro-2H-3a,6-methanobenzo[d]isothiazole 1,1-dioxide
- (2S)-Bornane-10,2-sultam ISO 9001:2015 REACH
- (3aR,6S,7aS)-8,8-Dimethylhexahydro-1H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide
- (7aS)-8,8-Dimethylhexahydro-1H-3a,6-methanobenzo[c]isothiazole 2,2-dioxide
- (+)-10,2-Camphorsultam
- (5S,7S)-10,10-dimethyl-3λ?-thia-4-azatricyclo[5.2.1.01?]decane 3,3-dioxide
- (+)-2,10-Camphorsultam
- 108448-77-7
- C10H17NO2S
- Sulfur-Based
- Sulfur Compounds (for Synthesis)
- Bicyclic Monoterpenes
- Terpenes
- Asymmetric Synthesis
- Chiral Auxiliaries
- chiral
- Asymmetric Synthesis
- Bicyclic Monoterpenes
- Biochemistry