Zirconiumchlorid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R14:Reagiert heftig mit Wasser.
R22:Gesundheitsschädlich beim Verschlucken.
R34:Verursacht Verätzungen.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S8:Behälter trocken halten.
Chemische Eigenschaften
White, lustrous crystals. Sublimes
above 300C. Soluble in alcohol; decomposes in
water.
Chemische Eigenschaften
Zirconium tetrachloride forms lustrous, white, monoclinic
crystals that melt at 437 ℃. It is a corrosive powder. It is
hygroscopic, and thus soluble in cold water, alcohol, ether,
and concentrated hydrochloric acid. It reacts vigorously with
water forming hydrogen chloride (irritating vapor) and zirconium
oxychloride. When moist, zirconium tetrachloride
reacts with common materials to form hydrochloric acid that
is corrosive to many metals. Through hydrolysis to HCl,
zirconium tetrachloride can irritate the respiratory tract and
other superficial surfaces of the body on exposure.
Zirconium tetrachloride readily forms coordinate bonds with
oxygen and nitrogen in organic molecules.
Physikalische Eigenschaften
White monoclinic crystals; hygroscopic; density 2.80 g/cm
3; sublimes at 331°C; triple point 437°C; vapor pressure 1 torr at 190°C; critical temperature 504.85°C; critical pressure 56.95 atm; critical volume 319 cm3/mol; decomposed by water; soluble in alcohol, ether, and concentrated hydrochloric acid.
Verwenden
Zirconium tetrachloride is commonly utilized as a Lewis acid catalyst in many organic synthesis reactions. It is an important source for organometallic complexes of zirconium. It is practiced in many areas like nuclear industry, metal industry, photography, glass, and ceramic industry.
synthetische
Zirconium tetrachloride is obtained as an intermediate in recovering zirconium metal from zircon and other minerals (See Zirconium, Recovery). The tetrachloride is obtained by heating a mixture of zirconium hydroxide and car 1004 bon with chlorine gas
Also, tetrachloride can be made by reacting zirconium hydroxide with hydrochloric acid: Zr(OH)
4 + 4HCl → ZrCl
4 + 4H
2O.
Definition
ChEBI: Zirconium tetrachloride is a zirconium coordination entity comprising four chlorine atoms bound to a central zirconium atom. It has a role as a catalyst. It is a zirconium coordination entity and an inorganic chloride.
Allgemeine Beschreibung
White lustrous crystalline solid. Used as a source of pure zirconium, as a tanning agent, in analytical chemistry and in treating textiles. Zirconium tetrachloride is decomposed by water. Corrosive to metals in the presence of moisture and to tissue.
Air & Water Reaktionen
Reacts vigorously with water forming hydrochloric acid with the evolution of heat.
Reaktivität anzeigen
Zirconium tetrachloride is corrosive to metals in the presence of moisture and to tissue. Behavior in Fire: Will not burn - sublimes above 626°F (331°C). May give off HCl fumes [USCG, 1999]. Zirconium tetrachloride is incompatible with alcohols (ethanol), lithium metal, and tetrahydrofuran.
Health Hazard
INHALATION: Irritating to upper respiratory tract; presumably caused by liberated HCl. EYES: Irritating. SKIN: Irritating. INGESTION: Burning pain in the mouth and throat, vomiting, watery or bloody diarrhea, retching, collapse, and convulsions.
Brandgefahr
Behavior in Fire: Will not burn - sublimes above 626°F (331°C). May give off HCl fumes.
Sicherheitsprofil
Moderately toxic by
ingestion. A corrosive irritant to skin, eyes,
and mucous membranes. Ignites
spontaneously in air. When heated to
decomposition it emits toxic fumes of Cl-.
See also ZIRCONIUM COMPOUNDS and
HYDROCHLORIC ACID.
läuterung methode
Crystallise it repeatedly from conc HCl. It is hydrolysed by H2O to form white ZrOCl2 (see below) and HCl. [Krebs Z Anorg Allgem Chem 378 263 1970.]
Zirconiumchlorid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
