N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE

N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE Struktur
60394-88-9
CAS-Nr.
60394-88-9
Englisch Name:
N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE
Synonyma:
Arnottianamide;N-[6-(2-hydroxy-3,4-dimethoxyphenyl)benzo[f][1,3]benzodioxol-5-yl]-N-methylformamide;N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE;Formamide, N-[6-(2-hydroxy-3,4-dimethoxyphenyl)naphtho[2,3-d]-1,3-dioxol-5-yl]-N-methyl-;N-[6-(2-HYDROXY-3,4-DIMETHOXY-PHENYL)-NAPHTHO[2,3-'D][1,3]DIOXOL-5-YL]-N-METHYL-FORMAMIDE
CBNumber:
CB9237645
Summenformel:
C21H19NO6
Molgewicht:
381.38
MOL-Datei:
60394-88-9.mol

N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE Eigenschaften

Schmelzpunkt:
264-267 °C
Siedepunkt:
573.8±50.0 °C(Predicted)
Dichte
1.353±0.06 g/cm3(Predicted)
pka
8.50±0.40(Predicted)

Sicherheit

N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

Arnottianamide occurs in Xanthoxylum arnottianum and, in trace amounts, in X. cuspidatum. It crystallizes as colourless prisms from EtOH and gives an ultraviolet spectrum in ethanol with absorption maxima at 236 and 332 nm and shoulders at 280 and 324 nm. The structure has been elucidated from chemical and spectro-scopic data and confirmed by its preparation from chelerythrine chloride by a Baeyer-Villiger type oxidation of the irnmonium group. Treatment with LiA1H4 gives the deoxo derivative as colourless prisms, m.p. 200-2°C, forming a crystalline methyl derivative, m.p. l66.5-168.5°C.

Einzelnachweise

Ishii et al., Tetrahedron Lett., 1203 (1976)

N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 13)Lieferanten
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60394-88-9()Verwandte Suche:


  • Arnottianamide
  • N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE
  • N-[6-(2-HYDROXY-3,4-DIMETHOXY-PHENYL)-NAPHTHO[2,3-'D][1,3]DIOXOL-5-YL]-N-METHYL-FORMAMIDE
  • N-[6-(2-hydroxy-3,4-dimethoxyphenyl)benzo[f][1,3]benzodioxol-5-yl]-N-methylformamide
  • Formamide, N-[6-(2-hydroxy-3,4-dimethoxyphenyl)naphtho[2,3-d]-1,3-dioxol-5-yl]-N-methyl-
  • 60394-88-9
  • C21H19NO6
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