N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE

N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE 구조식 이미지
카스 번호:
60394-88-9
상품명:
N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE
동의어(영문):
Arnottianamide;N-[6-(2-hydroxy-3,4-dimethoxyphenyl)benzo[f][1,3]benzodioxol-5-yl]-N-methylformamide;N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE;Formamide, N-[6-(2-hydroxy-3,4-dimethoxyphenyl)naphtho[2,3-d]-1,3-dioxol-5-yl]-N-methyl-;N-[6-(2-HYDROXY-3,4-DIMETHOXY-PHENYL)-NAPHTHO[2,3-'D][1,3]DIOXOL-5-YL]-N-METHYL-FORMAMIDE
CBNumber:
CB9237645
분자식:
C21H19NO6
포뮬러 무게:
381.38
MOL 파일:
60394-88-9.mol

N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE 속성

녹는점
264-267 °C
끓는 점
573.8±50.0 °C(Predicted)
밀도
1.353±0.06 g/cm3(Predicted)
산도 계수 (pKa)
8.50±0.40(Predicted)

안전

N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE C화학적 특성, 용도, 생산

개요

Arnottianamide occurs in Xanthoxylum arnottianum and, in trace amounts, in X. cuspidatum. It crystallizes as colourless prisms from EtOH and gives an ultraviolet spectrum in ethanol with absorption maxima at 236 and 332 nm and shoulders at 280 and 324 nm. The structure has been elucidated from chemical and spectro-scopic data and confirmed by its preparation from chelerythrine chloride by a Baeyer-Villiger type oxidation of the irnmonium group. Treatment with LiA1H4 gives the deoxo derivative as colourless prisms, m.p. 200-2°C, forming a crystalline methyl derivative, m.p. l66.5-168.5°C.

참고 문헌

Ishii et al., Tetrahedron Lett., 1203 (1976)

N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE 준비 용품 및 원자재

원자재

준비 용품


N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE 공급 업체

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N-[6-(2-HYDROXY-3,4-DIMETHOXY PHENYL)NAPHTHO[2,3-D][1,3]DIOXOL-5-YL]-N-METHYLFORMAMIDE 관련 검색:

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