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Bromstyrol

CAS No.
103-64-0
Chemical Name:
Bromstyrol
Synonyms
[(E)-2-Bromoethenyl]benzene;β-Bromostyrene;1-BROMO-2-PHENYLETHYLENE;(Z)-β-bromostyrene;BROMSTYROL;BROMOSTYROL;Bromstyrole;B-BROMSTYROL;hyacinthbase;styrylbromide
CBNumber:
CB00124309
Molecular Formula:
C8H7Br
Molecular Weight:
183.05
MDL Number:
MFCD00000185
MOL File:
103-64-0.mol
MSDS File:
SDS
Last updated:2024-07-02 17:33:06

Bromstyrol Properties

Melting point 7 °C(lit.)
Boiling point 219-221 °C(lit.)
Density 1.427 g/mL at 25 °C(lit.)
vapor pressure 16.4Pa at 25℃
refractive index n20/D 1.608
Flash point 215 °F
storage temp. 2-8°C
solubility Soluble in alcohol.
form Liquid
color very deep green-yellow
Odor at 1.00 % in dipropylene glycol. strong leafy green hyacinth
Odor Type green
Water Solubility 56.624mg/L at 25℃
BRN 2038495
LogP 3.391 at 25℃
CAS DataBase Reference 103-64-0(CAS DataBase Reference)
EWG's Food Scores 1-3
FDA UNII 46J0U1IRC9
NIST Chemistry Reference Benzene, (2-bromoethenyl)-(103-64-0)
EPA Substance Registry System .beta.-Bromostyrene (103-64-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H227
Precautionary statements  P264-P270-P301+P312+P330-P501-P210e-P280a-P301+P312a-P403+P235-P501a
Hazard Codes  Xn
Risk Statements  22
Safety Statements  23-24/25-36/37
WGK Germany  3
RTECS  WL3850000
TSCA  Yes
HS Code  29039990
Toxicity An acute oral LD50 in rats was reported as 1.25 ml/kg(0.82-189 ml/kg). The acute dermal LD50 was reported as > 6 ml/kg in the rabbit
NFPA 704
2
2 0

Bromstyrol price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 157449 β-Bromostyrene 97% 103-64-0 5g $68.9 2024-03-01 Buy
TCI Chemical B0655 beta-Bromostyrene (cis- and trans- mixture) >95.0%(GC) 103-64-0 25g $75 2024-03-01 Buy
TRC B415360 2-Bromovinylbenzene 103-64-0 5g $75 2021-12-16 Buy
TRC B415360 2-Bromovinylbenzene 103-64-0 500mg $45 2021-12-16 Buy
SynQuest Laboratories 1900-9-23 beta-Bromostyrene 98% 103-64-0 25g $29 2021-12-16 Buy
Product number Packaging Price Buy
157449 5g $68.9 Buy
B0655 25g $75 Buy
B415360 5g $75 Buy
B415360 500mg $45 Buy
1900-9-23 25g $29 Buy

Bromstyrol Chemical Properties,Uses,Production

Chemical Properties

CLEAR YELLOWISH TO BROWN LIQUID

Occurrence

Apparently has not been reported to occur in nature.

Uses

Perfumery.

Uses

Beta-Bromostyrene, cis + trans is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.

Uses

β-Bromostyrene was used in the one-pot method for the preparation of cinnamonitriles. It was also used in the preparation of pure ethyl Z- and E-α,α-difluoro-4-phenyl-3-butenoate and 1,3-diphenyl-1-butene. It may be used in the synthesis of β-tert-butylstyrene via cross coupling reaction with tert-butylmagnesium chloride in the presence of dichloro[1,1′-bis(diphenylphosphino)ferrocene]nickel(II) catalyst. It may also be used to prepare γ-but-2-enolactone by reacting with nickel carbonyl in the presence of alkynes.

Preparation

By the action of aqueous alkali on cinnamic acid dibromide.

General Description

β-Bromostyrene is an α,β-unsaturated aromatic halide. It can be synthesized by catalytic Hunsdiecker reaction (CHR) of cinnamic acid. It is commonly utilized as a precursor for preparing substituted alkenes, corresponding acetylenes and also in the total synthesis of natural compounds and antibiotics.

Flammability and Explosibility

Not classified

Bromstyrol Preparation Products And Raw materials

Global( 229)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Kingfiner Technology Development Co.Ltd
+86-15532196582 +86-15373005021 lisa@kingfinertech.com China 2989 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20318 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21673 55
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29897 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293 sales@sdzschem.com China 2931 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34571 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23556 58

View Lastest Price from Bromstyrol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Sodium tetraborate pentahydrate pictures 2023-08-21 Sodium tetraborate pentahydrate
12179-04-3
1kg 99% 100tons Anhui Ruihan Technology Co., Ltd
(2-bromoethenyl)-benzen 1-Bromo-2-phenylethene Styryl bromide styrylbromide 2-(BROMOVINYL)BENZENE OMEGA-BROMOSTYRENE B-BROMOSTYRENE B-BROMSTYROL BETA-BROMOSTYRENE BETA-BROMOSTYROL BROMOSTYROL BROMSTYROL beta-bromostyrene (cis+trans) beta-Bromostyrene, mixture of cis- and trans isomers Bromostyrenecistrans BETA-BROMOSTYRENE, MIXTURE OF ISOMERS, 97% BETA-BROMOSTYRENE MIXTURE OF CIS AND TR& BETA-BROMOSTYROL, CIS+TRANS B-Bromostyrol á-bromostyrene, cis + trans Beta-bromostyrene, 97%, mixture of cis/trans isomers 2-Phenylvinyl bromide (E)-1-Bromo-2-phenylethene (E)-Styryl bromide [(E)-2-Bromovinyl]benzene [(E)-2-Phenylvinyl] bromide [(E)-Styryl] bromide ^b-Bromostyrene, cis + trans, 98% SS-BROMOSTYRENE, CIS + TRANS beta-Bromostyrene (cis- and trans- mixture) ^b-BroMostyrene, cis + trans, 96%, stab. with 0.1% 4-tert-butylcatechol beta-BroMostyrene, Mixture of cis/trans isoMers, 97% 5ML beta-BroMostyrene  β-BroMostyrene, Mixture of cis and trans beta-Bromostyrene 1-Bromo-2-phenylethylene beta-BroMostyrene, cis + trans,stab. with 0.1% 4-tert-butylcatechol Beta-Bromostyrol (Styrene) -Bromostyrene (cis- and trans- mixture) β-Bromostyrene (cis- and trans- mixture) beta-Bromostyrene, cis + trans, stabilized with 0.1% 4-tert-butylcatechol 2-Bromostyrol alpha-Bromo-beta-phenylethylene Benzene,(2-bromoethenyl)- beta-bromo-styren beta-bromostyrene,mixtureofcis/transisomers beta-Bromstyrol Bromostyrolene -Bromovinylbenzene Bromstyrole Hyacinth base hyacinthbase omega-Bromosytrene Styrene, beta-bromo- β-Bromostyrene (cis- and trans- mixture) β-Bromostyrene, 98%, mixture of cis and trans 2-Phenylethenyl bromide β-Bromostyrene (cis- and trans- mixture)> beta-Bromostyrene ISO 9001:2015 REACH