Bromstyrol
- CAS No.
- 103-64-0
- Chemical Name:
- Bromstyrol
- Synonyms
- [(E)-2-Bromoethenyl]benzene;β-Bromostyrene;1-BROMO-2-PHENYLETHYLENE;(Z)-β-bromostyrene;BROMSTYROL;BROMOSTYROL;Bromstyrole;B-BROMSTYROL;hyacinthbase;styrylbromide
- CBNumber:
- CB00124309
- Molecular Formula:
- C8H7Br
- Molecular Weight:
- 183.05
- MDL Number:
- MFCD00000185
- MOL File:
- 103-64-0.mol
- MSDS File:
- SDS
Melting point | 7 °C(lit.) |
---|---|
Boiling point | 219-221 °C(lit.) |
Density | 1.427 g/mL at 25 °C(lit.) |
vapor pressure | 16.4Pa at 25℃ |
refractive index |
n |
Flash point | 215 °F |
storage temp. | 2-8°C |
solubility | Soluble in alcohol. |
form | Liquid |
color | very deep green-yellow |
Odor | at 1.00 % in dipropylene glycol. strong leafy green hyacinth |
Odor Type | green |
Water Solubility | 56.624mg/L at 25℃ |
BRN | 2038495 |
LogP | 3.391 at 25℃ |
CAS DataBase Reference | 103-64-0(CAS DataBase Reference) |
EWG's Food Scores | 1-3 |
FDA UNII | 46J0U1IRC9 |
NIST Chemistry Reference | Benzene, (2-bromoethenyl)-(103-64-0) |
EPA Substance Registry System | .beta.-Bromostyrene (103-64-0) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H302-H227 | |||||||||
Precautionary statements | P264-P270-P301+P312+P330-P501-P210e-P280a-P301+P312a-P403+P235-P501a | |||||||||
Hazard Codes | Xn | |||||||||
Risk Statements | 22 | |||||||||
Safety Statements | 23-24/25-36/37 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | WL3850000 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29039990 | |||||||||
Toxicity | An acute oral LD50 in rats was reported as 1.25 ml/kg(0.82-189 ml/kg). The acute dermal LD50 was reported as > 6 ml/kg in the rabbit | |||||||||
NFPA 704 |
|
Bromstyrol price More Price(24)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 157449 | β-Bromostyrene 97% | 103-64-0 | 5g | $68.9 | 2024-03-01 | Buy |
TCI Chemical | B0655 | beta-Bromostyrene (cis- and trans- mixture) >95.0%(GC) | 103-64-0 | 25g | $75 | 2024-03-01 | Buy |
TRC | B415360 | 2-Bromovinylbenzene | 103-64-0 | 5g | $75 | 2021-12-16 | Buy |
TRC | B415360 | 2-Bromovinylbenzene | 103-64-0 | 500mg | $45 | 2021-12-16 | Buy |
SynQuest Laboratories | 1900-9-23 | beta-Bromostyrene 98% | 103-64-0 | 25g | $29 | 2021-12-16 | Buy |
Bromstyrol Chemical Properties,Uses,Production
Chemical Properties
CLEAR YELLOWISH TO BROWN LIQUID
Occurrence
Apparently has not been reported to occur in nature.
Uses
Perfumery.
Uses
Beta-Bromostyrene, cis + trans is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.
Uses
β-Bromostyrene was used in the one-pot method for the preparation of cinnamonitriles. It was also used in the preparation of pure ethyl Z- and E-α,α-difluoro-4-phenyl-3-butenoate and 1,3-diphenyl-1-butene. It may be used in the synthesis of β-tert-butylstyrene via cross coupling reaction with tert-butylmagnesium chloride in the presence of dichloro[1,1′-bis(diphenylphosphino)ferrocene]nickel(II) catalyst. It may also be used to prepare γ-but-2-enolactone by reacting with nickel carbonyl in the presence of alkynes.
Preparation
By the action of aqueous alkali on cinnamic acid dibromide.
General Description
β-Bromostyrene is an α,β-unsaturated aromatic halide. It can be synthesized by catalytic Hunsdiecker reaction (CHR) of cinnamic acid. It is commonly utilized as a precursor for preparing substituted alkenes, corresponding acetylenes and also in the total synthesis of natural compounds and antibiotics.
Flammability and Explosibility
Not classified
Bromstyrol Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Kingfiner Technology Development Co.Ltd | +86-15532196582 +86-15373005021 | lisa@kingfinertech.com | China | 2989 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20318 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21673 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29897 | 58 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34571 | 58 |
ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23556 | 58 |
View Lastest Price from Bromstyrol manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2023-08-21 | Sodium tetraborate pentahydrate
12179-04-3
|
1kg | 99% | 100tons | Anhui Ruihan Technology Co., Ltd |
- Sodium tetraborate pentahydrate
12179-04-3
- 99%
- Anhui Ruihan Technology Co., Ltd
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