N-Norsinoactine

CAS No.
13186-21-5
Chemical Name:
N-Norsinoactine
Synonyms
Norsinoacutine;N-Norsinoactine;(9α,13α)-5,6,8,14-Tetradehydro-4-hydroxy-3,6-dimethoxymorphinan-7-one;Morphinan-7-one, 5,6,8,14-tetradehydro-4-hydroxy-3,6-dimethoxy-, (9α,13α)-
CBNumber:
CB02370028
Molecular Formula:
C18H19NO4
Molecular Weight:
313.35
MDL Number:
MOL File:
13186-21-5.mol

N-Norsinoactine Properties

Melting point 113-5°C (solvate)

N-Norsinoactine Chemical Properties,Uses,Production

Description

Isolated from Croton balsamifera Jacq. and C. j1avens, this alkaloid crystallizes from AcOEt with 1 mole of solvent which is difficult to remove. It has [α] 16 D-107° (EtOH) and the ultraviolet spectrum in has absorption maxima at 241 (shoulder) and 275 mfJ.. The base gives a deep blue colour with FeCL3 . The structure has been determined from chemical degradation and the NMR and mass spectra.

References

Chambers, Haynes, Stuart., Chem. Commun., 449 (1966)
Stuart, Chambers., Tetrahedron Lett., 2879 (1967)

N-Norsinoactine Preparation Products And Raw materials

Raw materials

Preparation Products

N-Norsinoactine Norsinoacutine (9α,13α)-5,6,8,14-Tetradehydro-4-hydroxy-3,6-dimethoxymorphinan-7-one Morphinan-7-one, 5,6,8,14-tetradehydro-4-hydroxy-3,6-dimethoxy-, (9α,13α)- 13186-21-5