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Ethyl carbazate

Ethyl carbazate structure

CAS No.: 4114-31-2

Chemical Name:: Ethyl carbazate

Synonyms: ETHYL HYDRAZINECARBOXYLATE;HYDRAZINOCARBOXYLIC ACID ETHYL ESTER;AKOS 90785;ETHYL CARBAZATE;ethylecarbazate;ethylcarbazinate;Ethyl carbazinate;Ethyl Carbazatecas;Carbethoxyhydrazine;Ethyl carbazate 97%

CBNumber:: CB0697565

Molecular Formula:: C3H8N2O2

Molecular Weight:: 104.11

MDL Number:: MFCD00007595

MOL File:: 4114-31-2.mol

MSDS File:: SDS

Last updated:2024-08-21 22:41:43

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Ethyl carbazate Properties

Melting point	44-47 °C (lit.)
Boiling point	108-110 °C/22 mmHg (lit.)
Density	1.2719 (rough estimate)
refractive index	1.4715 (estimate)
Flash point	187 °F
storage temp.	Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
form	Powder
pka	10.72±0.20(Predicted)
color	White to cream
Water Solubility	Very soluble in water.
Sensitive	Moisture Sensitive
BRN	878265
InChIKey	VYSYZMNJHYOXGN-UHFFFAOYSA-N
CAS DataBase Reference	4114-31-2(CAS DataBase Reference)
NIST Chemistry Reference	Hydrazinecarboxylic acid, ethyl ester(4114-31-2)
EPA Substance Registry System	Hydrazinecarboxylic acid, ethyl ester (4114-31-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Codes

Xi,T

Risk Statements

36/37/38-25

Safety Statements

26-36-45

RIDADR

2811

WGK Germany

RTECS

FE2545000

TSCA

Yes

HazardClass

6.1

PackingGroup

III

HS Code

29280090

NFPA 704

	2
3		1

Ethyl carbazate price More Price(20)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	E16503	Ethyl carbazate 97%	4114-31-2	25g	$76.1	2024-03-01	Buy
TCI Chemical	C1097	Ethyl Carbazate >99.0%(T)	4114-31-2	25g	$79	2024-03-01	Buy
TCI Chemical	C1097	Ethyl Carbazate >99.0%(T)	4114-31-2	500g	$944	2024-03-01	Buy
Alfa Aesar	A13860	Ethyl carbazate, 97%	4114-31-2	50g	$48.65	2024-03-01	Buy
Alfa Aesar	A13860	Ethyl carbazate, 97%	4114-31-2	250g	$195	2024-03-01	Buy

Product number	Packaging	Price	Buy
E16503	25g	$76.1	Buy
C1097	25g	$79	Buy
C1097	500g	$944	Buy
A13860	50g	$48.65	Buy
A13860	250g	$195	Buy

Ethyl carbazate Chemical Properties,Uses,Production

Chemical Properties

Off-white crystals.

Uses

Prepare 4-phenylurazole from ethyl carbazate and then oxidize the urazole with gaseous dinitrogen tetroxide to yield 4-phenyl-1,2,4-tri- azoline-3,5-dione la. Modification of the ethyl carbazate procedure in which analytically pure monoalkylhydrazine hydrochlorides were isolated in greater than 90% yield, starting from a ketone or aldehyde. Treatment of primary amines is with chloroamine or hydroxylamine-0-sulfonic acid and the condensation of a carbonyl compound with ethyl carbazate. The FeCl 3 -catalyzed reaction of ethyl carbazate (2 b) proceeded readily to give β-hydroxyester 3 b in better yield. A new one-pot neat synthesis of some 5-aryl-2,4-dihydro-3H-1,2,4-triazol-3-ones through cyclocondensation of ethyl carbazate with aryl nitriles catalyzed by DMAP as an efficient and basic nucleophilic catalyst is described.

Uses

Synthetic intermediate.

Hazard

Irritant.

Purification Methods

Fractionate the carbazate using a Vigreux column (p 11) until the distillate crystallises [Allen & Bell Org Synth Coll Vol III 404 1955, Beilstein 3 IV 174].

Ethyl carbazate Preparation Products And Raw materials

Raw materials

Methyl carbazate HYDRAZINE Diethyl carbonate

Preparation Products

4-[4-(BROMOMETHYL)PHENYL]-1,2,3-THIADIAZOLE 4-METHYL-1,2,3-THIADIAZOLE-5-CARBOXAMIDE 1,2,3-THIADIAZOLE-4-CARBOXYLIC ACID 4-(1,2,3-THIADIAZOL-4-YL)PHENOL Cadralazine

4-(1,2,3-THIADIAZOL-4-YL)BENZOIC ACID 4-(4-METHOXYPHENYL)-1,2,3-THIADIAZOLE 4-(1,2,3-THIADIAZOL-4-YL)ANILINE 4-(4-NITROPHENYL)-1,2,3-THIADIAZOLE 4-(1,2,3-THIADIAZOL-4-YL)BENZALDEHYDE

4-PHENYL-1,2,3-THIADIAZOL-5-AMINE 4-(4-METHYLPHENYL)-1,2,3-THIADIAZOLE Thidiazuron 1,2,3-Thiadiazole-4-carbonyl chloride (6CI,7CI,8CI,9CI) 4-(4-CHLOROPHENYL)-1,2,3-THIADIAZOLE

4-(1,2,3-THIADIAZOL-4-YL)BENZOYL CHLORIDE ETHYL 1,2,3-THIADIAZOLE-4-CARBOXYLATE 4-(1,2,3-THIADIAZOL-4-YL)BENZONITRILE 4-[4-(TRIFLUOROMETHYL)PHENYL]-1,2,3-THIADIAZOL-5-AMINE 4-(4-METHOXYPHENYL)-1,2,3-THIADIAZOL-5-AMINE

4-(1,2,3-THIADIAZOL-4-YL)BENZYLAMINE HYDROCHLORIDE ETHYL 4-METHYL-1,2,3-THIADIAZOLE-5-CARBOXYLATE 4-ISOPROPYL-1,2,3-THIADIAZOLE-5-CARBOXYLIC ACID 4-(4-CHLOROPHENYL)-1,2,3-THIADIAZOL-5-AMINE 4-METHYL-1,2,3-THIADIAZOLE-5-CARBONYL CHLORIDE

ETHYL 4-ISOPROPYL-1,2,3-THIADIAZOLE-5-CARBOXYLATE 4-(4-BROMOPHENYL)-1,2,3-THIADIAZOLE 5-CYANO-4-METHYL-1,2,3-THIADIAZOLE (1,2,3-THIADIAZOL-4-YL)METHANOL 4-Methyl-1,2,3-thiadiazole-5-carboxylic acid

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Ethyl carbazate Suppliers

Global( 305)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5893	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
Tianjin Zhongxin Chemtech Co., Ltd.	+86-022-66880623 +8618622897568	sales@tjzxchem.com	China	563	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28172	58
Hebei Weibang Biotechnology Co., Ltd	+8615531157085	abby@weibangbio.com	China	8812	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49374	58
career henan chemical co	+86-0371-86658258 +8613203830695	factory@coreychem.com	China	29811	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10032	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co,.LTD	58
Henan Tianfu Chemical Co.,Ltd.	55
Tianjin Zhongxin Chemtech Co., Ltd.	58
Hubei Jusheng Technology Co.,Ltd.	58
Hebei Weibang Biotechnology Co., Ltd	58
Chongqing Chemdad Co., Ltd	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
Fuxin Pharmaceutical	58

View Lastest Price from Ethyl carbazate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-11-22	Ethyl carbazate 4114-31-2	US $0.00 / KG	1KG	98%min	30tons/month	WUHAN FORTUNA CHEMICAL CO., LTD
2024-10-11	Ethyl Carbazatecas 4114-31-2	US $5.70 / KG	10KG	99%	10000kg	Hebei Chuanghai Biotechnology Co,.LTD
2021-08-12	Ethyl carbazate 4114-31-2	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd

Ethyl carbazate
4114-31-2
US $0.00 / KG
98%min
WUHAN FORTUNA CHEMICAL CO., LTD

Ethyl Carbazatecas
4114-31-2
US $5.70 / KG
99%
Hebei Chuanghai Biotechnology Co,.LTD

Ethyl carbazate
4114-31-2
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

Ethyl carbazate Spectrum

Ethyl carbazate(4114-31-2)MS Ethyl carbazate(4114-31-2)¹HNMR Ethyl carbazate(4114-31-2)¹³CNMR Ethyl carbazate(4114-31-2)IR1 Ethyl carbazate(4114-31-2)IR2 Ethyl carbazate(4114-31-2)Raman

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(Ethoxycarbonyl)hydrazide (Monocarbethoxy)hydrazine 1-(Carbethoxy)hydrazine 1-(Ethoxycarbonyl)hydrazine AKOS 90785 Ethoxycarbonylhydrazine~Ethyl hydrazinocarboxylate ETHOXY CARBONYLHYDRAZINE ETHOXY FORMHYDRAZINE ETHYL CARBAZATE ETHYL HYDRAZINE-1-CARBOXYLATE HYDRAZINOFORMIC ACID ETHYL ESTER CARBAZIC ACID ETHYL ESTER CARBOETHOXY HYDRAZINE Ethyl N-aminocarbamate Ethyl carbazate ,97% Carbazinic acid ethyl Hydrazinecarboxylic acid ethyl N-Aminocarbamic acid ethyl ester ETHOXY FORMYL HYDRAZINE Ethoxycarbonylhydrazine Carbazic Acid Ethyl Ester 1-carbethoxyhydrazine Carbethoxyhydrazine ethoxycarbonylhydrazide Ethyl carbazinate ethylcarbazinate ethylhydrazinocarboxylate hydrazinecarboxylicacid,ethylester monocarbethoxyhydrazine N-(Carbethoxy)hydrazine N-(Ethoxycarbonyl)hydrazine Ethyl carbazate 97% Hydrazine ethyl forMate ethylecarbazate Ethyl Carbazate > Ethyl Carbazatecas 4114-31-2 Hydrazinecarboxylicacid, ethyl ester ETHYL HYDRAZINECARBOXYLATE HYDRAZINOCARBOXYLIC ACID ETHYL ESTER Ethyl hydrazine formate 4114-31-2 H2NNHCO2C2H5 ACETATE Building Blocks Carbonyl Compounds Nitrogen Compounds Protected Amines Organic Building Blocks Hydrazides Pharmaceutical Intermediates Miscellaneous Building Blocks Chemical Synthesis Nitrogen Compounds Organic Building Blocks Protected Amines bc0001