Dibutyl sulfide
- CAS No.
- 544-40-1
- Chemical Name:
- Dibutyl sulfide
- Synonyms
- FEMA 2215;(n-C4H9)2S;'LGC' (4000);5-Thianonane;Thianonane-5;Thiononane-5;BUTYL SULFIDE;Dibutylsulfid;BUTYL SULPHIDE;dibutylsulfane
- CBNumber:
- CB0738088
- Molecular Formula:
- C8H18S
- Molecular Weight:
- 146.29
- MDL Number:
- MFCD00009468
- MOL File:
- 544-40-1.mol
- MSDS File:
- SDS
| Melting point | -76 °C (lit.) |
|---|---|
| Boiling point | 188-189 °C (lit.) |
| Density | 0.838 g/mL at 25 °C (lit.) |
| vapor density | 5.07 (vs air) |
| vapor pressure | 5.17 mm Hg ( 37.7 °C) |
| refractive index |
n |
| FEMA | 2215 | BUTYL SULFIDE |
| Flash point | 170 °F |
| storage temp. | Store below +30°C. |
| form | Liquid |
| color | Clear colorless to very slightly yellow |
| Odor | at 0.10 % in dipropylene glycol. green grassy violet-leaf herbal rose geranium |
| Odor Type | alliaceous |
| Odor Threshold | 0.00051ppm |
| Water Solubility | Silghtly miscible with water. Miscible with olive oil and almond oil. |
| Merck | 14,1590 |
| JECFA Number | 455 |
| BRN | 1732829 |
| Dielectric constant | 4.4100000000000001 |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents. |
| InChIKey | HTIRHQRTDBPHNZ-UHFFFAOYSA-N |
| LogP | 3.87 |
| Substances Added to Food (formerly EAFUS) | BUTYL SULFIDE |
| FDA 21 CFR | 172.515 |
| CAS DataBase Reference | 544-40-1(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | 3E3H471GA3 |
| NIST Chemistry Reference | Di-n-butyl sulfide(544-40-1) |
| EPA Substance Registry System | Dibutyl sulfide (544-40-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H227-H303-H315-H319-H335 | |||||||||
| Precautionary statements | P210e-P261-P280a-P305+P351+P338-P405-P501a-P210-P280-P370+P378-P403+P235-P501 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38-41 | |||||||||
| Safety Statements | 26-36/37/39-24/25-36 | |||||||||
| RIDADR | 2810 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | ER6417000 | |||||||||
| F | 13 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1(b) | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29309070 | |||||||||
| Toxicity | LD50 orally in Rabbit: 2220 mg/kg | |||||||||
| NFPA 704 |
|
Dibutyl sulfide price More Price(33)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | W221503 | Butyl sulfide ≥95%, FG | 544-40-1 | 1kg | $199 | 2024-03-01 | Buy |
| Sigma-Aldrich | W221503 | Butyl sulfide ≥95%, FG | 544-40-1 | 4kg | $472 | 2024-03-01 | Buy |
| Sigma-Aldrich | W221503 | Butyl sulfide ≥95%, FG | 544-40-1 | 8kg | $936 | 2024-03-01 | Buy |
| Sigma-Aldrich | NIST2720 | Sulfur in di-n-butyl sulfide NIST?SRM?2720 | 544-40-1 | 5x4.5mL | $1100 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.20252 | Dibutyl sulfide for synthesis | 544-40-1 | 50mL | $69.1 | 2024-03-01 | Buy |
Dibutyl sulfide Chemical Properties,Uses,Production
Description
Dibutyl sulfide (also named as butyl sulfide; N-butyl sulfide; Di-n-butyl sulfide; butylthiobutane), a colorless to pale yellow clear liquid, is a symmetric thioether. Dibutyl sulfide is found in raw cabbage, boiled and cooked beef, and some varieties of mushroom.
Dibutyl sulfide is typically used as a flavoring agent. As a thioether, dibutyl sulfide has applications in organic synthesis as a solvent as well as a reagent. It is used to synthesize specific compound classes including property-enhancing additives, pharmacological drugs, chemical resistant polymers, detergents, and rubber antioxidants. Dibutyl sulfide can also be used as an agricultural intermediate, a sulfiding agent, a refinery catalyst, a lubricant additive, a gas odorant, and a processing aid in mining applications. Furthermore, it can be used as an internal standard in X-ray fluorescence spectrometry (XRF) measurements of sulfur in oils and other liquid hydrocarbon matrices.
References
[1] George A. Burdock (1996) Encyclopedia of Food and Color Additives, Band 1
[2] http://chemicalland21.com/specialtychem/NH/DIBUTYL%20SULFIDE.htm
Chemical Properties
Butyl sulfide has an herbaceous, green, garlic, onion, heavy odor.
Chemical Properties
colourless liquid with a very unpleasant smell
Occurrence
Reported found in raw cabbage, cooked beef and mushrooms.
Uses
Di-n-butyl sulfide is generally used as an agricultural intermediate, a sulfiding agent, a refinery catalyst, a lubricant additive, a gas odorant and a processing aid in mining applications. It finds application as an internal standard in X-ray fluorescence spectrometry (XRF) measurements of sulfur in oils and other liquid hydrocarbon matrices.
Preparation
From butyl bromide and sodium sulfide in boiling ethanol; according to some authors two forms exist, exhibiting different boiling points but identical solubilities in various solvents; both forms are insoluble in water.
Definition
ChEBI: Dibutyl sulfide is an aliphatic sulfide.
Aroma threshold values
Recognition: 0.88 ppb
Synthesis Reference(s)
Journal of the American Chemical Society, 73, p. 2251, 1951 DOI: 10.1021/ja01149a096
Tetrahedron Letters, 29, p. 4477, 1988 DOI: 10.1016/S0040-4039(00)80527-4
General Description
Butyl sulfide is a volatile sulfur compound that can be used as a flavoring agent.
Biochem/physiol Actions
Taste at 5 ppm
Purification Methods
Wash the sulfide with aqueous 5% NaOH, then water. Dry with CaCl2 and distil it from sodium. [Beilstein 1 IV 1559.]
Dibutyl sulfide Preparation Products And Raw materials
Raw materials
1of3
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Qingdao Scienoc Chemical CO Ltd | +86-0532-68076095 +8618661673503 | info@scienoc.com | China | 113 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12839 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5857 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5892 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18153 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20286 | 58 |
| Shandong Deshang Chemical Co., Ltd. | +86-0531-8875-2665 +8613153039501 | info@deshangchem.com | China | 662 | 58 |
| JINING XINHE CHEMICAL CO., LTD | +8615318402391 | sales@xinhepharma.com | China | 809 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
View Lastest Price from Dibutyl sulfide manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-11-11 | Dibutyl sulfide
544-40-1
|
US $8.80-6.20 / kg | 1kg | 99% | 10 tons | Shandong Deshang Chemical Co., Ltd. | |
 |
2024-10-31 | Dibutyl sulfide
544-40-1
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Weibang Biotechnology Co., Ltd | |
 |
2024-10-25 | Dibutyl sulfide
544-40-1
|
US $20.00-1.00 / kg | 1kg | 0.99 | 10 tons | Hebei Yanxi Chemical Co., Ltd. |
-
- Dibutyl sulfide
544-40-1
- US $8.80-6.20 / kg
- 99%
- Shandong Deshang Chemical Co., Ltd.
-
- Dibutyl sulfide
544-40-1
- US $0.00-0.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
-
- Dibutyl sulfide
544-40-1
- US $20.00-1.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.