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(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE structure

CAS No.: 192463-40-4

Chemical Name:: (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE

Synonyms: (s)-phanephos;(R)-PHANEPHOS;(Sp)-Phanephos;(S)-(+)-4,12-Bis(D;(S)-Phanephos, 98%, ee 98%;Bisdiphenylphosphinoparacyclophane;(Sp)-(+)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane;(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE;(S)-(+)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE;4-FLUOROBENZOYLACETONITRILE, 97% N-BOC-4-OXO-L-PROLINE, 97%

CBNumber:: CB1224685

Molecular Formula:: C40H34P2

Molecular Weight:: 576.65

MDL Number:: MFCD03094575

MOL File:: 192463-40-4.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE Properties

Melting point	222-225°C
alpha	+63.2° (c 3.27, CH2Cl2)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	solid
color	white
optical activity	[α]22/D +34°, c = 1 in chloroform
CAS DataBase Reference	192463-40-4

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P305+P351+P338
Hazard Codes	Xi
Risk Statements	36/37/38-37
Safety Statements	26-36/37/39
WGK Germany	3

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE price More Price(15)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	682136	(S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane 96%	192463-40-4	500mg	$685	2024-03-01	Buy
Sigma-Aldrich	682136	(S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane 96%	192463-40-4	100mg	$164	2023-06-20	Buy
Strem Chemicals	15-0426	(S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (S)-PHANEPHOS	192463-40-4	100mg	$102	2024-03-01	Buy
Strem Chemicals	15-0426	(S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (S)-PHANEPHOS	192463-40-4	500mg	$412	2024-03-01	Buy
American Custom Chemicals Corporation	ING0001372	(S)-(+)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE 95.00%	192463-40-4	100MG	$657.07	2021-12-16	Buy

Product number	Packaging	Price	Buy
682136	500mg	$685	Buy
682136	100mg	$164	Buy
15-0426	100mg	$102	Buy
15-0426	500mg	$412	Buy
ING0001372	100MG	$657.07	Buy

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE Chemical Properties,Uses,Production

Reaction

Ligand for rhodium-catalyzed enantioselective hydroboration of cyclopropenes.
Ligand for iridium-catalyzed enantioselective [2+2] cycloaddition of oxabicyclic alkenes with terminal alkynes.
Ligand for the palladium-catalyzed enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
Ligand for the palladium-catalyzed amides synthesis via C(sp3 )–H bond functionalization and CO insertion.
Ligand for iridium-catalyzed diene hydrohydroxymethylation.

Uses

Efficient ligand for asymmetric hydrogentation of dehydroamino acids, methyl esters and keytones.

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE Suppliers

Global( 40)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Coresyn Pharmatech Co., Ltd.	+86-571-86626709 +86-18157142896	cbc@coresyn.com	China	9984	58
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	57505	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	021-61259108 18621169109	market03@meryer.com	China	40228	62
Alfa Aesar	400-6106006	saleschina@alfa-asia.com	China	30123	84
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44689	61
Daicel Chiral Technologies (China)CO.,LTD	021-50460086-9 15921403865	han_yajun@dctc.daicel.com	China	7191	65
Bide Pharmatech Ltd.	400-164-7117 13681763483	product02@bidepharm.com	China	41462	60
Xinxiang Runyu Material Co., Ltd.	166-166-37336996 15690792173	chenxi.song@runvmat.com	China	294	55
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51456	80

Supplier	Advantage
Coresyn Pharmatech Co., Ltd.	58
Aladdin Scientific	58
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Alfa Aesar	84
Energy Chemical	61
Daicel Chiral Technologies (China)CO.,LTD	65
Bide Pharmatech Ltd.	60
Xinxiang Runyu Material Co., Ltd.	55
Sigma-Aldrich	80

192463-40-4((R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE)Related Search:

Diphenylphosphine [2.2]Paracyclophane 4-FLUOROBENZOYLACETONITRILE (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% (R)-PHANEPHOS (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE (R)-PHANEPHOS

(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS (S)-PARAPHOS RUTHENIUMCL2 (R,R)-DPEN DICHLORO[(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2,2]-PARACYCLOPHANE][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM [(R)-PARAPHOS RHODIUM (NBD)]BF4 DICHLORO[(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)

(R)-(-)-4,12-BIS(DI-3,5-XYLYLPHOSPHINO)[2.2]PARACYCLOPHANE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE

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(S)-(+)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE (R)-PHANEPHOS (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE Bisdiphenylphosphinoparacyclophane 4-FLUOROBENZOYLACETONITRILE, 97% N-BOC-4-OXO-L-PROLINE, 97% (s)-phanephos (S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane,min.95%(S)-PHANEPHOS (S)-(+)-4,12-BIS-(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE (S)-PHANEPHOS (S)-Phanephos, 98%, ee 98% (S)-(+)-4,12-Bis(D (S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 97% (S)-PHANEPHOS (Sp)-(+)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane (Sp)-Phanephos (S)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane,99%e.e. (S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (S)-(+)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%,99%ee 192463-40-4 Hydrogenation Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Chiral Phosphine PHANEPhos Series organophosphine ligand