Parylene N | 1633-22-3

Parylene N Properties

Melting point	285-288 °C(lit.)
Boiling point	282.51°C (rough estimate)
Density	1.0102 (estimate)
vapor pressure	0.001Pa at 25℃
refractive index	1.5000 (estimate)
storage temp.	Sealed in dry,Room Temperature
form	powder to crystal
color	White to Almost white
Water Solubility	INSOLUBLE
BRN	1910888
InChI	InChI=1S/C16H16/c1-2-14-4-3-13(1)9-10-15-5-7-16(8-6-15)12-11-14/h1-8H,9-12H2
InChIKey	OOLUVSIJOMLOCB-UHFFFAOYSA-N
SMILES	C12C=CC(=CC=1)CCC1C=CC(=CC=1)CC2
LogP	5.14 at 20℃
FDA UNII	0I9PQB142O
NIST Chemistry Reference	[2.2]Paracyclophane(1633-22-3)
EPA Substance Registry System	Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene (1633-22-3)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302-H315-H319-H332-H335

Precautionary statements

P261-P280-P305+P351+P338

Hazard Codes

Xi,C,F

Risk Statements

11-34

Safety Statements

24/25-45-36/37/39-26-16

WGK Germany

3

RTECS

YD2404000

Hazard Note

Irritant

TSCA

Yes

HS Code

29029080

NFPA 704

	1
0		0

Parylene N price More Price(35)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	P225	[2.2]Paracyclophane 97%	1633-22-3	5G	$36.4	2024-03-01	Buy
TCI Chemical	P1165	[2.2]Paracyclophane >99.0%(GC)	1633-22-3	1g	$99	2024-03-01	Buy
Alfa Aesar	B20136	[2.2]Paracyclophane, 99%	1633-22-3	1g	$54.65	2024-03-01	Buy
Alfa Aesar	B20136	[2.2]Paracyclophane, 99%	1633-22-3	5g	$201	2024-03-01	Buy
TRC	P205825	[2.2]Paracyclophane	1633-22-3	50mg	$60	2021-12-16	Buy

Product number	Packaging	Price	Buy
P225	5G	$36.4	Buy
P1165	1g	$99	Buy
B20136	1g	$54.65	Buy
B20136	5g	$201	Buy
P205825	50mg	$60	Buy

Parylene N Chemical Properties,Uses,Production

Description

[2.2]Paracyclophane is used as an intermediate in organic synthesis or as a reagent in chemical reactions. It serves as the structural backbone of 4-toluenesulfinyl [2.2]p-dicyclohexane and can be used in the synthesis of various mono- and disubstituted [2.2]p-dicyclohexane derivatives. It can also be used for the preparation of metal complexes, and the interaction of the Ag+ cation with the cation -π of [2.2]paracyclophane can be used to synthesise Ag+ - [2.2]paracyclophane complexes using the Ag+ cation. The complex is formed by binding the cation Ag+ to three carbon atoms on a benzene ring of the [2.2]paracyclophane ligand using a cation-π interaction^[1].

Chemical Properties

Parylene N appears as white to light beige crystals or crystalline powder. It serves as an excellent dielectric material, characterized by a very low dissipation factor, high dielectric strength, and a frequency-independent dielectric constant. Parylene N does not contain any chlorine and is very crystalline. Parylene D contains two chlorine atoms per repeating unit. Parylene HT contains two fluorine atoms per repeating unit.

Characteristics

Parylene N has excellent electronic properties, including low dissipation factor, high dielectric strength, and low dielectric constant. These properties are beneficial for applications involving printed circuit boards and signal transmission. The extra chlorine in Parylene D results in slightly higher operating temperature for Parylene D relative to Parylene C.

Uses

2,2]-Paracyclophane is the raw material for the synthesis of parylene which is widely used in microelectronic integrated circuit.

Application

Parylene N, also known as [2.2]Paracyclophane, is a poly-p-xylene variant. Polyparacyclophane has been widely used as a coating for medical devices. It has also been used to make films and porous membranes on which cells can grow.Exposure of Parylene N films to UV light under aerobic conditions leads to the formation of aldehyde and carboxylic acid groups near the film surface. At the maximum exposure dose, the oxygen concentration on the surface of the Parylene N film is approximately 13% and decreases exponentially with depth. This suggests that further modelling and optimisation of this process could be used to regulate the surface concentration of oxygenated substances in poly(parylene) to optimise adhesion and wettability, or for chemical binding to other groups.^[2]

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 1043, 1981 DOI: 10.1021/jo00318a047

Flammability and Explosibility

Not classified

Purification Methods

Purify it by recrystallisation from AcOH. 1H-NMR : 1.62 (Ar-H) and -1.71 (CH2) [Waugh & Fessenden J Am Chem Soc 79 846 1957, IR and UV: Cram et al. J Am Chem Soc 76 6132 1954, Cram & Steinberg J Am Chem Soc 73 5691 1951. It complexes with unsaturated compounds: Cram & Bauer J Am Chem Soc 81 5971 1959, Syntheses: Brink Synthesis 807 1975, Givens et al. J Org Chem 44 16087 1979, Kaplan et al. Tetrahedron Lett 3665 1976]. [Beilstein 5 IV 2223.]

References

[1] DR. PETR VA?URA; Dr. T U; Prof David Sykora. Interaction of the Silver(I) Cation with [2.2]Paracyclophane: Experimental and Theoretical Study[J]. ChemistrySelect, 2022. DOI:10.1002/slct.202203008.
[2] K. G. PRUDEN; S. B; K Sinclair. Characterization of parylene-N and parylene-C photooxidation[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2003, 41 10: 1486-1496. DOI:10.1002/pola.10681.

Parylene N synthesis

Synthesis of Parylene N from trimethyl(p-methylbenzyl)ammonium chloride

Parylene N Preparation Products And Raw materials

Raw materials

P-XYLENE

Preparation Products

4-BROMO[2.2]PARACYCLOPHANE

Parylene N Suppliers

Global( 305)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shenzhen FCD Technology Co., Ltd	+8618676776815	fcd-sd@fcdtech.com	China	10	58
Hebei Mujin Biotechnology Co.,Ltd	+86 13288715578 +8613288715578	sales@hbmojin.com	China	12809	58
AFINE CHEMICALS LIMITED	+86-0571-85134551	sales@afinechem.com	China	15389	58
Hebei Chuanghai Biotechnology Co., Ltd	+8615531151365	mina@chuanghaibio.com	China	18137	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29730	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21628	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29858	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49732	58
Tangshan Moneide Trading Co., Ltd.	+86-315-8309571 +8615633399667	sales@moneidechem.com	China	574	58

Supplier	Advantage
Shenzhen FCD Technology Co., Ltd	58
Hebei Mujin Biotechnology Co.,Ltd	58
AFINE CHEMICALS LIMITED	58
Hebei Chuanghai Biotechnology Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
career henan chemical co	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Tangshan Moneide Trading Co., Ltd.	58

View Lastest Price from Parylene N manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-04-25	[2.2]Paracyclophane 1633-22-3	US $0.00-0.00 / Kg/Drum	1KG	99%	10 TONS	WUHAN FORTUNA CHEMICAL CO., LTD
2025-04-25	[2.2]Paracyclophane,Parylene N Dimer 1633-22-3	US $0.00-0.00 / g	500g	99.7%	100kg	Shenzhen FCD Technology Co., Ltd
2025-04-25	Parylene N 1633-22-3	US $0.00-0.00 / g	500g	99.7%	100kg	Shenzhen FCD Technology Co., Ltd

[2.2]Paracyclophane
1633-22-3
US $0.00-0.00 / Kg/Drum
99%
WUHAN FORTUNA CHEMICAL CO., LTD

[2.2]Paracyclophane,Parylene N Dimer
1633-22-3
US $0.00-0.00 / g
99.7%
Shenzhen FCD Technology Co., Ltd

Parylene N
1633-22-3
US $0.00-0.00 / g
99.7%
Shenzhen FCD Technology Co., Ltd

Parylene N Spectrum

[2.2]Paracyclophane(1633-22-3)¹HNMR [2.2]Paracyclophane(1633-22-3)¹³CNMR [2.2]Paracyclophane(1633-22-3)IR1 [2.2]Paracyclophane(1633-22-3)Raman [2.2]Paracyclophane(1633-22-3)ESR

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TRICYCLO[8.2.2.24,7]HEXADECA-4,6,10,12,13,15-HEXAENE TRICYCLO[8.2.2.2]HEXADECA-4,6,10,12,13,15-HEXAENE [2.2]paracylophan Cyclobis(benzene-1,4-dimethylene) Di-1,4-xylylene Tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene 4,4'-DIMETHYLENE-1,2-DIPHENYLETHANE [2.2]PARACYCLOPHAN [2.2]PARACYCLOPHANE DI-P-XYLENE [2.2]Paracylophane Tricyclo[8,2,2,24,7]hexadeca-4,6,1,12,13,15-hexaene (2.2)PARACYCLOPHAN 97% [2.2]-PARACYCLOPHANE 99+% DI-PARA-XYLYLENE Dimer,Parylene N Parylene N ,99% [2.2](1,4)Cyclophane Di-p-xylylene Tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaene Tricyclo[8,2,2,2]4,7 hexa-4,6,10,12,13,15-decane 2.2ü-Paracyclophane, 99% 4,4'-Ethylene(1,1'-ethylenebisbenzene) Dicyclo-p-xylylene Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12(1),13,15-hexaene [2.2]Paracyclophane,98% PLANYLENE N [2.2]-paracyclophane (Parylene N) Paracyclophan TwodiMericp-xylene Parylene N ([2,2]Paracyclophane) [2.2]Paracyclophane> DI-P-XYLYLENE PCF Paracyclophane 1,4(1,4)-dibenzenacyclohexaphane Parylene N dimer tricyclo[8.2.2.2??]hexadeca-1(13),4(16),5,7(15),10(14),11-hexaene Di-p-xylylene, Parylene N [2.2]Paracyclophane,Parylene N Dimer parylene N Parylene N UVtrace p-Xylene dimer 1633-22-3 C16H16 Organic Building Blocks Cyclophanes Macrocycles for Host-Guest Chemistry Building Blocks Arenes coating Arenes Building Blocks Chemical Synthesis Organic Building Blocks fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials Cyclophanes Functional Materials Macrocycles for Host-Guest Chemistry