- PLANYLENE N
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- $0.00 / 500g
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2024-07-28
- CAS:1633-22-3
- Min. Order: 500g
- Purity: 99.7%
- Supply Ability: 100kg
- [2.2]Paracyclophane
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- $0.00 / 1Kg/Bag
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2024-07-25
- CAS:1633-22-3
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 10 TONS
- Parylene N
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- $0.00 / 500g
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2024-07-12
- CAS:1633-22-3
- Min. Order: 500g
- Purity: 99.7%
- Supply Ability: 100kg
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| [2.2]Paracyclophane Basic information |
Product Name: | [2.2]Paracyclophane | Synonyms: | TRICYCLO[8.2.2.24,7]HEXADECA-4,6,10,12,13,15-HEXAENE;TRICYCLO[8.2.2.2]HEXADECA-4,6,10,12,13,15-HEXAENE;[2.2]paracylophan;Cyclobis(benzene-1,4-dimethylene);Di-1,4-xylylene;Tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene;4,4'-DIMETHYLENE-1,2-DIPHENYLETHANE;[2.2]PARACYCLOPHAN | CAS: | 1633-22-3 | MF: | C16H16 | MW: | 208.3 | EINECS: | 216-644-2 | Product Categories: | coating;Arenes;Building Blocks;Chemical Synthesis;Organic Building Blocks;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials;Cyclophanes;Functional Materials;Macrocycles for Host-Guest Chemistry;1 | Mol File: | 1633-22-3.mol | |
| [2.2]Paracyclophane Chemical Properties |
Melting point | 285-288 °C(lit.) | Boiling point | 282.51°C (rough estimate) | density | 1.0102 (estimate) | vapor pressure | 0.001Pa at 25℃ | refractive index | 1.5000 (estimate) | storage temp. | Sealed in dry,Room Temperature | form | powder to crystal | color | White to Almost white | Water Solubility | INSOLUBLE | BRN | 1910888 | InChI | InChI=1S/C16H16/c1-2-14-4-3-13(1)9-10-15-5-7-16(8-6-15)12-11-14/h1-8H,9-12H2 | InChIKey | OOLUVSIJOMLOCB-UHFFFAOYSA-N | SMILES | C12C=CC(=CC=1)CCC1C=CC(=CC=1)CC2 | LogP | 5.14 at 20℃ | NIST Chemistry Reference | [2.2]Paracyclophane(1633-22-3) | EPA Substance Registry System | Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene (1633-22-3) |
| [2.2]Paracyclophane Usage And Synthesis |
Description | [2.2]Paracyclophane is used as an intermediate in organic synthesis or as a reagent in chemical reactions. It serves as the structural backbone of 4-toluenesulfinyl [2.2]p-dicyclohexane and can be used in the synthesis of various mono- and disubstituted [2.2]p-dicyclohexane derivatives. It can also be used for the preparation of metal complexes, and the interaction of the Ag+ cation with the cation -π of [2.2]paracyclophane can be used to synthesise Ag+ - [2.2]paracyclophane complexes using the Ag+ cation. The complex is formed by binding the cation Ag+ to three carbon atoms on a benzene ring of the [2.2]paracyclophane ligand using a cation-π interaction[1]. | Chemical Properties | WHITE TO LIGHT BEIGE CRYSTALS OR CRYSTAL. POWDER | Uses | 2,2]-Paracyclophane is the raw material for the synthesis of parylene which is widely used in microelectronic integrated circuit. | Synthesis Reference(s) | The Journal of Organic Chemistry, 46, p. 1043, 1981 DOI: 10.1021/jo00318a047 | Flammability and Explosibility | Not classified | Purification Methods | Purify it by recrystallisation from AcOH. 1H-NMR : 1.62 (Ar-H) and -1.71 (CH2) [Waugh & Fessenden J Am Chem Soc 79 846 1957, IR and UV: Cram et al. J Am Chem Soc 76 6132 1954, Cram & Steinberg J Am Chem Soc 73 5691 1951. It complexes with unsaturated compounds: Cram & Bauer J Am Chem Soc 81 5971 1959, Syntheses: Brink Synthesis 807 1975, Givens et al. J Org Chem 44 16087 1979, Kaplan et al. Tetrahedron Lett 3665 1976]. [Beilstein 5 IV 2223.] | References | [1] DR. PETR VA?URA; Dr. T U; Prof David Sykora. Interaction of the Silver(I) Cation with [2.2]Paracyclophane: Experimental and Theoretical Study[J]. ChemistrySelect, 2022. DOI:10.1002/slct.202203008. |
| [2.2]Paracyclophane Preparation Products And Raw materials |
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