ChemicalBook >> CAS DataBase List >>Methylthio acetaldoxime

Methylthio acetaldoxime

Methylthio acetaldoxime structure

CAS No.: 10533-67-2

Chemical Name:: Methylthio acetaldoxime

Synonyms: Einecs 234-096-2;Methylthio aldoxime;Methylthioacetaldoxime;2-(methylthio)acetaldeh;2-methylthioethanaldoxime;2-(Methylthio)Acetaldoxime;(methylthio)acetaldehyde oxime;(methylthio)-acetaldehyd oxime;2-(Methylthio)Acetaldehyde Oxime;methylsulfanyl-acetaldehyde oxime

CBNumber:: CB2874742

Molecular Formula:: C3H7NOS

Molecular Weight:: 105.16

MDL Number:: MFCD09751193

MOL File:: 10533-67-2.mol

MSDS File:: SDS

Last updated:2023-05-09 09:30:37

Methylthio acetaldoxime Properties

Boiling point	209.2±23.0 °C(Predicted)
Density	1.09±0.1 g/cm3(Predicted)
pka	10.66±0.14(Predicted)
FDA UNII	M9P2B4GEE9
EPA Substance Registry System	Acetaldehyde, 2-(methylthio)-, oxime (10533-67-2)

Methylthio acetaldoxime Chemical Properties,Uses,Production

Chemical Properties

Pure methylthio acetaldoxime is white or light yellow solid, mp 94～97℃[93～95℃(Z type), 47～50℃(E type)], does not decompose within 24h at 74℃; 48h at 105℃ Decompose 93%. Methomyl oxime aqueous solution, when pH=7, does not decompose within 12h; when pH=2, it decomposes 12% in 24h and 18% in 72h (both at 25°C). It is insoluble in water and easily soluble in organic solvents.

Uses

1-Methylthio acetaldoxime, referred to as Methylthio acetaldoxime.It is an intermediate with considerable economic value, which can be used in the manufacture of carbamate insecticides such as methomyl, thiodimethoxam and cotton bollcarb.

Definition

ChEBI: (methylsulfanyl)acetaldehyde oxime is an aliphatic aldoxime resulting from the formal condensation of 2-(methylsulfanyl)acetaldehyde with hydroxylamine. It is an aliphatic aldoxime and a methyl sulfide. It is functionally related to a (methylsulfanyl)acetaldehyde.

Synthesis

The key to the synthesis of methomyl is the synthesis of the intermediate Methylthio acetaldoxime. The synthesis of Methylthio acetaldoxime generally has the following five methods: ① thioacetaldoxime method; ② acetonitrile method; ③ methyl ethyl ketone method; ④ nitroethane method; ⑤ acetaldehyde method.

Methylthio acetaldoxime Preparation Products And Raw materials

Raw materials

Sodium thiomethoxide Acetaldoxime Chlorine 2-Butanone Hydroxylamine hydrochloride

Acetaldehyde Nitroethane

1of2

Preparation Products

Methomyl Methomyl emulsifiable concentrate Thiodicarb

10533-67-2(Methylthio acetaldoxime)Related Search:

ALDICARB-SULFONE ALDICARB 2-Mercaptobenzothiazolyl-(Z)-(2-aminothiazol-4-yl)-2-(tert-butoxycarbonyl) isopropoxyiminoacetate BUTOCARBOXIM 2-(4-FLUOROBENZYLSULFONYL)ACETAMIDOXIME

BUTOXYCARBOXIM ALDICARB-SULFOXIDE 2-[(4-CHLOROPHENYL)SULFONYL]-N'-HYDROXYETHANIMIDAMIDE BUTOCARBOXIM SULFOXIDE METHOMYL-OXIME

Methomyl Acetaldoxime Thiodicarb S-benzothiazol-2-yl 2-(2-amino-1,3-thiazol-4-yl)-2-(methoxyimino)thioacetate 2-[(2-FURYLMETHYL)SULFONYL]-N'-HYDROXYETHANIMIDAMIDE

N'-HYDROXY-2-(PHENYLSULFONYL)ETHANIMIDAMIDE 3-(methylthio)butan-2-one oxime TETRAHYDROTHIOPHEN-3-ONE OXIME

1of4

Acetaldehyde, 2-(methylthio)-, oxime Einecs 234-096-2 MethoMyl oxiMe,MHTA,METHYL-THIOACETOHYDROXAMATE 2-(Methylthio)Acetaldehyde Oxime 2-(Methylthio)Acetaldoxime 2-methylthioethanaldoxime Methylthio Acetaldoxime 2-Methylsulfanylacetaldehyde Oxime Methylthioacetaldoxime (methylthio)acetaldehyde oxime Acetaldehyde, (methylthio)-, oxime (methylthio)-acetaldehyd oxime Methylthio aldoxime 2-(methylthio)acetaldeh methylsulfanyl-acetaldehyde oxime 10533-67-2