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Benzyl 2-chloroacetate

CAS No.
140-18-1
Chemical Name:
Benzyl 2-chloroacetate
Synonyms
AKOS B029322;monochloroacetate;benzyl chloracetate;Benzyl 2-chloroaceta;BENZYL CHLOROACETATE;BENZYL-(CHLORACETAT);benzyl 2-chloroacetate;benzylmonochloracetate;Benzyl chloroacetate,98%;Benzyl chloroacetate 99%
CBNumber:
CB3245642
Molecular Formula:
C9H9ClO2
Molecular Weight:
184.62
MDL Number:
MFCD00157062
MOL File:
140-18-1.mol
MSDS File:
SDS
Last updated:2024-07-18 18:48:51

Benzyl 2-chloroacetate Properties

Boiling point 90 °C/1 mmHg (lit.)
Density 1.215 g/mL at 25 °C (lit.)
refractive index n20/D 1.525(lit.)
Flash point >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form clear liquid
Specific Gravity 1.215
color Oil
Water Solubility insoluble
CAS DataBase Reference 140-18-1(CAS DataBase Reference)
FDA UNII B52EJ32AB5
EPA Substance Registry System Acetic acid, chloro-, phenylmethyl ester (140-18-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
RTECS  AF8750000
HS Code  29154000
Toxicity LDLo ipr-mus: 500 mg/kg CBCCT* 8,99,56
NFPA 704
1
0 0

Benzyl 2-chloroacetate price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 349712 Benzyl chloroacetate 99% 140-18-1 5ml $50.9 2023-01-07 Buy
TCI Chemical C1265 Benzyl Chloroacetate >97.0%(GC) 140-18-1 25g $103 2024-03-01 Buy
TCI Chemical C1265 Benzyl Chloroacetate >97.0%(GC) 140-18-1 250g $646 2024-03-01 Buy
American Custom Chemicals Corporation HCH0013935 BENZYL CHLOROACETATE 95.00% 140-18-1 2.5G $746.88 2021-12-16 Buy
American Custom Chemicals Corporation HCH0013935 BENZYL CHLOROACETATE 95.00% 140-18-1 5G $808.96 2021-12-16 Buy
Product number Packaging Price Buy
349712 5ml $50.9 Buy
C1265 25g $103 Buy
C1265 250g $646 Buy
HCH0013935 2.5G $746.88 Buy
HCH0013935 5G $808.96 Buy

Benzyl 2-chloroacetate Chemical Properties,Uses,Production

Chemical Properties

Benzyl 2-chloroacetate is a colorless, slightly viscous liquid. Insoluble in water, soluble in alcohol and oils. Sp.Gr = 1.22. Mild, Jasmin-type odor, floral-fruity, of considerable tenacity.

Uses

Benzyl chloroacetate may be used:

  • in the synthesis of monoesters of phosphonoacetic acid
  • in the synthesis of N-benzoyl-glycyl- hydroxyl acetic acid, ester substrate for carboxypeptidase Y catalyzed peptide synthesis
  • as reagent in the total syntheses of the (±)-di-O-methyl ethers of the norlignans sequirin-A, agatharesinol, and hinokiresinol, and of (±)-tri-O-methyl sequirin-E

Preparation

From Benzyl alcohol and Monochloroacetic acid by direct esterification under azeotropic conditions.

General Description

Benzyl chloroacetate is an ester. Could find usc in Jasmin, Lilac. Appleblossom fragrances, particularly for soap, where this ester has greater fixative effect than the Benzyl acetate. However, this ester must be absolutely acid-free to be permitted or recommended for use in any cosmetic product. The acid is highly corrosive. Older odor-descriptions of this ester seem to indicate that the product has not always been very pure.

Safety Profile

Moderately toxic byintraperitoneal route. When heated todecomposition it emits toxic fumes of Cl- .

Benzyl 2-chloroacetate Preparation Products And Raw materials

Global( 175)Suppliers
Supplier Tel Email Country ProdList Advantage
Shaanxi Dideu Medichem Co. Ltd
+86-29-81148696 +86-15536356810 1022@dideu.com China 3878 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29798 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18642 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21667 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9337 55
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29888 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49392 58
Career Henan Chemica Co
+86-0371-86658258 +8613203830695 laboratory@coreychem.com China 30250 58

View Lastest Price from Benzyl 2-chloroacetate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Benzyl 2-chloroacetate pictures 2024-07-18 Benzyl 2-chloroacetate
140-18-1
US $0.00-0.00 / KG 1KG 99.0% 1000KG Shaanxi Dideu Medichem Co. Ltd
Benzyl 2-chloroacetate pictures 2019-07-06 Benzyl 2-chloroacetate
140-18-1
US $1.00 / KG 1KG 98% 100KG Career Henan Chemical Co
AKOS B029322 CHLOROACETIC ACID BENZYL ESTER BENZYL-(CHLORACETAT) BENZYL CHLOROACETATE benzyl 2-chloroacetate Acetic acid, chloro-, phenylmethyl ester benzyl chloracetate Phenylmethyl 2-chloroacetate Benzyl chloroacetate,98% Benzyl 2-chloroaceta Benzyl chloroacetate, 98% 25ML Benzyl chloroacetate 99% 2-CHLORO ACETIC ACID BENZYLESTER benzyl-alpha-chloroacetate benzylmonochloracetate chloro-aceticacibenzylester chloro-aceticaciphenylmethylester monochloroacetate phenylmethylchloroacetate Benzyl monochloroacetate 2-chloroacetic acid (phenylmethyl) ester Benzyl Chloroacetate > Acetic acid, 2-chloro-, phenylmethyl ester 2-CHLORO ACETIC ACID BENZYLESTER (BENZYL CHLORO ACETATE) 140-18-1 140-18-0 ClCH2COOCH2C6H5 ClCH2CO2CH2C6H5 Carbonyl Compounds C8 to C9 Building Blocks HALOGEN Organic Building Blocks Esters C8 to C9 Carbonyl Compounds Esters