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DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

CAS No.
12148-71-9
Chemical Name:
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
Synonyms
[Ir(OMe)(1,5-cod)]2;Bis(1,5-cyclooctadiene)dimethoxydiiridium;(1,5-Cyclooctadiene)(methoxy)iridium dimer;DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM;Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I);Bis(1,5-cyclooctadiene)di-mu-methoxydiiridium(I);5-cod)]2;[Ir(OMe)(1;Methoxy(cycL;Di-μ-methoxobis
CBNumber:
CB3287961
Molecular Formula:
C18H22Ir2O2
Molecular Weight:
654.81
MDL Number:
MFCD08459360
MOL File:
12148-71-9.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Properties

Melting point 154-179 °C (D)
storage temp. -20°C
form Powder
color yellow
Sensitive Light, Air & Moisture Sensitive
InChIKey WLPGZWOTJGJODI-SXGOCSEPSA-N

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3
TSCA  No
HS Code  2843909000
NFPA 704
1
2 0

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 685062 (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer 12148-71-9 1g $214 2024-03-01 Buy
Sigma-Aldrich 685062 (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer 12148-71-9 25g $3800 2024-03-01 Buy
TCI Chemical C2662 (1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer 12148-71-9 1g $606 2024-03-01 Buy
TCI Chemical C2662 (1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer 12148-71-9 200mg $122 2024-03-01 Buy
Alfa Aesar 044967 Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58% 12148-71-9 1g $429 2023-06-20 Buy
Product number Packaging Price Buy
685062 1g $214 Buy
685062 25g $3800 Buy
C2662 1g $606 Buy
C2662 200mg $122 Buy
044967 1g $429 Buy

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Chemical Properties,Uses,Production

Description

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I), also known as methoxy(cyclooctadiene)iridium(I) dimer, is used as a catalyst in the preparation of heteroaryl fused indole ring systems as inhibition of HCV NS5B polymerase and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration. It is a powerful C-H activation catalyst to prepare phenols from arenes. It is also the catalyst of ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation.

Chemical Properties

yellow solid

Uses

Methoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration.

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 268)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29791 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18779 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32957 60
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29884 58
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715 admin@nexconn.com China 10310 58
Shanghai Worldyang Chemical Co.,Ltd.
+86-021-56795779 +8613651600618 sales@worldyachem.com China 1243 58
Xi'an Kono chem co., Ltd.,
029-86107037 13289246953 info@konochemical.com China 2993 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5600 58

View Lastest Price from DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer pictures 2024-11-22 (1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer
12148-71-9
US $0.00 / G 10G 98%min 30kg/month WUHAN FORTUNA CHEMICAL CO., LTD
	DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) pictures 2022-09-24 DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
12148-71-9
US $0.00 / kg 1kg 99% 1000kg henan kanbei chemical co.,ltd
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) pictures 2022-09-07 DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
12148-71-9
US $0.00-0.00 / KG 1KG 98% 1tone Henan Aochuang Chemical Co.,Ltd.
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I),min.98% BIS(1,5-CYCLOOCTADIENE) DI-MU-METHOXYDII [Ir(OMe)(1 5-cod)]2 Bis[(1,5-cyclooctadiene)(methanolato)iridium] -methoxy)iridium(I) dimer (1,5-Cyclooctadiene)(methoxy)iridium(I) dimer Methoxy(cyclooctadiene)iridium(I) dimer Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I), min. 98% Methoxy(cyclooctadiene)iridium(I) dimer, Ir nominally 58% Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(I),98% Bis(1,5-cyclooctadiene) di-u-methoxydiiridium Di-Methoxobis(1,5-cyclooctadiene)diiridiuM(I) Di-mu-methoxobis(1,5-cyclooctadiene)diiridium (I), min. 98% (Cycloocta-1,5-diene)(methoxy)iridium(I) dimer Bis(cycloocta-1,5-diene) di-u-methoxydiiridium Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I),98% [Ir(COD)(OMe)]2 IridiuM, bis[(1,2,5,6-h)-1,5-cyclooctadiene]di-M-Methoxydi- Di-μ-Methoxobis(1,5-cyclooctadiene)diiridiuM(I),[Ir(COD)(OMe)]2 Di-mu-methoxobis(1,5-cycloo [Ir(Ome)(1,5-cod)Cl]2 (Cycloocta-1,5-diene)(methoxy)iridium(I) dimer 97% Di-μ-methoxobis(1,5-cyclooctadiene)diiridium(Ⅰ) Methoxy(cycL ooctadiene)iridium(I) dimer Methoxy(cyclooctadiene)iridium(I)dimer,Irnominally58% Methoxy(cyclooctadiene)iridium(I) dimerIr nominally DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) ISO 9001:2015 REACH 5-CYCLOOCTADIENE)DIIRIDIUM(I) DI-MU-METHOXOBIS(1 [Ir(OMe)(1,5-cod)]2 (1,5-Cyclooctadiene)(methoxy)iridium dimer Bis(1,5-cyclooctadiene)dimethoxydiiridium Bis(1,5-cyclooctadiene)di-μ-methoxydiiridium(I) DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM Bis(1,5-cyclooctadiene)di-mu-methoxydiiridium(I) Bis[(1,2,5,6-h)-1,5-cyclooctadiene]di-m- methoxydi-iridium Di-(μ-methoxy)bis(1,5-cyclooctadiene)diiridium(I) Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium (1,5-Cyclooctadiene)(methoxy)iridium(I)dimer,Bis(1,5-cyclooctadiene)di-u-methoxydiiridium (1,5-Cyclooctadiene)(methoxy)iridium(I) Di-μ-methoxobis bis((1Z,5Z)-cycloocta-1,5-diene) dimethyl-2,4-dioxa-1,3-diiridabicyclo[1.1.0]butane-2,4-diium-1,3-diuide Di-u-methoxobis(1,5-cyclooctadiene)diiridium (I) Tetrakis(acetonitrle)palladium(I)tetrafluoroborate 12148-71-9 121148-71-9 2C8H12C2H6Ir2O2 IrOCH3C8H122 C18H30Ir2O2 C22H42Ir2O2 organometallic complex Metal Catalysts Ir