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ChemicalBook >> CAS DataBase List >>ethyl 4,4,4-trifluorobut-2-enoate

ethyl 4,4,4-trifluorobut-2-enoate

ethyl 4,4,4-trifluorobut-2-enoate Structure
ethyl 4,4,4-trifluorobut-2-enoate structure
CAS No.
406-10-0
Chemical Name:
ethyl 4,4,4-trifluorobut-2-enoate
Synonyms
ethyl 4,4,4-trifluorobut-2-enoate;4,4,4-trifluoro-2-Butenoic acid ethyl ester;2-Butenoic acid, 4,4,4-trifluoro-, ethyl ester
CBNumber:
CB41551282
Molecular Formula:
C6H7F3O2
Molecular Weight:
168.11
MDL Number:
MFCD00009903
MOL File:
406-10-0.mol
MSDS File:
SDS
Last updated:2025-01-27 09:38:02
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ethyl 4,4,4-trifluorobut-2-enoate Properties

Density 1.125 g/mL at 25 °C(lit.)
refractive index n20/D 1.3601(lit.)
Flash point 26°C
form liquid
Boiling point 114-115°C(lit.)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H319-H335
Precautionary statements  P210-P305+P351+P338
RIDADR  UN 3272 3 / PGIII
WGK Germany  3

ethyl 4,4,4-trifluorobut-2-enoate price More Price(1)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 269697 Ethyl 4,4,4-trifluorocrotonate 98% 406-10-0 5g $77.2 2024-03-01 Buy
Product number Packaging Price Buy
269697 5g $77.2 Buy

ethyl 4,4,4-trifluorobut-2-enoate Chemical Properties,Uses,Production

Uses

Ethyl 4,4,4-trifluorocrotonate was used in the synthesis of (2S,3S)-3-methyl- and (2S,3S)-3-trifluoromethylpyroglutamic acid. It undergoes diastereoselective Michael addition reaction with ethyl crotonate.

General Description

The Michael reaction between ethyl 4,4,4-trifluorocrotonate and a Ni(II) complex of the Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone was studied.

ethyl 4,4,4-trifluorobut-2-enoate Preparation Products And Raw materials

Raw materials

Preparation Products

ethyl 4,4,4-trifluorobut-2-enoate Suppliers

Global( 21)Suppliers
Supplier Tel Email Country ProdList Advantage
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Anichem Inc. 0512-69369885 sales@anichem.com.cn China 495 55
Shanghai Tombiopharma Chemical Co. Ltd. 13391076197 tombiopharma@163.com China 4987 55
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51456 80
Zhengzhou Huiju Chemical Co., Ltd. 0371-0371-55900031 18137872243 2853979815@qq.com China 10112 55
Nanjing Chemedicine BioTech Co., Ltd. 15722927296 71139532@qq.com China 426 58
TCI (Shanghai) Chemical Trading Co., Ltd. 021-021-61109150 sales@tcisct.com China 31121 58
Bide Pharmatech Ltd. 400-1647117 13681763483 product02@bidepharm.com China 62072 58
Aikon International Limited 18626450290 yftan@aikonchem.com China 10715 58
Hangzhou Mingma Technology Co., LTD 17621758100 xinming1991@126.com China 113 58
Supplier Advantage
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Anichem Inc. 55
Shanghai Tombiopharma Chemical Co. Ltd. 55
Sigma-Aldrich 80
Zhengzhou Huiju Chemical Co., Ltd. 55
Nanjing Chemedicine BioTech Co., Ltd. 58
TCI (Shanghai) Chemical Trading Co., Ltd. 58
Bide Pharmatech Ltd. 58
Aikon International Limited 58
Hangzhou Mingma Technology Co., LTD 58

ethyl 4,4,4-trifluorobut-2-enoate Spectrum

ethyl 4,4,4-trifluorobut-2-enoate(406-10-0)1HNMRethyl 4,4,4-trifluorobut-2-enoate(406-10-0)FT-IRethyl 4,4,4-trifluorobut-2-enoate(406-10-0)IR
ethyl 4,4,4-trifluorobut-2-enoate 2-Butenoic acid, 4,4,4-trifluoro-, ethyl ester 4,4,4-trifluoro-2-Butenoic acid ethyl ester 406-10-0