(S)-(-)-1-(1-Naphthyl)ethylamine
- CAS No.
- 10420-89-0
- Chemical Name:
- (S)-(-)-1-(1-Naphthyl)ethylamine
- Synonyms
- (S)-1-(1-NAPHTHYL)ETHYLAMINE;(S)-1-(NAPHTHALEN-1-YL)ETHANAMINE;Cinacalcet-22;Cinacalcet Impurity 35;Cinacalcet Impurity 73;1-(1-Naphthyl)ethanamine;L-A-(1-NAPHTHYL)ETHYLAMINE;(S) 1-(1-NAPTHYL)ETHYLAMINE;(s)-1-naphthalenemethanamin;(1S)-1-(1-Naphthyl)ethanamine
- CBNumber:
- CB4323198
- Molecular Formula:
- C12H13N
- Molecular Weight:
- 171.24
- MDL Number:
- MFCD00064179
- MOL File:
- 10420-89-0.mol
- MSDS File:
- SDS
alpha | -60 º (C=2, MEOH) |
---|---|
Boiling point | 153 °C/11 mmHg (lit.) |
Density | 1.067 g/mL at 20 °C (lit.) |
refractive index |
n |
Flash point | >230 °F |
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
solubility | Soluble in chloroform, ethanol. |
form | Liquid |
pka | 9.26±0.40(Predicted) |
color | brown |
optical activity | [α]20/D 59°, c = 5 in methanol |
Sensitive | Air Sensitive |
BRN | 2208024 |
InChIKey | RTCUCQWIICFPOD-VIFPVBQESA-N |
CAS DataBase Reference | 10420-89-0(CAS DataBase Reference) |
NIST Chemistry Reference | (S)-(-)-«alpha»-(1-naphthyl)ethylamine(10420-89-0) |
EPA Substance Registry System | 1-Naphthalenemethanamine, .alpha.-methyl-, (.alpha.S)- (10420-89-0) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36-37/39 | |||||||||
RIDADR | 2735 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | QJ6963000 | |||||||||
F | 10-34 | |||||||||
Hazard Note | Irritant | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29214990 | |||||||||
NFPA 704 |
|
(S)-(-)-1-(1-Naphthyl)ethylamine price More Price(45)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 237450 | (S)-(?)-1-(1-Naphthyl)ethylamine ≥99% | 10420-89-0 | 1g | $61 | 2024-03-01 | Buy |
Sigma-Aldrich | 237450 | (S)-(?)-1-(1-Naphthyl)ethylamine ≥99% | 10420-89-0 | 5g | $122 | 2024-03-01 | Buy |
TCI Chemical | N0481 | (S)-(-)-1-(1-Naphthyl)ethylamine >99.0%(GC) | 10420-89-0 | 1g | $40 | 2024-03-01 | Buy |
TCI Chemical | N0481 | (S)-(-)-1-(1-Naphthyl)ethylamine >99.0%(GC) | 10420-89-0 | 5g | $113 | 2024-03-01 | Buy |
Alfa Aesar | A17176 | (S)-(-)-1-(1-Naphthyl)ethylamine, 99% | 10420-89-0 | 1g | $26.65 | 2024-03-01 | Buy |
(S)-(-)-1-(1-Naphthyl)ethylamine Chemical Properties,Uses,Production
Description
(S)-(-)-1-(1-Naphthyl)ethylamine is an organic compound used as a raw material for organic synthesis. Chiral moieties were connected to the heteroatom-bridged calix-triazin scaffold by reactions of (S)- or (R)-(+)-1-(1-Naphthyl)ethylamine with tetraazacalix[4]arene[2]triazine.
Chemical Properties
(S)-(-)-1-(1-Naphthyl)ethylamine Appearance is colourless to light orange to yellow transparent liquid, hygroscopicity, thermal sensitivity. Density: 1.067 g/mL (lit.) at 20 °C; Boiling Point: 125 °C/3 mmHg; Specific Gravity (20/20): 1.07; Refractive Index: 1.62. Store under inert gas.
Uses
(S)-(-)-1-(1-Naphthyl)ethylamine is used in the asymmetric synthesis of α-cyanocarboxylates. Also used in the synthesis of chiral imadazolin-2-ylidene ligands used in organometallic catalysis. Chiral/Asymmetric synthesis.
Uses
Employed in a preparation of a chiral thiourea solvating agent useful for enantiodiscrimination of α-hydroxy and α-amino acids by 1H NMR.
Purification Methods
Purify the amine by distillation in a good vacuum. [Mori et al. Tetrahedron 37 1343 1981, cf Wilson in Topics Stereochem (Allinger and Eliel eds) v o l 6 135 1971, Fredga et al. Acta Chem Scand 11 1609 1957.] The hydrochlorides crystallise from H2O [] D 18 ±3.9o (c 3, H2O), and the sulfates recrystallise from H2O as tetrahydrates m 230-232o. The RS-amine has b 153o/11mm, 156o/15mm, 183.5o/41mm [Blicke & Maxwell J Am Chem Soc 6 1 1780 1939]. [Beilstein 12 III 3111.]
(S)-(-)-1-(1-Naphthyl)ethylamine Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Golden Pharma Co., Limited | +undefined18958062155 | sales@zjgoldpharm.com | China | 5899 | 58 |
Hangzhou Zelixir Biotech Co., Ltd. | +8618867646786 | neal.chen@zelixir.com | China | 232 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20286 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18775 | 58 |
Beijing Cooperate Pharmaceutical Co.,Ltd | 010-60279497 | sales01@cooperate-pharm.com | CHINA | 1803 | 55 |
Chembon Pharmaceutical Co., Ltd. | +86-28-8425-2981 | CHINA | 722 | 55 | |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29881 | 58 |
Shanghai Arbor Chemical Co., Ltd. | 021-60451682 | act@arborchemical.com | CHINA | 904 | 58 |
Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 8497 | 58 |
Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 | info@konochemical.com | China | 2993 | 58 |
View Lastest Price from (S)-(-)-1-(1-Naphthyl)ethylamine manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-10-31 | (S)-(-)-1-(1-Naphthyl)ethylamine
10420-89-0
|
US $0.00 / g | 10g | 99% | 10tons | Yangzhou Qinyuan Pharmatech Co.,ltd | ||
2023-12-24 | (S)-(-)-1-(1-Naphthyl)ethylamine
10420-89-0
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2022-09-20 | (S)-(-)-1-(1-Naphthyl)ethylamine
10420-89-0
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. |
- (S)-(-)-1-(1-Naphthyl)ethylamine
10420-89-0
- US $0.00 / g
- 99%
- Yangzhou Qinyuan Pharmatech Co.,ltd
- (S)-(-)-1-(1-Naphthyl)ethylamine
10420-89-0
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
- (S)-(-)-1-(1-Naphthyl)ethylamine
10420-89-0
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
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