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(S)-(-)-1-(1-Naphthyl)ethylamine

CAS No.
10420-89-0
Chemical Name:
(S)-(-)-1-(1-Naphthyl)ethylamine
Synonyms
(S)-1-(1-NAPHTHYL)ETHYLAMINE;(S)-1-(NAPHTHALEN-1-YL)ETHANAMINE;Cinacalcet-22;Cinacalcet Impurity 35;Cinacalcet Impurity 73;1-(1-Naphthyl)ethanamine;L-A-(1-NAPHTHYL)ETHYLAMINE;(S) 1-(1-NAPTHYL)ETHYLAMINE;(s)-1-naphthalenemethanamin;(1S)-1-(1-Naphthyl)ethanamine
CBNumber:
CB4323198
Molecular Formula:
C12H13N
Molecular Weight:
171.24
MDL Number:
MFCD00064179
MOL File:
10420-89-0.mol
MSDS File:
SDS
Last updated:2024-04-02 16:06:51

(S)-(-)-1-(1-Naphthyl)ethylamine Properties

alpha -60 º (C=2, MEOH)
Boiling point 153 °C/11 mmHg (lit.)
Density 1.067 g/mL at 20 °C (lit.)
refractive index n20/D 1.623(lit.)
Flash point >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Soluble in chloroform, ethanol.
form Liquid
pka 9.26±0.40(Predicted)
color brown
optical activity [α]20/D 59°, c = 5 in methanol
Sensitive Air Sensitive
BRN 2208024
InChIKey RTCUCQWIICFPOD-VIFPVBQESA-N
CAS DataBase Reference 10420-89-0(CAS DataBase Reference)
NIST Chemistry Reference (S)-(-)-«alpha»-(1-naphthyl)ethylamine(10420-89-0)
EPA Substance Registry System 1-Naphthalenemethanamine, .alpha.-methyl-, (.alpha.S)- (10420-89-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
RIDADR  2735
WGK Germany  3
RTECS  QJ6963000
10-34
Hazard Note  Irritant
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29214990
NFPA 704
0
3 0

(S)-(-)-1-(1-Naphthyl)ethylamine price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 237450 (S)-(?)-1-(1-Naphthyl)ethylamine ≥99% 10420-89-0 1g $61 2024-03-01 Buy
Sigma-Aldrich 237450 (S)-(?)-1-(1-Naphthyl)ethylamine ≥99% 10420-89-0 5g $122 2024-03-01 Buy
TCI Chemical N0481 (S)-(-)-1-(1-Naphthyl)ethylamine >99.0%(GC) 10420-89-0 1g $40 2024-03-01 Buy
TCI Chemical N0481 (S)-(-)-1-(1-Naphthyl)ethylamine >99.0%(GC) 10420-89-0 5g $113 2024-03-01 Buy
Alfa Aesar A17176 (S)-(-)-1-(1-Naphthyl)ethylamine, 99% 10420-89-0 1g $26.65 2024-03-01 Buy
Product number Packaging Price Buy
237450 1g $61 Buy
237450 5g $122 Buy
N0481 1g $40 Buy
N0481 5g $113 Buy
A17176 1g $26.65 Buy

(S)-(-)-1-(1-Naphthyl)ethylamine Chemical Properties,Uses,Production

Description

(S)-(-)-1-(1-Naphthyl)ethylamine is an organic compound used as a raw material for organic synthesis. Chiral moieties were connected to the heteroatom-bridged calix-triazin scaffold by reactions of (S)- or (R)-(+)-1-(1-Naphthyl)ethylamine with tetraazacalix[4]arene[2]triazine.

Chemical Properties

(S)-(-)-1-(1-Naphthyl)ethylamine Appearance is colourless to light orange to yellow transparent liquid, hygroscopicity, thermal sensitivity. Density: 1.067 g/mL (lit.) at 20 °C; Boiling Point: 125 °C/3 mmHg; Specific Gravity (20/20): 1.07; Refractive Index: 1.62. Store under inert gas.

Uses

(S)-(-)-1-(1-Naphthyl)ethylamine is used in the asymmetric synthesis of α-cyanocarboxylates. Also used in the synthesis of chiral imadazolin-2-ylidene ligands used in organometallic catalysis. Chiral/Asymmetric synthesis.

Uses

Employed in a preparation of a chiral thiourea solvating agent useful for enantiodiscrimination of α-hydroxy and α-amino acids by 1H NMR.

Purification Methods

Purify the amine by distillation in a good vacuum. [Mori et al. Tetrahedron 37 1343 1981, cf Wilson in Topics Stereochem (Allinger and Eliel eds) v o l 6 135 1971, Fredga et al. Acta Chem Scand 11 1609 1957.] The hydrochlorides crystallise from H2O [] D 18 ±3.9o (c 3, H2O), and the sulfates recrystallise from H2O as tetrahydrates m 230-232o. The RS-amine has b 153o/11mm, 156o/15mm, 183.5o/41mm [Blicke & Maxwell J Am Chem Soc 6 1 1780 1939]. [Beilstein 12 III 3111.]

1025949-34-1
10420-89-0
Synthesis of (S)-(-)-1-(1-Naphthyl)ethylamine from 1-Naphthalenemethanol, α-methyl-, 1-methanesulfonate, (αR)-

(S)-(-)-1-(1-Naphthyl)ethylamine Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 352)Suppliers
Supplier Tel Email Country ProdList Advantage
Golden Pharma Co., Limited
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029-86107037 13289246953 info@konochemical.com China 2993 58

View Lastest Price from (S)-(-)-1-(1-Naphthyl)ethylamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S)-(-)-1-(1-Naphthyl)ethylamine pictures 2024-10-31 (S)-(-)-1-(1-Naphthyl)ethylamine
10420-89-0
US $0.00 / g 10g 99% 10tons Yangzhou Qinyuan Pharmatech Co.,ltd
(S)-(-)-1-(1-Naphthyl)ethylamine pictures 2023-12-24 (S)-(-)-1-(1-Naphthyl)ethylamine
10420-89-0
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
(S)-(-)-1-(1-Naphthyl)ethylamine pictures 2022-09-20 (S)-(-)-1-(1-Naphthyl)ethylamine
10420-89-0
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
(1S)-1-NAPHTHALEN-1-YLETHANAMINE (S)-(-)-1-(1-Naphthyl)ethylamine, ChiPros 99+%, ee 99+% (S)-(-)-Alpha-(1-naphtyl)ethylamine, 99+%, (-)-1-[(S)-1-Aminoethyl]naphthalene (1S)-1-(1-Naphthyl)ethanamine (S)-α-Methylnaphthalene-1-methanamine (αS)-α-Methylnaphthalene-1-methanamine [S,(-)]-α-Methyl-1-naphthalenemethanamine (S)-(-)-1-(1-NAPHTHYL)ETHYLAMINE: CHIPROS 99%, EE 99% (S)-(-)-1-(1-NAPHTYL)ETHYLAMINE (S)-(-)-1-(1-Naphthyl)ethylamine ,98% (1S)-(-)-1-(Naphth-1-yl)ethylamine 1(S)-(-)-1-(1-Naphthyl)ethylaMine (S)-(-)-alpha-(1-Naphthyl)ethylaMine, 99+% 1GR 1-[(1S)-1-Aminoethyl]naphthalene (1S)-1-(naphthalen-1-yl)ethan-1-aMine L-A-(1-NAPHTHYL)ETHYLAMINE L-ALPHA-(ALPHA-NAPHTHYL)ETHYLAMINE (S)-(-)-1-(1-NAPHTHYL)ETHYLAMINE 99% (S)-(-)-alpha-(1-Naphthyl)ethylamine, 99+% (S)(-)-ALPHA-(1-NAPHTHYL)ETHYLAMINE (S)-(-)-ALPHA-(1-AMINOETHYL)NAPHTHALENE (S)-(-)-1-(1-NAPHTHYL)ETHYLAMINE (S) 1-(1-NAPTHYL)ETHYLAMINE (S)-(-)-A-(1-NAPHTHYL)ETHYLAMINE (S)-(-)-(1-Naphthyl)ethylamine (s)-1-naphthalenemethanamin (S)-alpha-Methyl-1-naphthalenemethanamine 1-(1-Naphthyl)ethanamine 1-Naphthalenemethanamine, alpha-methyl-, (S)- L-alpha-(1-Naphthyl)ethylamine, (-)- S-(-)-1-(alpha-Naphthyl)ethylamine 1-Naphthalenemethanamine, .alpha.-methyl-, (.alpha.S)- (s)-(-)-α-methyl-1-naphthalenemethylamine (S)-(-)-1-(Naphth-1-yl)ethylamine (S)-1-(1-naphthyl)ethylamine,99%e.e. Cinacalcet Impurity 35 [(1S)-1-(1-naphthalenyl)ethyl]ammonium Cinacalcet-22 (S)-1-(napthalen-1-yl)ethanmine (S)-(-)-1-(1-Naphthyl)ethylamine> (S)-(-)-1-(1-Naphthyl)ethylamine, 99%, reagent grade 1-Naphthalenemethanamine, α-methyl-, (αS)- (S)-(-)-1-(1-Naphthyl)ethylamine (Cinacalcet Impurity) (S)-1-(NAPHTHALEN-1-YL)ETHANAMINE (S)-1-(1-NAPHTHYL)ETHYLAMINE Cinacalcet Impurity 73 1-(naphthalen-1-yl)-N-((R)-1-(naphthalen-1-yl)ethyl)ethanamine 10420-89-0 Amines Analytical Chromatography Product Catalog Asymmetric Synthesis Chiral Derivatization Derivatization Reagents Organic Building Blocks Optical Resolution Enantiomer Excess & Absolute Conefiguration Determination e.e. / Absolute Conefiguration Determination (NMR)