TETRAPROPYLAMMONIUM PERRUTHENATE
- CAS No.
- 114615-82-6
- Chemical Name:
- TETRAPROPYLAMMONIUM PERRUTHENATE
- Synonyms
- TPAP;TETRA-N-PROPYLAMMONIUM PERRUTHENATE;Tetrapropylammonium tetraoxoruthenate;TerapropylaMMoniuMperruthenate;etrapropylammoniumperruthenate;TETRAPROPYLAMMONIUM PERRUTHENATE;TetrapropylaMMoniuM perruthenate 97%;tetrapropylammonium perruthenate(VII);Tetrapropylammonium Perruthenate (TPAP);TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII)
- CBNumber:
- CB4468073
- Molecular Formula:
- C12H28NO4Ru
- Molecular Weight:
- 351.43
- MDL Number:
- MFCD00074914
- MOL File:
- 114615-82-6.mol
- MSDS File:
- SDS
| Melting point | ~160 °C (dec.) (lit.) |
|---|---|
| storage temp. | Inert atmosphere,2-8°C |
| solubility | Methanol (Slightly) |
| form | crystal |
| color | green |
| Water Solubility | Insoluble in water. |
| Sensitive | Hygroscopic |
| Stability | store cold |
| InChIKey | NQSIKKSFBQCBSI-UHFFFAOYSA-N |
| FDA UNII | Y4N78L8V1T |
| UNSPSC Code | 12352116 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS03,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H272-H315-H319-H335 | |||||||||
| Precautionary statements | P210a-P405-P501a-P220-P261-P305+P351+P338-P210-P221-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P501 | |||||||||
| Hazard Codes | O,Xi | |||||||||
| Risk Statements | 5-8-36/37/38 | |||||||||
| Safety Statements | 17-26-36 | |||||||||
| RIDADR | UN 1479 5.1/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 3-10 | |||||||||
| HazardClass | 5.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28439000 | |||||||||
| NFPA 704 |
|
TETRAPROPYLAMMONIUM PERRUTHENATE price More Price(45)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 330744 | Tetrapropylammonium perruthenate 97% | 114615-82-6 | 250mg | $72.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 330744 | Tetrapropylammonium perruthenate 97% | 114615-82-6 | 1g | $252 | 2024-03-01 | Buy |
| TCI Chemical | T1559 | Tetrapropylammonium Perruthenate | 114615-82-6 | 1g | $93 | 2024-03-01 | Buy |
| TCI Chemical | T1559 | Tetrapropylammonium Perruthenate | 114615-82-6 | 5g | $270 | 2024-03-01 | Buy |
| Alfa Aesar | B24511 | Tetra-n-propylammonium perruthenate(VII) 98% | 114615-82-6 | 0.5g | $82 | 2024-03-01 | Buy |
TETRAPROPYLAMMONIUM PERRUTHENATE Chemical Properties,Uses,Production
Uses
A mild oxidant for the selective transformation of primary alcohols to aldehydes and secondary alcohols to ketones.
Chemical Properties
dark green solid
Uses
Tetrapropylammonium Perruthenate is used in sustainable oxidation reactions and has potential for chemical recycling.
Definition
ChEBI: A quaternary ammonium salt having tetrapropylammonium as the cation and perruthenate as the anion.
General Description
Tetrapropylammonium perruthenate is a mild oxidizing agent used for the oxidation of alcohols to corresponding carbonyl compounds. It is a non-volatile, air-stable, and readily soluble reagent, which can be used either stoichiometrically or catalytically with a suitable co-oxidant.
reaction suitability
reagent type: oxidant
Purification Methods
It is a strong oxidant and may explode on heating. It can be washed with aqueous n-propanol, then H2O and dried over KOH in a vacuum. It is stable at room temperature but best stored in a refrigerator. It is soluble in CH2Cl2 and MeCN. [Dengel et al. Transition Met Chem 10 98 1985, Griffith et al. J Chem Soc, Chem Commun 1625 1987.] § Polymer supported reagent is available commercially.
TETRAPROPYLAMMONIUM PERRUTHENATE Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29730 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21628 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 19825 | 58 |
| Wuhan Pengo Technology.,Ltd. | +86-27-81330736 +86-13628634921 | sunny.w@boronicgroup.com | CHINA | 171 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49732 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29808 | 58 |
| Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 +8613506123987 | marketing1@neostarunited.com | China | 8831 | 58 |
| Shanghai Daeyeon Chemicals Co., Ltd | 021-64478606 +8615900664856 | daeyeon001@vip.163.com | China | 2062 | 58 |
View Lastest Price from TETRAPROPYLAMMONIUM PERRUTHENATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-12-24 | TETRAPROPYLAMMONIUM PERRUTHENATE
114615-82-6
|
US $1.00 / KG | 1KG | 99% | 1000KGS | Career Henan Chemical Co |
-
- TETRAPROPYLAMMONIUM PERRUTHENATE
114615-82-6
- US $1.00 / KG
- 99%
- Career Henan Chemical Co