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Barium selenite

CAS No.
13718-59-7
Chemical Name:
Barium selenite
Synonyms
Bariumselenit;BARIUM SELENITE;barium(2+),selenite;bariumselenite99.8%;Selenious acid barium salt;seleniousacid,bariumsalt(1:1)
CBNumber:
CB4725754
Molecular Formula:
BaO3Se
Molecular Weight:
264.29
MDL Number:
MFCD00003446
MOL File:
13718-59-7.mol
Last updated:2023-10-17 17:11:53

Barium selenite Properties

solubility insoluble in H2O
form solid
Water Solubility g/100g solution H2O: 0.005 (0°C), 0.005 (25°C); solid phase, BaSeO3 [KRU93]
Exposure limits ACGIH: TWA 0.5 mg/m3; TWA 0.2 mg/m3
NIOSH: IDLH 50 mg/m3; IDLH 1 mg/m3; TWA 0.5 mg/m3; TWA 0.2 mg/m3
CAS DataBase Reference 13718-59-7(CAS DataBase Reference)
EPA Substance Registry System Selenious acid, barium salt (1:1) (13718-59-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08
Hazard statements  H300-H310-H330-H373
Precautionary statements  P301+P310a-P304+P340-P320-P330-P405-P501a
Hazard Codes  T,N
Risk Statements  23/24/25-50/53-33-23/25
Safety Statements  22-26-36/37/39-45-61-60-28-20/21
RIDADR  UN 2630 6.1/PG 1
WGK Germany  2
TSCA  Yes
HazardClass  6.1
PackingGroup  I
NFPA 704
0
4 0

Barium selenite price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Alfa Aesar A17451 Barium selenite, 97% 13718-59-7 100g $35.3 2021-12-16 Buy
Alfa Aesar A17451 Barium selenite, 97% 13718-59-7 500g $121 2021-12-16 Buy
Alfa Aesar A17451 Barium selenite 97% 13718-59-7 2500ml $531 2021-12-16 Buy
American Custom Chemicals Corporation ING0002455 BARIUM SELENITE 95.00% 13718-59-7 100G $2469.29 2021-12-16 Buy
American Custom Chemicals Corporation ING0002455 BARIUM SELENITE 95.00% 13718-59-7 500G $4396.22 2021-12-16 Buy
Product number Packaging Price Buy
A17451 100g $35.3 Buy
A17451 500g $121 Buy
A17451 2500ml $531 Buy
ING0002455 100G $2469.29 Buy
ING0002455 500G $4396.22 Buy

Barium selenite Chemical Properties,Uses,Production

Description

Barium selenite has the molecular formula of BaSeO3 and the molecular weight of 264.2865 g/mol. Its CAS number is 13718-59-7. It is a white solid that is insoluble in water. It can be prepared by the addition of sodium selenite to a solution of barium chloride:
BaCl2(aq)+ Na2SeO3(aq) ? BaSeO3(solid)
It can also be prepared by treating a solution of barium chloride with selenous acid and adding sodium carbonate to start precipitation. There is no record of a hydrate and the anhydrate is stable upon heating to over 950 °C.

Chemical Properties

solid [ALD93]

Physical properties

The heat of formation of barium selenite is: △fH298 - BaSeO3 = 2230.6 kcal/mol (—964.7 kJ/mol). The precipitate of barium selenite is not oxidized by air during drying at 110°C. In air, however, it oxidizes to the selenate at about 700–750°C:
2BaSeO3+ O2+ heat ? 2BaSeO4
Bariumselenite is a fine white crystalline powder that is mainly used in the glass industry to color and decolor glass.

Uses

Barium selenite is primarily chosen for producing special glass and leads to the formation of glass with high index of refraction. Barium selenite has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. Noncombustible, the substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes of SeO2.

Reactivity Profile

Barium selenite has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive. Noncombustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazard

Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.

Flammability and Explosibility

Not classified

Barium selenite Preparation Products And Raw materials

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Supplier Tel Email Country ProdList Advantage
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Guangdong Wengjiang Chemical Reagent Co., Ltd. 0751-2886766 13927870850 3001267247@qq.com China 9974 58
Selenious acid barium salt bariumselenite99.8% seleniousacid,bariumsalt(1:1) BARIUM SELENITE Bariumselenit barium(2+),selenite 13718-59-7 BaO3Se BaSeO3