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tert-Butyl(triphenylphosphoranylidene)acetate

CAS No.
35000-38-5
Chemical Name:
tert-Butyl(triphenylphosphoranylidene)acetate
Synonyms
TERT-BUTYL (TRIPHENYLPHOSPHORANYLIDENE)ACETATE;2-(triphenyL;Tert-Butyl (Triphen;LABOTEST-BB LT00233234;Triphenylphoranylidene;tert-butyl 2-(triphenyl-;ert-Butyl(triphenylphosphoranylidene)acetate;(Carbo-tert-butoxymethylene)triphenylphosphorane;tert-Butyl 2-tri(phenyl)phosphoranylideneacetate;(tert-butoxycarbonylmethylene)triphenyl-phosphora
CBNumber:
CB7199619
Molecular Formula:
C24H25O2P
Molecular Weight:
376.43
MDL Number:
MFCD00075545
MOL File:
35000-38-5.mol
MSDS File:
SDS
Last updated:2024-08-11 15:28:25

tert-Butyl(triphenylphosphoranylidene)acetate Properties

Melting point 152-155 °C(lit.)
Boiling point 503.5±33.0 °C(Predicted)
Density 1.203(20.0000℃)
storage temp. 2-8°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Crystalline Powder
color White
Water Solubility Sparingly soluble in water.
BRN 2759875
InChI InChI=1S/C24H25O2P/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22/h4-19H,1-3H3
InChIKey ZWZUFQPXYVYAFO-UHFFFAOYSA-N
SMILES C(OC(C)(C)C)(=O)C=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
CAS DataBase Reference 35000-38-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301-H317-H319-H373-H411
Precautionary statements  P273-P280-P301+P310+P330-P302+P352-P305+P351+P338-P314
Hazard Codes  T,N
Risk Statements  25-36-43-48/22-51/53
Safety Statements  26-36/37/39-45-61
RIDADR  UN 3464 6.1/PG 2
WGK Germany  3
HazardClass  6.1
PackingGroup  III
HS Code  29319090
NFPA 704
1
3 1

tert-Butyl(triphenylphosphoranylidene)acetate price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 369799 (tert-Butoxycarbonylmethylene)triphenylphosphorane 98% 35000-38-5 5g $118 2024-03-01 Buy
Sigma-Aldrich 369799 (tert-Butoxycarbonylmethylene)triphenylphosphorane 98% 35000-38-5 25g $184.8 2024-03-01 Buy
Alfa Aesar L15144 (tert-Butoxycarbonylmethylene)triphenylphosphorane, 98% 35000-38-5 5g $80.65 2024-03-01 Buy
Alfa Aesar L15144 (tert-Butoxycarbonylmethylene)triphenylphosphorane, 98% 35000-38-5 1g $29 2021-12-16 Buy
Alfa Aesar L15144 (tert-Butoxycarbonylmethylene)triphenylphosphorane, 98% 35000-38-5 25g $302 2024-03-01 Buy
Product number Packaging Price Buy
369799 5g $118 Buy
369799 25g $184.8 Buy
L15144 5g $80.65 Buy
L15144 1g $29 Buy
L15144 25g $302 Buy

tert-Butyl(triphenylphosphoranylidene)acetate Chemical Properties,Uses,Production

Chemical Properties

white crystalline powder

Uses

Wittig reagent used in the synthesis of aldose reductase inhibitors, a podophyllotoxin derivative, and tautomycin.
Versatile Wittig reagent used in medicinal chemistry.

Uses

(tert-Butoxycarbonylmethylene)triphenylphosphorane is a chemical used in the synthesis of aldose reductase inhibitors, a podophyllotoxin derivative and tautomycin, a podophyllotoxin derivative and tautomycin. It Is also used in medicinal chemistry.

Definition

ChEBI: Tert-butyl (triphenylphosphoranylidene)acetate is a phosphine.

tert-Butyl(triphenylphosphoranylidene)acetate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 183)Suppliers
Supplier Tel Email Country ProdList Advantage
Nanjing Bicbiotechnology Co., Ltd
+86-2552131256 +86-18251840740 sales@bicbiotech.com China 5994 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-81138252 +86-18789408387 1057@dideu.com China 3958 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12840 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29791 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32957 60
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29884 58
Hebei Weibang Biotechnology Co., Ltd
+8615531157085 abby@weibangbio.com China 8812 58
Xi'an Kono chem co., Ltd.,
029-86107037 13289246953 info@konochemical.com China 2993 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58

View Lastest Price from tert-Butyl(triphenylphosphoranylidene)acetate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
tert-Butyl(triphenylphosphoranylidene)acetate pictures 2024-08-11 tert-Butyl(triphenylphosphoranylidene)acetate
35000-38-5
US $1.00 / KG 1KG 99% 20T Shaanxi Dideu Medichem Co. Ltd
Tert-butyl (triphenylphosphoranylidene)acetate pictures 2024-04-25 Tert-butyl (triphenylphosphoranylidene)acetate
35000-38-5
US $5.00 / kg 1kg 99.92% 50000tons Ouhuang Engineering Materials (Hubei) Co., Ltd
tert-Butyl(triphenylphosphoranylidene)acetate pictures 2023-08-15 tert-Butyl(triphenylphosphoranylidene)acetate
35000-38-5
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
(tert-ButoxycarbonylMethylene)triphenylphosphorane, 97% 1GR (tert-ButoxycarbonylMethylene)triphenylphosphorane, 97% 5GR (tert-ButoxycarbonylMethylene)triphenylphosphorane 98% Acetic acid, 2-(triphenylphosphoranylidene)-, 1,1-diMethylethyl ester LABOTEST-BB LT00233234 (TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)-ACETIC ACID TERT-BUTYL ESTER (tert-butoxycarbonylmethylene)triphenyl-phosphora tert-Butyl (triphenylphosphoranylidene)acetate~(Carbo-tert-butoxymethylene)triphenylphosphorane TRIPHENYLPHORANYLIDENE ACETIC ACID 1,1-DIMETHYLETHYL ESTER (Carbo-tert-butoxymethylene)triphenylphosphorane Triphenylphoranylidene Acetic acid, (triphenylphosphoranylidene)-, 1,1-dimethylethyl ester (TERT-BUTOXYCARBONYLMETHYLENE)TRIPHENYLPHOSPHORANE (tert-butoxycarbonylmethylene)triphenylphosphorane, 98 % tert-Butyl 2-tri(phenyl)phosphoranylideneacetate (tert-Butoxycarbonylmethylene)triphenylphosphorane,97% Tert-Butyl (Triphen Triphenylthoranylidene acetic acid 1,1-dimethylethyl ester (tert-Butoxycarbonylmethylene)triphenylphosphorane ,94% tert-butyl 2-(triphenyl- TIANFU-CHEM - tert-Butyl(triphenylphosphoranylidene)acetate tert-butyl 2-(triphenyl-λ?-phosphanylidene)acetate ert-Butyl(triphenylphosphoranylidene)acetate 2-(triphenyL (tert-Butoxycarbonylmethylene)triphenylphosphorane, 97%, for synthesis (t-Butoxycarbonylmethylene)triphenylphosphorane:[t-Butyl(triphenylphosphoranylidene)acetate] TERT-BUTYL (TRIPHENYLPHOSPHORANYLIDENE)ACETATE 35000-38-5 CH33CO2CCHPC6H53 C6H53PCHCO2CCH33 C24H25O2P Synthetic Reagents Olefination Horner-Wadsworth-Emmons Reagents C-C Bond Formation API intermediates