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Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane

CAS No.
861445-91-2
Chemical Name:
Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane
Synonyms
Tris(trimethylsilyl)silyl vinyl ether;2-(Ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane;Trisilane, 2-(ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-;Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane
CBNumber:
CB72102941
Molecular Formula:
C11H30OSi4
Molecular Weight:
290.7
MDL Number:
MFCD11656064
MOL File:
861445-91-2.mol
Last updated:2023-07-17 08:27:58

Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Properties

Melting point 51-61 °C
Flash point 78 °C
storage temp. 2-8°C

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H319-H315-H335-H228
Precautionary statements  P264-P280-P302+P352-P321-P332+P313-P362-P210-P240-P241-P280-P370+P378-P264-P280-P305+P351+P338-P337+P313P
Hazard Codes  F,Xi
Risk Statements  11-36/37/38
Safety Statements  26-36/37
RIDADR  UN 1325 4.1/PG 3

Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
American Custom Chemicals Corporation ORS0000874 TRIS(TRIMETHYLSILYL)SILYL VINYL ETHER 95.00% 861445-91-2 1G $649.43 2021-12-16 Buy
American Custom Chemicals Corporation ORS0000874 TRIS(TRIMETHYLSILYL)SILYL VINYL ETHER 95.00% 861445-91-2 10G $1320.08 2021-12-16 Buy
Product number Packaging Price Buy
ORS0000874 1G $649.43 Buy
ORS0000874 10G $1320.08 Buy

Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Chemical Properties,Uses,Production

Uses

Super Silyl Protecting Groups

Used for:

  • Diastereoselective [2+2] cyclizations
  • Cross-Aldol cascade reaction
  • Diastereoselective sequential reactions for generating polyols
  • Accessing distinct diastereomers and 4-component reactions
  • Supersilyl-directed aldol reactions

  • Strong electron-donating effect of the supersilyl group operates only in the α-position and not in the β-position

1873-77-4
75-07-0
861445-91-2
Synthesis of Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane from TRIS(TRIMETHYLSILYL)SILANE and Acetaldehyde

Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Preparation Products And Raw materials

Raw materials

Preparation Products

Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Suppliers

Global( 6)Suppliers
Supplier Tel Email Country ProdList Advantage
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44700 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42959 64
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Baoji Didu Pharmaceutical and Chemical Co., Ltd 029-81148929 13186179623 1049@dideu.com China 10011 58
Tris(trimethylsilyl)silyl vinyl ether Tris(trimethylsilyl)silyloxyethylene, Vinyloxytris(trimethylsilyl)silane Trisilane, 2-(ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- 2-(Ethenyloxy)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane 861445-91-2 C11H30OSi4