DifluoroiodoMethyl phenyl sulfone
- CAS No.
- 802919-90-0
- Chemical Name:
- DifluoroiodoMethyl phenyl sulfone
- Synonyms
- DifluoroiodoMethyl phenyl sulfone;(difluoroiodomethylsulfonyl)benzene;Benzene, [(difluoroiodomethyl)sulfonyl]-
- CBNumber:
- CB82709840
- Molecular Formula:
- C7H5F2IO2S
- Molecular Weight:
- 318.08
- MDL Number:
- MFCD28100936
- MOL File:
- 802919-90-0.mol
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| Safety Statements | 24/25 |
| HS Code | 29309090 |
DifluoroiodoMethyl phenyl sulfone price More Price(10)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| AK Scientific | 8573AJ | Difluoroiodomethylphenylsulfone | 802919-90-0 | 250mg | $162 | 2021-12-16 | Buy |
| Frontier Specialty Chemicals | JK1711633 | Difluoroiodomethylphenylsulfone 98% | 802919-90-0 | 250mg | $72 | 2021-12-16 | Buy |
| AK Scientific | 8573AJ | Difluoroiodomethylphenylsulfone | 802919-90-0 | 1g | $358 | 2021-12-16 | Buy |
| Apolloscientific | PC911469 | [(Difluoroiodomethyl)sulfonyl]benzene 98% | 802919-90-0 | 1g | $475 | 2021-12-16 | Buy |
| Ambeed | A264821 | ((Difluoroiodomethyl)sulfonyl)benzene 98% | 802919-90-0 | 5g | $890 | 2021-12-16 | Buy |
DifluoroiodoMethyl phenyl sulfone Chemical Properties,Uses,Production
Description
A visible light-catalysed direct and regioselective (phenylsulfonyl) difluoromethylation of imidazo[1,2-A]pyridines and benzo[d]-imidazo[2,1-b]thiazoles was carried out by DifluoroiodoMethyl phenyl sulfone under mild conditions. This synthetic methodology enables the introduction of a CF2SO2Ph group in an efficient and regioselective reaction through C-H bond functionalization with a broad substrate scope in good to excellent yields.
Uses
Iododifluoromethyl phenyl sulfone can be used for the difluoromethylation of alkenes and alkynes initiated by triethylborane/air or arenediazonium salt/titanium chloride in moderate to good yields.
Reactions
(1) Difluoromethylation of terminal alkenes and alkynes.
References
[1] GUO-JIE YIN; W. F; Mei Zhu. Visible-light mediated regioselective (phenylsulfonyl)difluoromethylation of fused imidazoles with iododifluoromethyl phenyl sulfone[J]. Heterocyclic Communications, 2017. DOI:10.1515/hc-2017-0101.
[2] YA LI. Radical (Phenylsulfonyl)difluoromethylation with Iododifluoromethyl Phenyl Sulfone[J]. The Journal of Organic Chemistry, 2007. DOI:10.1021/jo070618s.
DifluoroiodoMethyl phenyl sulfone Preparation Products And Raw materials
Raw materials
Preparation Products
DifluoroiodoMethyl phenyl sulfone Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43348 | 58 |
| Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 52927 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Daicel Chiral Technologies (China)CO.,LTD | 021-50460086-9 15921403865 | han_yajun@dctc.daicel.com | China | 6943 | 65 |
| ShangHai YuanYe Biotechnology Co., Ltd. | 021-61312847 13636370518 | shyysw007@163.com | China | 4941 | 60 |
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| Shanghai potentpharm CO.,Ltd | 13524892556 | sales-cn@potentpharm.com | China | 1011 | 55 |
| Nanjing ShengSai Chemical Co., Ltd. | 025-85205967 13951876367 | shengsaichem@163.com | China | 811 | 58 |
| Bide Pharmatech Ltd. | 400-1647117 15221909166 | product02@bidepharm.com | China | 41438 | 60 |
| Shanghai Balmxy Pharmaceutical Co., Ltd | 021-24206007 13764915196 | sales@balmxy.com | China | 6751 | 55 |