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Silicon nitride

CAS No.
12033-89-5
Chemical Name:
Silicon nitride
Synonyms
Si3N4 SILICON NITRIDE;silicon(iv) nitride, electronic grade;E 05;E 10;β-Si3N4;α-Si3N4;SI3N4 B7;SI3N4 M11;ALPHA HYDROXY;E 05 (nitride)
CBNumber:
CB8744847
Molecular Formula:
N4Si3
Molecular Weight:
140.2833
MDL Number:
MFCD00011230
MOL File:
12033-89-5.mol
MSDS File:
SDS
Last updated:2024-07-30 17:43:28

Silicon nitride Properties

Melting point 1900 °C
Density 3.44 g/mL at 25 °C (lit.)
refractive index 2.8
RTECS VW0650000
form powder
color Pale gray
Specific Gravity 3.44
Resistivity 10*6 (ρ/μΩ.cm)
Water Solubility Insoluble water.
Crystal Structure Hexagonal
Hydrolytic Sensitivity 1: no significant reaction with aqueous systems
Merck 14,8497
Stability Stable.
CAS DataBase Reference 12033-89-5(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII QHB8T06IDK
EPA Substance Registry System Silicon nitride (Si3N4) (12033-89-5)

Silicon nitride Properties

Modulus of Elasticity 120 - 150 GPa
Poissons Ratio 0.20
Shear Modulus 50.0 - 62.5 GPa, Calculated
Hardness, Vickers 1600

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Hazard Codes  Xi
Risk Statements  37
Safety Statements  22-24/25
WGK Germany  3
10
TSCA  Yes
NFPA 704
0
0 0

Silicon nitride price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich NISTRM8983 Silicon nitride NIST? RM 8983 12033-89-5 4.5G $1130 2024-03-01 Buy
Sigma-Aldrich NIST1900 Silicon nitride powder - specific surface area standard NIST? SRM? 1900 12033-89-5 4g $743 2024-03-01 Buy
Sigma-Aldrich GF99991300 Silicon nitride powder, weight 200?g, 10 max. part. size (micron), condition alpha si3n4 (85% minimum) 12033-89-5 1EA $381 2024-03-01 Buy
Sigma-Aldrich 248622 Silicon nitride predominantly β-phase, ≤10micron primary particle size 12033-89-5 100g $108 2024-03-01 Buy
Sigma-Aldrich 248622 Silicon nitride predominantly β-phase, ≤10micron primary particle size 12033-89-5 500g $434 2024-03-01 Buy
Product number Packaging Price Buy
NISTRM8983 4.5G $1130 Buy
NIST1900 4g $743 Buy
GF99991300 1EA $381 Buy
248622 100g $108 Buy
248622 500g $434 Buy

Silicon nitride Chemical Properties,Uses,Production

Description

Silicon nitride (molecular formula Si3N4) is a kind of chemical compound comprised of both silicon and nitrogen elements. It appears as a white solid with a high melting point. It is chemically stable upon the presence of dilute HF and hot H2SO4. It has a series of properties such as high strength among a wide temperature range, high fracture toughness, high hardness, outstanding wear resistance and chemical property. It has a strikingly high thermal shock resistance. It has a wide applications in various kinds of fields. In automobile industry, it is an important materials for engine parts. It can also be applied to the manufacturing of bearings due to its high shock resistance. For example, in spacecraft, silicon nitride ceramic is capable of surviving the severe thermal shock generated in the hydrogen/oxygen rocket engines. It can also be used as abrasive and cutting tools due to its harness and resistance to wear. In electronics, it can be used as an insulator and chemical barrier during the production of integrated circuits. There are several method for the manufacturing the silicon nitride. 1. The powdered silicon is subject to a heating reaction of 1300-1400 °C in the atmosphere of nitrogen. 2 Diimide route which involves the reaction of SiCl and NH3. 3 Silicon dioxide is subject to carbothemral reduction at 1300-1400 °C under the presence of nitrogen.

References

https://en.wikipedia.org/wiki/Silicon_nitride
http://accuratus.com/silinit.html

Chemical Properties

slightly beige powder

Physical properties

Gray amorphous powder or crystals. Resistant to thermal shock. Good oxidation resistance up to 1500°C but decomposes into nitrogen and silicon above 1850°C. Excellent corrosion resistance to molten nonferrous metals such as Al, Pb, Zn, Cd, Bi, Rb, and Sn, and molten salts like NaCl-KCl, NaF, and silicate glasses. However, corroded by molten Mg, Ti, V, Cr, Fe, and Co, cryolite, KOH, and Na2 O.

Uses

As high tempereture engineering material for use in gas turbines, diesel engines.

Uses

Silicon Nitride is used in preparation of thermal conductive Poly(Me Methacrylate)/Silicon Nitride nanocomposites via click chemistry.

Uses

Silicon nitride (Si3N4), resistant to oxidation, is an excellent coating for metals, as well as an adhesive and abrasive, and it is used in high-temperature crucibles. It has proven useful as heat-resistant substance for the nozzles on rocket engines.

General Description

Silicon nitride based ceramics possess high fracture toughness, hardness and wear resistance, resistance to corrosion, thermal stability. Two known polymorphs of silicon nitride exist, alpha and beta Si3N4, both have hexagonal structure. A study shows that a third state, cubic spinel structure, has also been synthesized.

Flammability and Explosibility

Non flammable

Silicon nitride Preparation Products And Raw materials

Global( 223)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Andu Technology Com.,Ltd
+86-86-17798073498 +8617798073498 admin@hbandu.com China 299 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29885 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22963 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 13515 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17365 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34553 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167 1026@dideu.com China 7724 58

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View Lastest Price from Silicon nitride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Silicon nitride pictures 2024-11-14 Silicon nitride
12033-89-5
US $3.60 / kg 1kg ≥99% 3000tons/month Hebei Andu Technology Com.,Ltd
Silicon nitride pictures 2022-10-18 Silicon nitride
12033-89-5
US $0.00 / kg 1kg 99% 20ton/month Sense Chemicals (Shanghai) Co., Ltd.
Silicon nitride pictures 2022-09-27 Silicon nitride
12033-89-5
US $0.00 / kg 1kg 99% 1000kg henan kanbei chemical co.,ltd
  • Silicon nitride pictures
  • Silicon nitride
    12033-89-5
  • US $3.60 / kg
  • ≥99%
  • Hebei Andu Technology Com.,Ltd
  • Silicon nitride pictures
  • Silicon nitride
    12033-89-5
  • US $0.00 / kg
  • 99%
  • Sense Chemicals (Shanghai) Co., Ltd.

Silicon nitride Spectrum

Silicon(IV) nitride, Electronic Grade, 99.85% (Metals basis), 90+% ^a-phase Silicon nitrid Denka Silicon Nitride SN-F 2 E 05 E 05 (nitride) E 10 E 10 (nitride) Silicon nitride powder, >=99.9% trace Metals basis Silicon nitride predoMinantly alpha-phase, -325 Mesh Silicon nitride predoMinantly beta-phase, -325 Mesh Silicon nitride Nanopowder<50NM SILICON (IV) NITRIDE ALPHA PHASE Silicon IV nitride Powder SILICON NITRIDE Siliconnitridemeshlightgraypowder Siliconnitridepowderprimarilyphase trisilicon tetranitride SILICON NITRIDE, NANOPOWDER, 98.5+% SILICON NITRIDE, POWDER, SUBMICRON, 99.9 +% SILICON NITRIDE, -325 MESH, PREDOMINANTL Y ALPHA-PHASE SILICON NITRIDE, -325 MESH, PREDOMINANTL Y BETA-PHASE SILICON NITRIDE, NANOPOWDER, 98+% SILICON NITRIDE B-PHASE SILICON NITRIDE A-PHASE alpha-Silicon nitride Silicon(IV) nitride, 99.3% (metals basis), typically 90% β-phase Silicon(IV) nitride, Electronic Grade, 99.85% (metals basis), 94% ɑ-phase Silicon(IV) nitride, ɑ-phase, 99.9% (metals basis) Silicon(IV) nitride, ɑ-phase, 95% Silicon(IV) nitride, MgO binder, sputtering target, 50.8mm (2.0in) dia x 3.18mm (0.125in) thick, 99.9% (metals basis) Silicon(IV) nitride, MgO binder, sputtering target, 76.2mm (3.0in) dia x 3.18mm (0.125in) thick, 99.9% (metals basis) Silicon(IV) nitride, amorphous, 96+% Silicon(IV)nitride,<5micron(99%-Si) silicon (iv) nitride, amorphous MILLEDSILICONNITRIDE NONFIBROUSSILICONNITRIDE FIBROUSSILICONNITRIDE SILICONNITRIDEWHISKERS SILICON NITRIDE GRADE ST <10M, A PRODUCT OF H.C. STARCK SILICON NITRIDE , -200 MESH SI3N4 B7 SILICON NITRIDE GRADE B7 - A PRODUCT OF H.C. STARCK SI3N4 M11 SILICON NITRIDE GRADE M11 - A PRODUCT OF H.C. STARCK SILICON NITRIDE GRADE S <10M, A PRODUCT OF H.C. STARCK SILICON NITRIDE, POWDER, PRIMARILY ALPHA-PHASE SILICON NITRIDE, GRADE M11 HIGHER PURITY Silicon nitride (Si3N4) Silicon(Ⅳ) Nitride Silicon(IV) nitride, amorphous, 98.5+% Silicon(IV) nitride, alpha-phase (metals basis) Silicon nitride powder (Si3N4) SI3N4 B7 SI3N4 M11 SILICON (IV) NITRIDE Silicon(IV) nitride, MgO binder, sputtering target, 50.8mm (2.0in) dia x 6.35mm (0.250in) thick, 99.9% (metals basis) Silicon(IV) nitride, MgO binder, sputtering target, 76.2mm (3.0in) dia x 6.35mm (0.250in) thick, 99.9% (metals basis) Silicon(IV) nitride, 99.3% (metals basis), typically 90% beta phase Silicon(IV) nitride, alpha phase, 99.9% (metals basis) Silicon(IV) nitride, Electronic Grade, 99.85% (metals basis), 94% alpha phase