Isobornyl acrylate
- CAS No.
- 5888-33-5
- Chemical Name:
- Isobornyl acrylate
- Synonyms
- iboa;IBXA;exo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate;sr506;ebecryliboa;(1R,2R,4R)-rel-1,7,7-TriMethylbicyclo[2.2.1]heptan-2-yl acrylate;qm589;EM70DN;sartomer506;al-co-cureiba
- CBNumber:
- CB9327469
- Molecular Formula:
- C13H20O2
- Molecular Weight:
- 208.3
- MDL Number:
- MFCD00080424
- MOL File:
- 5888-33-5.mol
| Melting point | <-35°C |
|---|---|
| Boiling point | 119-121 °C15 mm Hg(lit.) |
| Density | 0.986 g/mL at 25 °C(lit.) |
| vapor pressure | 1.3Pa at 20℃ |
| refractive index |
n |
| Flash point | 207 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Viscosity | 9cp (25C) |
| Water Solubility | Difficult to mix in water. |
| FreezingPoint | 5 |
| Sensitive | Light Sensitive |
| BRN | 2254825 |
| Stability | Light sensitive |
| InChIKey | PSGCQDPCAWOCSH-BREBYQMCSA-N |
| LogP | 4.52 at 20℃ |
| CAS DataBase Reference | 5888-33-5(CAS DataBase Reference) |
| EWG's Food Scores | 2-5 |
| FDA UNII | IX0PRH184P |
| EPA Substance Registry System | Isobornyl acrylate (5888-33-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H317-H319-H335-H410 | |||||||||
| Precautionary statements | P261-P264-P273-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xn,N,Xi | |||||||||
| Risk Statements | 20/22-36/37/38-51/53 | |||||||||
| Safety Statements | 26-36-61-28 | |||||||||
| RIDADR | UN 3082 9 / PGIII | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | UD3940000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 9 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29161290 | |||||||||
| Toxicity | LD50 oral in rat: 4890mg/kg | |||||||||
| NFPA 704 |
|
Isobornyl acrylate price More Price(24)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 392103 | Isobornyl acrylate technical grade, contains 200 ppm monomethyl ether hydroquinone as inhibitor | 5888-33-5 | 100ml | $52.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 392103 | Isobornyl acrylate technical grade, contains 200 ppm monomethyl ether hydroquinone as inhibitor | 5888-33-5 | 1l | $225 | 2024-03-01 | Buy |
| TCI Chemical | I0638 | Isobornyl Acrylate (stabilized with MEHQ) >90.0%(GC) | 5888-33-5 | 25g | $27 | 2024-03-01 | Buy |
| TCI Chemical | I0638 | Isobornyl Acrylate (stabilized with MEHQ) >90.0%(GC) | 5888-33-5 | 500g | $104 | 2024-03-01 | Buy |
| Alfa Aesar | L09977 | Isobornyl acrylate, tech. 85%, stab. with 100ppm 4-methoxyphenol | 5888-33-5 | 250g | $69.3 | 2024-03-01 | Buy |
Isobornyl acrylate Chemical Properties,Uses,Production
Description
Isobornyl acrylate can be used to prepare block copolymers with n-butyl acrylate by atom transfer radical polymerization (ATRP)1. It is a photo-polymerizable monomer that is employed in micro-fluidic devices because of desirable properties, such as inertness, transparency, and resolution2.
Sources
- https://www.sigmaaldrich.com/catalog/product/aldrich/392103?lang=en®ion=US
- López-García, M. D. C., D. J. Beebe, and W. C. Crone. Characterization of poly(isobornyl acrylate) as a construction material for microfluidic applications. Journal of Applied Polymer Science. 2007:1894–1902.
Uses
Isobornyl acrylate (IBA) is used as UVcuring EBcuring adhesive, it can also be used to prepare block copolymers with n-butyl acrylate by atom transfer radical polymerization (ATRP).
Application
Isobornyl acrylate can be used as a co-monomer with other acrylic monomers in the preparation of pressure-sensitive adhesives (PSAs) for optical applications. It is also used in the development of high-performance and stable polymer gate dielectrics for organic thin-film transistors (OTFTs). Furthermore, it can also used in the preparation of UV-curable waterborne polyurethane (WPU) by copolymerization.
Hazard
Moderately toxic by ingestion. Low toxicity by skin contact. A moderate skin and mild eye irritant.
Flammability and Explosibility
Non flammable
Synthesis
Isobornyl acrylate is prepared by reacting (-)- borneol,triethylamine with acryloyl chloride in anhydrous THF.Dissolve (-)- borneol (1.00 g, 6.48 mmol, 1 equiv) and triethylamine (0.98 g, 9.72 mmol, 1.5 equiv) in anhydrous THF (20 mL) in a 100 mL round-bottom flask. Add acryloyl chloride (0.88 g, 9.72 mmol, 1.5 equiv) dropwise to the reaction mixture at 0 °C. Allow the reaction to stir at room temperature overnight. Filter the reaction solution. Concentrate the reaction solution on the rotary evaporator. Wash the mixture with water (20 mL). Extract the mixture with dichloromethane (3x20 mL). Dry the combined organic phases over anhydrous sodium sulfate. Filter and concentrate the residue. Purify the crude product further by silica gel column chromatography (petroleum ether/ethyl acetate = 4:1) to obtain isobornyl acrylate.
Fig Synthetic method of Isobornyl acrylate
Isobornyl acrylate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Anhui Royal Chemical Co., Ltd. | +86-25-86655873 +8613962173137 | marketing@royal-chem.com | China | 193 | 55 |
| Yancheng Green Chemicals Co.,Ltd | +undefined-86-25-86655873 | info@royal-chem.com | China | 114 | 58 |
| Gansu Jinyuantai New Material Co., Ltd. | +86-025-86618065 +86-13914714331 | sales@jinyuantaichem.com | China | 73 | 58 |
| Hubei Ipure Biology Co., Ltd | +8613367258412 | ada@ipurechemical.com | China | 10319 | 58 |
| Qingdao RENAS Polymer Material Co., Ltd. | +86-0532-86867058 +86-18562606086 | sales@qdrenas.com | China | 476 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8808 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12834 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5889 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20284 | 58 |
| Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | admin@zlchemi.com | China | 3002 | 58 |
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View Lastest Price from Isobornyl acrylate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-12-23 | Isobornyl acrylate
5888-33-5
|
US $2.00 / kg | 1kg | 99% | 5000mt | Jinan Finer Chemical Co., Ltd | |
 |
2024-12-23 | Bornylacrylate
5888-33-5
|
US $70.00 / kg | 1kg | 99 | 5000 | Hebei Zhuanglai Chemical Trading Co.,Ltd | |
 |
2024-12-23 | Acrylic acid isobornyl ester
5888-33-5
|
US $70.00 / kg | 1kg | 99 | 5000 | Hebei Zhuanglai Chemical Trading Co.,Ltd |
-
- Isobornyl acrylate
5888-33-5
- US $2.00 / kg
- 99%
- Jinan Finer Chemical Co., Ltd
-
- Bornylacrylate
5888-33-5
- US $70.00 / kg
- 99
- Hebei Zhuanglai Chemical Trading Co.,Ltd
-
- Acrylic acid isobornyl ester
5888-33-5
- US $70.00 / kg
- 99
- Hebei Zhuanglai Chemical Trading Co.,Ltd