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4-Nitrobenzo-15-crown-5

4-Nitrobenzo-15-crown-5 structure

CAS No.: 60835-69-0

Chemical Name:: 4-Nitrobenzo-15-crown-5

Synonyms: NITROBENZO-15-CROWN-5;4-Nitrobenzo-15-crown-5;4'-Nitrobenzo-15-crown-5;Nitrobenzo-15-crown-5,99%;4-nitryl-benzo-15-crown-5;4-Nitrobenzo-15-crown-5,99%;4'-Nitrobenzo-15-crown 5-Ether;4'-Nitrobenzo-15-crown 5-Ether;4'-Nitrobenzo-15-crown5-Ether>4- Nitrobenzene -15- crown ether -5

CBNumber:: CB9439728

Molecular Formula:: C14H19NO7

Molecular Weight:: 313.3

MDL Number:: MFCD00060713

MOL File:: 60835-69-0.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-11-04 17:04:01

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4-Nitrobenzo-15-crown-5 Properties

Melting point	93-97 °C(lit.)
Boiling point	453.11°C (rough estimate)
Density	1.191
refractive index	1.5230 (estimate)
storage temp.	Store below +30°C.
solubility	It is soluble in non-polar solvents.
form	powder to crystal
color	Light orange to Yellow to Green
BRN	1598970
InChI	InChI=1S/C14H19NO7/c16-15(17)12-1-2-13-14(11-12)22-10-8-20-6-4-18-3-5-19-7-9-21-13/h1-2,11H,3-10H2
InChIKey	XIWRBQVYCZCEPG-UHFFFAOYSA-N
SMILES	O1C2=CC=C([N+]([O-])=O)C=C2OCCOCCOCCOCC1
CAS DataBase Reference	60835-69-0(CAS DataBase Reference)
Comptox DTXSID	DTXSID90209686
UNSPSC Code	12352005
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a

PPE

dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36

WGK Germany

HazardClass

IRRITANT

HS Code

29329985

Storage Class

11 - Combustible Solids

NFPA 704

	0
2		0

4-Nitrobenzo-15-crown-5 price More Price(26)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	341878	4′-Nitrobenzo-15-crown-5 99%	60835-69-0	1g	$50.9	2023-01-07	Buy
TCI Chemical	N0561	4'-Nitrobenzo-15-crown 5-Ether >99.0%(GC)	60835-69-0	1g	$135	2026-04-30	Buy
TCI Chemical	N0561	4'-Nitrobenzo-15-crown 5-Ether >99.0%(GC)	60835-69-0	5g	$406	2026-04-30	Buy
Apolloscientific	OR10924	15-Nitro-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine 99%	60835-69-0	1g	$44	2026-06-04	Buy
Apolloscientific	OR10924	15-Nitro-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine 99%	60835-69-0	5g	$172	2026-06-04	Buy

Product number	Packaging	Price	Buy
341878	1g	$50.9	Buy
N0561	1g	$135	Buy
N0561	5g	$406	Buy
OR10924	1g	$44	Buy
OR10924	5g	$172	Buy

4-Nitrobenzo-15-crown-5 Chemical Properties, Uses, Production

Chemical Properties

LIGHT YELLOW GRANULAR POWDER

Uses

4-Nitrobenzo-15-crown-5 is a raw material used in synthesis as well as an intemediate in chemical syntheis and pharmaceutica intemediate. It is also used to separate cations, dissolve inorganic salts into organic solvents to perform naked anion chemistry, serve as phase transfer catalysts, and chiral crown ethers have been used to resolve racemic mixtures or separate isomers by chiral chromatography.

Purification Methods

Recrystallise the crown ether from EtOH, MeOH or *C6H6/hexane as for the 18-crown-6 compound below. It complexes with Na+, K+, NH4+, Ca2+, Mg2+ and Cd2+. The 1HNMR spectrum (CDCl3) has (ppm): 3.6-4.4 (m 16CH2), 6.8 (d 1H arom), 7.65 (d 1H arom), 7.80 (dd 1H arom Jab 9Hz and Jbc 3Hz) [Schmid et al. J Am Chem Soc 98 5198 1976, Kikukawa et al. Bull Chem Soc Jpn 50 2207 1977, Toke et al. Justus Liebigs Ann Chem 349 349, 761 1988, Lindner et al. Z Anal Chem 322 157 1985].

4-Nitrobenzo-15-crown-5 synthesis

Synthesis of 4-Nitrobenzo-15-crown-5 from Benzo-15-crown-5

4-Nitrobenzo-15-crown-5 Preparation Products And Raw materials

Raw materials

Diethylene glycol bis(2-chloroethyl) ether Benzo-15-crown-5

Preparation Products

4'-Amino-5'-nitrobenzo-15-crown-5

4-Nitrobenzo-15-crown-5 Suppliers

Global Suppliers ( 144)

Supplier	Tel	Email	Country	ProdList	Advantage
Bide Pharmatech Ltd.	400-6005915	sales@picasso-e.com	China	39645	58
J & K SCIENTIFIC LTD.	18210857532 18210857532	jkinfo@jkchemical.com	China	96815	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006356688 18621169109	market03@meryer.com	China	40202	62
Alfa Aesar	400-6106006	saleschina@alfa-asia.com	China	30103	84
TCI (Shanghai) Development Co., Ltd.	021-67121386	Sales-CN@TCIchemicals.com	China	24512	81
Beijing HwrkChemical Technology Co., Ltd	89508211 18501085097	sales.bj@hwrkchemical.com	China	9409	55
Energy Chemical	400-0056266	sales8178@energy-chemical.com	China	44567	61
Shanghai Hanhong Scientific Co.,Ltd.	021-54306202 13764082696	info@hanhongsci.com	China	42917	64
Sichuan Kulinan Technology Co., Ltd	400-1166-196 18981987031	cdhxsj@163.com	China	11674	57
Tianjin heowns Biochemical Technology Co., Ltd.	400 638 7771	sales@heowns.com	China	14412	57

Supplier	Advantage
Bide Pharmatech Ltd.	58
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Alfa Aesar	84
TCI (Shanghai) Development Co., Ltd.	81
Beijing HwrkChemical Technology Co., Ltd	55
Energy Chemical	61
Shanghai Hanhong Scientific Co.,Ltd.	64
Sichuan Kulinan Technology Co., Ltd	57
Tianjin heowns Biochemical Technology Co., Ltd.	57

View Latest Price from 4-Nitrobenzo-15-crown-5 manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2026-08-25	4'-Nitrobenzo-15-crown-5 60835-69-0	$3.00-9.00		99%		ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

4'-Nitrobenzo-15-crown-5
60835-69-0
$3.00-9.00
99%
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

4-Nitrobenzo-15-crown-5 Spectrum

4-NITROBENZO-15-CROWN-5(60835-69-0)¹HNMR 4-NITROBENZO-15-CROWN-5(60835-69-0)¹³CNMR 4-NITROBENZO-15-CROWN-5(60835-69-0)IR1 4-NITROBENZO-15-CROWN-5(60835-69-0)Raman

60835-69-0 (4-Nitrobenzo-15-crown-5) Related Search:

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1of4

2,3,5,6,8,9,11,12-Octahydro-15-nitro-1,4,7,10,13-benzopentaoxacyclopentadecin CROWN ETHER/4'-NITROBENZO-15-CROWN-5 FOR Crown ether/4'-Nitrobenzo-15-crown-5 for synthesis 15-Nitro-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine 17-Nitro-2,3-benzo-1,4,7,10,13-pentaoxacyclopentadecen-2 NITROBENZO-15-CROWN-5 CROWN ETHER/4'-NITROBENZO-15-CROWN-5 2,3-(4-NITROBENZO)-1,4,7,10,13-PENTAOXACYCLOPENTADEC-2-ENE CARBON DISULFIDE, REAGENTPLUS, >=99.9%, LOW BENZENE 4-Nitrobenzo-15-crown-5,99% 1,4,7,10,13-Benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-15-nitro- 1,13-(4-Nitro-1,2-phenylene)-1,4,7,10,13-pentaoxatridecane 1,2-(1,4,7,10,13-Pentaoxatridecane-1,13-diyl)-4-nitrobenzene 15-Nitro-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin 16-Nitro-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin Nitrobenzo-15-crown-5,99% 4-nitryl-benzo-15-crown-5 17-nitro-2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene 4'-Nitrobenzo-15-crown5-Ether> 4- Nitrobenzene -15- crown ether -5 4'-Nitrobenzo-15-crown 5-Ether 4'-Nitrobenzo-15-crown-5 4'-Nitrobenzo-15-crown 5-Ether 15-nitro-2,3,5,6,8,9,11,12-octahydrobenzo[b][1,4,7,10,13]pentaoxacyclopentadecine 4-Nitrobenzo-15-crown-5 60835-69-0 33408-96-1 C14H19NO7 Macrocycles for Host-Guest Chemistry Crown Ethers Synthetic Reagents Chelation/Complexation Compounds Synthetic Reagents Crown Ethers Chelation/Complexation Compounds Macrocycles for Host-Guest Chemistry Functional Materials Crown Ethers