Salicylaldoxime
- CAS No.
- 94-67-7
- Chemical Name:
- Salicylaldoxime
- Synonyms
- icyL;Saldox;doxime;Sal-dox;2-(βSalicyladoxime;SALICYLALDOXIME;SalicyladoximeGr;SALICYLADOXIME AR;Salicaldehyde oxime
- CBNumber:
- CB0112910
- Molecular Formula:
- C7H7NO2
- Molecular Weight:
- 137.14
- MOL File:
- 94-67-7.mol
- Modify Date:
- 2024/5/27 15:57:40
| Melting point | 57-59 °C 59-61 °C (lit.) |
|---|---|
| Boiling point | 251.96°C (rough estimate) |
| Density | 1.2528 (rough estimate) |
| refractive index | 1.5030 (estimate) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | sparingly soluble in water, soluble in ethanol, diethyl ether, acetone, benzene. |
| form | Powder |
| pka | pK1:1.37(＋1);pK2:9.18;pK3:12.11 (25°C) |
| color | Bordeaux to purple-red |
| Odor | Odorless |
| Water Solubility | Slightly soluble in water |
| Merck | 14,8327 |
| BRN | 1859881 |
| InChIKey | ORIHZIZPTZTNCU-VMPITWQZSA-N |
| CAS DataBase Reference | 94-67-7(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzaldehyde, 2-hydroxy-, oxime(94-67-7) |
| EPA Substance Registry System | Benzaldehyde, 2-hydroxy-, oxime (94-67-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H319-H335 | |||||||||
| Precautionary statements | P301+P312+P330-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 22-36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | VN5775000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29280000 | |||||||||
| NFPA 704 |
|
Salicylaldoxime price More Price(9)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 84172 | Salicylaldoxime ≥98.0% (NT) | 94-67-7 | 100G | ₹13866.83 | 2022-06-14 | Buy |
| ALFA India | ALF-A11080-36 | Salicylaldoxime, 98% | 94-67-7 | 500g | ₹33756 | 2022-05-26 | Buy |
| TCI Chemicals (India) | S0005 | Salicylaldoxime min. 98.0 % | 94-67-7 | 25G | ₹2400 | 2022-05-26 | Buy |
| ALFA India | ALF-A11080-22 | Salicylaldoxime, 98% | 94-67-7 | 100g | ₹12823 | 2022-05-26 | Buy |
| TCI Chemicals (India) | S0005 | Salicylaldoxime min. 98.0 % | 94-67-7 | 500G | ₹27800 | 2022-05-26 | Buy |
Salicylaldoxime Chemical Properties,Uses,Production
Chemical Properties
off-white to light beige crystalline powder
Uses
Salicylaldoxime reacts with several metal ions to give intensively coloured
complexes which are insoluble in water. The structure of the copper(II), nickel(II)
and palladium(II) complexes is shown in Fig. 14 (structure I), and that of the
manganese(II), iron(II), cobalt(II) and zinc(II) complexes in Fig. 14 (structure
II). The copper(Il) and palladium(II) salicylaldoxime complexes are of importance
from an analytical point of view. The complexes precipitated from aqueous
media are easily filterable and washable and are weighed after drying at 100°C.
The precipitates are of stoichiometric composition.
The outstanding stabilities of the copper(II) and palladium(II) complexes
make the reagent suitable for the selective determination of these metal ions.
These two complexes form quantitatively at low pH values where the complexes
of other metal ions do not exist.
Besides the gravimetric method, salicylaldoxime is also useful in the volumetric,
amperometric and nephelometric determinations of copper and palladium.
Salicylaldoxime gives a black precipitate with VOs~ in media containing sulfuric
acid; this is soluble in chloroform to give an orange solution. The reaction is
specific for vanadium which can thus be detected by this method in the presence
of almost all other metals.
In neutral medium salicylaldoxime reacts with iron(III) to give a red complex
which is soluble in water. The reaction is utilized for the detection of micro
amounts of iron.
Salicylaldoxime Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
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| DeFINE CHEMICALS | +91-8010769889 +91-9320057099 | Maharashtra, India | 120 | 58 | Inquiry |
| Sree Kannika Scientific Supplies Co. | 08048372558Ext 785 | Karnataka, India | 7 | 58 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6351 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
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