cis-3-Hexenyl formate
- CAS No.
- 33467-73-1
- Chemical Name:
- cis-3-Hexenyl formate
- Synonyms
- FORMIC ACID CIS-3-HEXEN-1-YL ESTER;FEMA 3353;C3 HEXENYL FORMATE;3Z-Hexenyl Formate;Formicacidhexenester;HEXENYLFORMIAT-CIS-3;CIS-3-HEXENYL FORMATE;(Z)-3-HEXENOL FORMATE;(Z)-3-HEXENYL FORMATE;(Z)-Hex-3-enylformiat
- CBNumber:
- CB0190859
- Molecular Formula:
- C7H12O2
- Molecular Weight:
- 128.17
- MOL File:
- 33467-73-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/7/22 15:01:55
| Melting point | -62.68°C (estimate) |
|---|---|
| Boiling point | 72 °C/40 mmHg (lit.) |
| Density | 0.91 g/mL at 25 °C(lit.) |
| refractive index |
n |
| FEMA | 3353 | CIS-3-HEXENYL FORMATE |
| Flash point | 113 °F |
| solubility | Almost insoluble in water, soluble in alcohol, Propylene glycol and oils. |
| form | liquid |
| Specific Gravity | 0.92 |
| color | Colorless |
| Odor | at 10.00 % in dipropylene glycol. fresh green waxy sweet vegetable grassy sharp |
| Odor Type | green |
| JECFA Number | 1272 |
| LogP | 2.10 |
| CAS DataBase Reference | 33467-73-1(CAS DataBase Reference) |
| NIST Chemistry Reference | 3-Hexen-1-ol, formate, (z)-(33467-73-1) |
| EPA Substance Registry System | 3-Hexen-1-ol, formate, (3Z)- (33467-73-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H226-H315-H319 |
| Precautionary statements | P210-P302+P352-P305+P351+P338 |
| Hazard Codes | Xi |
| Risk Statements | 10-36/38 |
| Safety Statements | 16-26-36 |
| RIDADR | UN 3272 3/PG 3 |
| WGK Germany | 2 |
| RTECS | MP8550000 |
cis-3-Hexenyl formate Chemical Properties,Uses,Production
Description
cis-3-Hexenyl formate has a light topnote and a fruity fresh odor.
Chemical Properties
(Z)-3-Hexenyl Formate has been identified in tea. It possesses a green, fruity odor and is used in perfumery and flavor compositions to impart fruity, green notes.
Occurrence
Reported found in raspberry, corn mint oil, black tea, mango, corn oil and black chokeberry.
Uses
cis-3-Hexenyl formate finds some use in perfumery as part of various topnote complexes. It blends very well with Galbanum and with many herbaceous oils. Styrax is a good fixative, and supporting fixation and blending can be achieved with Cinnamates. The ester could constitute the main part of the green theme in Hyacinth when suitably incorporated. In flavors, it forms an excellent combination with Nonadienal and Nonadienol in Cucumber compositions and other vegetable, juicygreen flavor types. It is furthermore a generally refreshing modifier for the higher esters of the series.
Preparation
from cis-3-Hexenol and Formic acid, e. g. in presence of Acetic arrhydride in cold Formulation.
General Description
cis-3-Hexenyl formate is a flavor and fragrance ester mainly used for its green notes. It occurs naturally in gardenia and zinchoge flowers.
cis-3-Hexenyl formate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| JINING XINHE CHEMICAL CO., LTD | +8615318402391 | China | 807 | 58 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29896 | 58 | Inquiry |
| Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 | China | 2995 | 58 | Inquiry |
| SIMAGCHEM CORP | +86-13806087780 | China | 17367 | 58 | Inquiry |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | China | 34571 | 58 | Inquiry |
| Dideu Industries Group Limited | +86-29-89586680 +86-15129568250 | China | 24330 | 58 | Inquiry |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | China | 52861 | 58 | Inquiry |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | China | 49999 | 58 | Inquiry |
| Hebei Kingfiner Technology Development Co.Ltd | +86-15532196582 +86-15373005021 | China | 2989 | 58 | Inquiry |
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