Leaf alcohol
- CAS No.
- 928-96-1
- Chemical Name:
- Leaf alcohol
- Synonyms
- CIS-3-HEXENOL;(Z)-3-Hexen-1-ol;CIS-3-HEXEN-1-OL;(Z)-Hex-3-en-1-ol;(3Z)-3-Hexen-1-ol;Z-3-Hexenol;cis-Hex-3-en-1-ol;FEMA 2563;(z)-3-hexen-1-o;C3 LEAF ALCOHOL
- CBNumber:
- CB8723819
- Molecular Formula:
- C6H12O
- Molecular Weight:
- 100.16
- MOL File:
- 928-96-1.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/12/18 14:15:32
| Melting point | 22.55°C (estimate) |
|---|---|
| Boiling point | 156-157 °C(lit.) |
| Density | 0.848 g/mL at 25 °C(lit.) |
| vapor density | 3.45 (vs air) |
| vapor pressure | 2.26hPa at 25℃ |
| refractive index |
n |
| FEMA | 2563 | CIS-3-HEXENOL |
| Flash point | 112 °F |
| storage temp. | Flammables area |
| solubility | DMSO: 100 mg/mL (998.40 mM) |
| form | Liquid |
| pka | 15.00±0.10(Predicted) |
| Specific Gravity | 0.848 (20/4℃) |
| color | APHA: ≤100 |
| Odor | at 10.00 % in dipropylene glycol. fresh green cut grass foliage vegetable herbal oily |
| Odor Type | green |
| Water Solubility | INSOLUBLE |
| Merck | 14,4700 |
| JECFA Number | 315 |
| BRN | 1719712 |
| Stability | Stable. Substances to be avoided include strong oxidizing agents and strong acids. Flammable. |
| LogP | 1 at 35℃ |
| CAS DataBase Reference | 928-96-1(CAS DataBase Reference) |
| NIST Chemistry Reference | 3-Hexen-1-ol, (Z)-(928-96-1) |
| EPA Substance Registry System | (Z)-3-Hexen-1-ol (928-96-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS02 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226 | |||||||||
| Precautionary statements | P210-P240-P241-P280a-P303+P361+P353-P501a | |||||||||
| Hazard Codes | F | |||||||||
| Risk Statements | 10 | |||||||||
| Safety Statements | 16 | |||||||||
| RIDADR | UN 1987 3/PG 3 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | MP8400000 | |||||||||
| F | 10 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29052990 | |||||||||
| Hazardous Substances Data | 928-96-1(Hazardous Substances Data) | |||||||||
| Toxicity | The acute oral LD50 value in rats was reported as 4.70 g/kg (3.82-5.58 g/kg) (Moreno, 1973). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Moreno, 1973). | |||||||||
| NFPA 704 |
|
Leaf alcohol price More Price(8)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | W256323 | cis-3-Hexen-1-ol natural, >98%, FCC, FG | 928-96-1 | 1SAMPLE-K | ₹5347.55 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W256323 | cis-3-Hexen-1-ol natural, >98%, FCC, FG | 928-96-1 | 100G | ₹13726.1 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W256323 | cis-3-Hexen-1-ol natural, >98%, FCC, FG | 928-96-1 | 1KG | ₹100185.38 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | W256323 | cis-3-Hexen-1-ol natural, >98%, FCC, FG | 928-96-1 | 4KG | ₹389829.9 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | H12900 | cis-3-Hexen-1-ol 98% | 928-96-1 | 10G | ₹3258.33 | 2022-06-14 | Buy |
Leaf alcohol Chemical Properties,Uses,Production
Description
Leaf alcohol exists as a liquid at room temperature with a characteristic odor of green leaves. It is found in green tea, violet leaf oil, and many types of leaves, herbs, and grasses. Leaf alcohol finds applications in perfumery as floral fragrance. Leaf alcohol is also investigated for its antidiabetic activity.
Chemical Properties
Leaf Alcohol is a colorless
liquid with the characteristic odor of freshly cut grass. In small quantities,
leaf alcohol occurs in the green parts of nearly all plants. The volatile flavor
constituents of green tea contain up to 30%.
A stereospecific synthesis of (Z)-3-hexen-1-ol starts with the ethylation of
sodium acetylide to 1-butyne, which is reacted with ethylene oxide to give
3-hexyn-1-ol. Selective hydrogenation of the triple bond in the presence of
palladium catalysts yields (Z)-3-hexen-1-ol. Biotechnological processes have
been developed for its synthesis as a natural flavor compound, for example.
Leaf alcohol is used to obtain natural green top notes in perfumes and flavors. In
addition, it is the starting material for the synthesis of (2E,6Z)-2,6-nonadien-l-ol
and (2E,6Z)-2,6-nonadien-l-al.
Occurrence
Main constituent of the oil distilled from the infusion of fermented tea leaves. Reported found as the corresponding ester of phenylacetic acid in the oil of Japanese mint (Mentha arvensis); the volatile oil of Thea chinensis contains approximately 26 to 35% 3-hexen-1-ol, whereas larger amounts are reported in the oils of Morus bombysic, Robinia pseudacacia and Raphanus sativus. Probably occurring also in several green leaves and herbs; reported found in the fruit juices of raspberry, grapefruit and others. Also reported in over 200 foods including apple, apricot, banana, citrus peel oils and juices, berries, guava, mango, grapes, pineapple, cabbage, kohlrabi, celery, cucumber, lettuce, leek, peas, sauerkraut, tomato, ginger, peppermint oil, coconut oil, spearmint oil, mustard, parsley, breads, butter, fish, fish oil, cognac, brandy, cider, sherry, grape wines, tea, soybeans, avocado, olive, passion fruit, plum, rose apple, Malay apple, water apple (Syzigium spp.), beans, marjoram, starfruit, broccoli, pear and apple brandies, figs, brussels sprouts, radish, prickly pear, litchi, dill, lovage, pumpkin, corn oil, malt, laurel, kiwifruit and other sources
Preparation
By the reaction of butyne-1 with ethylene oxide and subsequent selective reduction to the eis isomer (Bedoukian, 1967).
Definition
ChEBI: A primary alcohol that consists of (3Z)-hex-3-ene substituted by a hydroxy group at position 1.
General Description
cis-3-Hexen-1-ol is one of the key volatile constituents of green leaf volatiles(GLV) that can act as an attractant to various insects. It is emitted by green plants when they are physically damaged.
References
[1] NPCS Board of Consultants & Engineers, Industrial Alcohol of Technology Handbook, 2010
[2] A. Shirwaikar, K. Rajendran and C. Kumar, Oral Antidiabetic Activity of Annona squamosa Leaf Alcohol Extract in NIDDM Rats, Pharmaceutical Biology, 2004, vol. 42, 30-35
Leaf alcohol Preparation Products And Raw materials
Raw materials
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chevron_rightPreparation Products
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chevron_right| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| Nagar Haveli Perfumes & Aromatics | +917506551149 | Mumbai, India | 230 | 58 | Inquiry |
| NEERU MENTHOL PRIVATE LIMITED | +91-8884114465 +91-8884114465 | Uttar Pradesh, India | 44 | 58 | Inquiry |
| SYNOVA CHEMICALS | +91-9920741772 +91-9920741772 | Mumbai, India | 428 | 58 | Inquiry |
| AOS Products Pvt Ltd | +91-8285111618 +91-8285111618 | Uttar Pradesh, India | 76 | 58 | Inquiry |
| Sharp Mint Limited | +91-1142290700 +91-1142290700 | New Delhi, India | 9 | 58 | Inquiry |
| Eco Organics | +91-9412251810 +91-9720999980 | Uttar Pradesh, India | 23 | 58 | Inquiry |
| Samde Aromatic Pvt Ltd | +91-9351546864 +91-9351546864 | Rajasthan, India | 21 | 58 | Inquiry |
| Star Iris Exports Pvt Ltd | +91-9837506000 +91-9837506000 | Uttar Pradesh, India | 18 | 58 | Inquiry |
| Fine Organics | +91-9837035981 +91-9837035981 | Uttar Pradesh, India | 3 | 58 | Inquiry |
| Bhagat Aromatics Ltd | +91-1204044300 +91-9321155125 | Uttar Pradesh, India | 24 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| Nagar Haveli Perfumes & Aromatics | 58 |
| NEERU MENTHOL PRIVATE LIMITED | 58 |
| SYNOVA CHEMICALS | 58 |
| AOS Products Pvt Ltd | 58 |
| Sharp Mint Limited | 58 |
| Eco Organics | 58 |
| Samde Aromatic Pvt Ltd | 58 |
| Star Iris Exports Pvt Ltd | 58 |
| Fine Organics | 58 |
| Bhagat Aromatics Ltd | 58 |
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