1-NAPHTHYLUREA

1-NAPHTHYLUREA Structure
CAS No.
6950-84-1
Chemical Name:
1-NAPHTHYLUREA
Synonyms
Nsc 65627;Ai3-61345;Naphthylurea;1-NAPHTHYLUREA;α-Naphthyl urea;Einecs 230-121-6;1-(1-Naphtyl)urea;ALPHA-NAPHTHYLUREA;Urea, 1-naphthalenyl-;1-(Naphthalen-1-yl)urea
CBNumber:
CB0224875
Molecular Formula:
C11H10N2O
Molecular Weight:
186.21
MOL File:
6950-84-1.mol
MSDS File:
SDS
Modify Date:
2022/12/21 16:56:50

1-NAPHTHYLUREA Properties

Melting point 219.5°C
Boiling point 320.7°C (rough estimate)
Density 1.1458 (rough estimate)
refractive index 1.5300 (estimate)
storage temp. 2-8°C
pka 14.45±0.50(Predicted)
EPA Substance Registry System Urea, 1-naphthalenyl- (6950-84-1)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
RIDADR  UN 1652 6.1/ PGII
HazardClass  6.1
PackingGroup  II

1-NAPHTHYLUREA Chemical Properties,Uses,Production

General Description

A gray solid. Insoluble in water and denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

1-NAPHTHYLUREA is an amide. Amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

Purification Methods

Crystallise the urea from EtOH (m 213-214o also 215o). [Beilstein 12 H 1238, 12 IV 3076.]

1-NAPHTHYLUREA Preparation Products And Raw materials

Raw materials

Preparation Products

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Naphthylurea α-Naphthyl urea ALPHA-NAPHTHYLUREA 1-(1-Naphtyl)urea Ai3-61345 Einecs 230-121-6 Nsc 65627 Urea, 1-naphthalenyl- 1-(naphthalen-2-yl)urea 1-(Naphthalen-1-yl)urea 1-NAPHTHYLUREA Urea, N-1-naphthalenyl- 6950-84-1