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Gallium(III) oxide

Gallium(III) oxide Structure
CAS No.
12024-21-4
Chemical Name:
Gallium(III) oxide
Synonyms
GALLIUM OXIDE;Ga2-O3;Gallia;β-Ga2O3;Gallic oxide;ium(III) oxide;galliumtrioxide;Gallium(Ⅲ) oxide;GALLIUM(+3)OXIDE;GalliuM(Ⅵ) oxide
CBNumber:
CB0268996
Molecular Formula:
Ga2O3
Molecular Weight:
187.44
MOL File:
12024-21-4.mol
Modify Date:
2024/6/4 15:29:52

Gallium(III) oxide Properties

Melting point 1740 °C
Density 6.44 g/mL at 25 °C
refractive index 1.92
storage temp. Sealed in dry,Room Temperature
solubility soluble in hot acid solutions
form Powder or Lump
Specific Gravity 6.44
color White
Water Solubility Soluble in acids. Insoluble in water
Merck 14,4346
Stability Stable. Incompatible with magnesium.
InChIKey QZQVBEXLDFYHSR-UHFFFAOYSA-N
CAS DataBase Reference 12024-21-4(CAS DataBase Reference)
EPA Substance Registry System Gallium trioxide (12024-21-4)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P271-P280
Safety Statements  24/25
WGK Germany  2
RTECS  LW9650000
TSCA  Yes
HS Code  28259090
Toxicity mammal (species unspecified),LDLo,intraperitoneal,10gm/kg (10000mg/kg),BEHAVIORAL: EXCITEMENTLUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSIONBEHAVIORAL: ATAXIA,Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 31(6), Pg. 58, 1987.
NFPA 704
0
0 0

Gallium(III) oxide price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 215066 Gallium(III) oxide ≥99.99% trace metals basis 12024-21-4 10G ₹15155 2022-06-14 Buy
Sigma-Aldrich(India) 215066 Gallium(III) oxide ≥99.99% trace metals basis 12024-21-4 50G ₹46266.05 2022-06-14 Buy
ALFA India ALF-042528-22 Gallium(III) oxide, Puratronic™, 99.999% (metals basis) 12024-21-4 100g ₹74423 2022-05-26 Buy
ALFA India ALF-042528-14 Gallium(III) oxide, Puratronic™, 99.999% (metals basis) 12024-21-4 25g ₹21269 2022-05-26 Buy
ALFA India ALF-042528-06 Gallium(III) oxide, Puratronic™, 99.999% (metals basis) 12024-21-4 5g ₹6499 2022-05-26 Buy
Product number Packaging Price Buy
215066 10G ₹15155 Buy
215066 50G ₹46266.05 Buy
ALF-042528-22 100g ₹74423 Buy
ALF-042528-14 25g ₹21269 Buy
ALF-042528-06 5g ₹6499 Buy

Gallium(III) oxide Chemical Properties,Uses,Production

Description

Gallium(III) oxide (Ga2O3) is a wide band gap semiconductor that belongs to a family of transparent semiconducting oxides (TSO). It can form different polymorphs such as α-,β-, γ-, δ-, and ε-. Polycrystalline and nanocrystalline Ga2O3 can be prepared using several methods such as chemical vapor deposition, thermal vaporization, and sublimation, molecular beam epitaxy, melt growth, etc. It is widely used as a functional material in various applications including optoelectronics, chemical sensors, catalysis, semiconductor devices, field-effect transistors, and many others.

Chemical Properties

white odourless powder

Uses

In semiconductors; gas sensing; catalysis. Nanostructures as blue and UV light emitters in optoelectronic device applications.
Gallium(III) oxide has been reported in applications in lasers, phosphors, and luminescent materials. Monoclinic ß-Ga2O3 is used in gas sensors and luminescent phosphors and can be applied to dielectric coatings for solar cells. This stable oxide has also shown potential for deep-ultraviolet transparent conductive oxides, and transistor applications. Thin Ga2O3 films are of commercial interest as gas sensitive materials. ß-Gallium(III) oxide is used in the production of Ga2O3-Al2O3 catalyst.

Production Methods

Gallium oxide is formed during the annealing or heating of semiconductors containing gallium in the microelectronics industry.

Application

Gallium(III) oxide is widely used as a host material for the fabrication of electroluminescent devices. For example, europium-doped Ga2O3 thin films can be used as a light-emitting layer to fabricate an optically transparent electroluminescent device.
Due to its distinct optical and electrical properties like moderate conductivity and high laser damage threshold, Ga2O3 can be used in laser-driven electron accelerators, low-loss plasmonics, and Si-based dielectric laser accelerators.
It can also be used as an effective catalyst for the dehydrogenation of propane to propene.
Starting material for the preparation of Sr2CuGaO3S, an example of a rare square pyramidal gallium.
Gallium(III) oxide is used in spectroscopic analysis and in preparing gallium arsenide for making semiconductors.    

General Description

Odorless fine white powder. Insoluble in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

GALLIUM(III) OXIDE may react with acids. Heating (to 1292° F) with magnesium causes a violent reduction to metallic slate.

Health Hazard

SYMPTOMS: Symptoms of exposure to GALLIUM(III) OXIDE include reduction of red blood cells and platelets, anemia, skin rash and nausea.

Fire Hazard

Flash point data for GALLIUM(III) OXIDE are not available; however, GALLIUM(III) OXIDE is probably combustible.

References

Highly selective and rapid enrichment of phosphorylated peptides using gallium oxide‐coated magnetic microspheres for MALDI‐TOF‐MS and nano‐LC‐ESI‐MS/MS/MS analysis DOI:10.1002/PMIC.200700454
Development of gallium oxide power devices (Phys. Status Solidi A 1∕2014) DOI:10.1002/PSSA.201470201
Synthesis and characterization of morphologically different high purity gallium oxide nanopowders DOI:10.1007/S10853-007-1869-2
Structure, Morphology, and Optical Properties of Amorphous and Nanocrystalline Gallium Oxide Thin Films DOI:10.1021/JP311300E
Electrical and optical properties of deep ultraviolet transparent conductive Ga2O3/ITO films by magnetron sputtering DOI:10.1088/1674-4926/31/10/103001
Patty's Toxicology, 6 Volume Set, 6th Edition

Gallium(III) oxide Preparation Products And Raw materials

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Welcome Impex Private Limited 08046036807 Ahmedabad, India 4 58 Inquiry
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Zhuoer Chemical Co., Ltd 02120970332; +8613524231522 China 3005 58 Inquiry
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