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PERFLUORO-1,3-DIMETHYLCYCLOHEXANE

PERFLUORO-1,3-DIMETHYLCYCLOHEXANE Structure
CAS No.
335-27-3
Chemical Name:
PERFLUORO-1,3-DIMETHYLCYCLOHEXANE
Synonyms
FLUTEC PP3;FLUTECR PP3;FLUTEC PP3102;1,3-bis(trifluorome;Perfluor-1,3-dimethylcyclohexan;Perfluoro-1,3-dimethylcyclohexan;PERFLUORO-1,3-DIMETHYLCYCLOHEXANE;Cyclohexane, perfluoro-1,3-dimethyl-;Perfluorine-1, 3-dimethylcyclohexane;Perfluoro(1,3-dimethylcyclohexane)90%
CBNumber:
CB0490412
Molecular Formula:
C8F16
Molecular Weight:
400.06
MOL File:
335-27-3.mol
Modify Date:
2024/6/5 17:10:12

PERFLUORO-1,3-DIMETHYLCYCLOHEXANE Properties

Melting point -55 °C (lit.)
Boiling point 101-102 °C (lit.)
Density 1.828 g/mL at 25 °C (lit.)
vapor density 14 (vs air)
vapor pressure 47.2hPa at 25℃
refractive index n20/D 1.3(lit.)
Flash point None
form Liquid
Specific Gravity 1.828
BRN 2064147
LogP 666 at 25℃
CAS DataBase Reference 335-27-3(CAS DataBase Reference)
NIST Chemistry Reference Perfluoro-1,3-dimethylcyclohexane(335-27-3)
EPA Substance Registry System Cyclohexane, 1,1,2,2,3,3,4,5,5,6-decafluoro-4,6-bis(trifluoromethyl)- (335-27-3)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  GV4990000
Hazard Note  Irritant
TSCA  T
HS Code  29038900
NFPA 704
1
0 0

PERFLUORO-1,3-DIMETHYLCYCLOHEXANE Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

Perfluoro-1,3-dimethylcyclohexane has been used in:

  • the preparation of amorphous fluorocarbon films by plasma polymerization
  • hydroformylation of linear terminal alkenes using rhodium based catalysts under fluorous biphasic conditions in the presence and absence of toluene

General Description

Quenching of the second excited singlet state of xanthione in inert, nonpolar perfluoro-1,3-dimethylcyclohexane has been studied using picosecond time-resolved fluorescence decay methods.

Purification Methods

Fractionally distil it, then 35mL are sealed with about 7g KOH pellets in a borosilicate glass ampoule and heated at 135o for 48hours. The ampoule is cooled, opened, and the liquid is resealed with fresh KOH in another ampoule and heated as before. This process is repeated until no further decomposition is observed. The substance is then washed with distilled water, dried (CaSO4) and distilled. [Grafstein Anal Chem 26 523 1954, Beilstein 5 III 378.] IRRITANT.

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PERFLUORO-1,3-DIMETHYLCYCLOHEXANE, TECH. , 80% PERFLUORO-1,3-DIMETHYLCYCLOHEXANE, TECH. 80+% 1,1,2,2,3,3,4,5,5,6-decafluoro-4,6-bis(trifluoromethyl)-cyclohexan 1,1,2,2,3,3,4,5,5,6-Decafluoro-4,6-bis(trifluoromethyl)cyclohexane 1,1,2,2,3,3,4,5,5,6-decafluoro-4,6-bis(trifluoromethyl)-Cyclohexane PERFLUORO-1,3-DIMETHYLCYCLOHEXANE,TECHNICAL Perfluoro(1,3-dimethylcyclohexane)90% Decafluoro-1,3-bis(trifluoromethyl)cyclohexane, Hexadecafluoro-1,3-dimethylcyclohexane, Hexadecafluoro-1,3-dimethylcyclohexane (cis+trans) 1,3-Bis(trifluoromethyl)-1,2,2,3,4,4,5,5,6,6-decafluorocyclohexane Perfluoro(1,3-dimethylcyclohexane), tech. 80%, remainder other fluorocarbons Carbogal (PERFLUORO-1,3-DIMETHYLCYCLOHEXANE) Perfluoro-1,3-dimethylcyclohexane,80%,tech. 1,3-bis(trifluorome Perfluoro-1,3-dimethylcyclohexane,Decafluoro-1,3-bis(trifluoromethyl)cyclohexane, Hexadecafluoro-1,3-dimethylcyclohexane (cis+trans), Hexadecafluoro-1,3-dimethylcyclohexane Perfluoro-1,3-dimethylcyclohexan 1,3-Bis(trifluoromethyl)-1,2,2,3,4,4,5,5,6,6-decafluorocyclohexane, Hexadecafluoro(1,3-dimethylcyclohexane) Perfluoro-1,3-dimethylcyclohexane technical grade, 80% 1,3-bis(trifluoromethyl)perfluorocyclohexane Cyclohexane, 1,1,2,2,3,3,4,5,5,6-decafluoro-4,6-bis(trifluoromethyl)- Cyclohexane, decafluoro-1,3-bis(trifluoromethyl)- Cyclohexane, perfluoro-1,3-dimethyl- cyclohexane,1,1,2,2,3,3,4,5,5,6-decafluoro-4,6-bis(trifluoromethyl)- cyclohexane,decafluoro-1,3-bis(trifluoromethyl)- Decafluoro-4,6-bis(trifluoromethyl)cyclohexane Perfluor-1,3-dimethylcyclohexan HEXADECAFLUORO-1,3-DIMETHYLCYCLOHEXANE FLUTEC PP3 FLUTEC PP3102 FLUTECR PP3 DECAFLUORO-1,3-BIS(TRIFLUOROMETHYL)CYCLOHEXANE PERFLUORO-1,3-DIMETHYLCYCLOHEXANE PERFLUORO-1,3-DIMETHYLCYCLOHEXANE ISO 9001:2015 REACH Perfluoro(1,3-dimethylcyclohexane), tech. 80%, remainder oth Perfluorine-1, 3-dimethylcyclohexane Perfluoro-1,3-dimethylcyclohexane 335-27-3 355-27-3 C6F10CF32 C8F16 C8F14 Fluorous Solvents Fluorous Chemistry Building Blocks Halogenated Hydrocarbons Alkyl Organic Building Blocks Fluorous Chemistry Fluorous Solvents Synthetic Organic Chemistry