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PERFLUORO(METHYLCYCLOHEXANE)

PERFLUORO(METHYLCYCLOHEXANE) Structure
CAS No.
355-02-2
Chemical Name:
PERFLUORO(METHYLCYCLOHEXANE)
Synonyms
1-(Trifluoromethyl)-1,2,2,3,3,4,4,5,5,6,6-undecafluorocyclohexane;FLUTEC PP2;FLUTECR PP2;Perfluor-(methylcyclohexan);PERFLUORO(METHYLCYCLOHEXANE);PERFLUOROMETHYLCYCLOHEXANE 97+%;Perfluoro(methylcyclohexane)95%;TETRADECAFLUOROMETHYLCYCLOHEXANE;Perfluoro(methylcyclohexane),94%;Perfluoro(methylcyclohexane),90%
CBNumber:
CB9301481
Molecular Formula:
C7F14
Molecular Weight:
350.05
MOL File:
355-02-2.mol
Modify Date:
2023/12/25 17:47:29

PERFLUORO(METHYLCYCLOHEXANE) Properties

Melting point -37 °C
Boiling point 76 °C(lit.)
Density 1.80 g/mL at 20 °C
vapor pressure 14kPa at 25℃
refractive index n17/D 1.285(lit.)
Flash point 75-76°C
storage temp. Refrigerator
solubility Miscible with acetone and benzene.
form Oil
color Colourless
Specific Gravity 1.787
BRN 1915981
Dielectric constant 1.8600000000000001
LogP 666 at 25℃
CAS DataBase Reference 355-02-2(CAS DataBase Reference)
EPA Substance Registry System Cyclohexane, 1,1,2,2,3,3,4,4,5,5,6-undecafluoro-6-(trifluoromethyl)- (355-02-2)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  24/25
WGK Germany  3
RTECS  GV7610000
Hazard Note  Irritant
TSCA  T
HS Code  29038900
Toxicity LCLo ihl-rat: 825 ppm/14H 11FYAN 3,90,63
NFPA 704
0
0 0

PERFLUORO(METHYLCYCLOHEXANE) Chemical Properties,Uses,Production

Chemical Properties

CLEAR LIQUID

Uses

Perfluoro(methylcyclohexane) is used as a solvent to determine fluorophilicity of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters. It combines with chloroform and acts as an ingredient for "fluorous" biphase reactions. Furthermore, it finds application as a heat transfer agent, a dielectric fluid and a perfluorocarbon tracer. It acts as a good solvent for gases.

General Description

Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions. Gas-phase structure of perfluoro(methylcyclohexane) was investigated.

Safety Profile

Mildly toxic by inhalation. When heated to decomposition it emits toxic fumes of Fí.

Purification Methods

Reflux it for 24hours with saturated acid KMnO4 (to oxidise and remove hydrocarbons), then neutralise, steam distil, dry with P2O5 and pass slowly through a column of dry silica gel. [Glew & Reeves J Phys Chem 60 615 1956.] It can also be purified by percolation through a 1metre neutral activated alumina column, and 1H-impurities are checked by NMR. [Beilstein 5 IV 102.] IRRITANT.

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FLUTEC PP2 FLUTECR PP2 PERFLUORO(METHYLCYCLOHEXANE) TETRADECAFLUOROMETHYLCYCLOHEXANE UNDECAFLUORO(TRIFLUOROMETHYL)CYCLOHEXANE (TRIFLUOROMETHYL)UNDECAFLUOROCYCLOHEXANE (Trifluormethyl)-undecafluorcyclohexan (Trifluoromethyl)undecafluorohexane (Trifluoromethyl)undecaflurocyclohexane 1,1,2,2,3,3,4,4,5,5,6-Undecafluoro-6-(trifluoromethyl)cyclohexane 1-trifluoromethyl-1,2,2,3,3,4,4,5,5,6,6-undecafluoro-cyclohexan Cyclohexane, 1-trifluoromethyl-1,2,2,3,3,4,4,5,5,6,6-undecafluoro- Cyclohexane, undecafluoro(trifluoromethyl)- cyclohexane,tetradecafluoromethyl- Cyclohexane,undecafluoro(trifluoromethyl)- Perfluor-(methylcyclohexan) Tetradecafluor-(methylcyclohexan) undecafluoro(trifluoromethyl)-cyclohexan PERFLUORO(METHYLCYCLOHEXANE), TECH., 90% PERFLUOROMETHYLCYCLOHEXANE 97+% Perfluoro(methylcyclohexane), pract., 95% (Trifluoromethyl)undecafluorocyclohexane,Perfluoromethylcyclohexane Perfluoro(methylcyclohexane),(Trifluoromethyl)undecafluorocyclohexane, Perfluoromethylcyclohexane Perfluoro(methylcyclohexane), (PMCH) Perfluoro(methylcyclohexane),94% Perfluoro(methylcyclohexane)95% 1,2,2,3,3,4,4,5,5,6,6-Undecafluoro-1-(trifluoromethyl)cyclohexane 1β-(Trifluoromethyl)-1,2,2,3,3,4,4,5,5,6,6-undecafluorocyclohexane PFMCH Fluid (PERFLUOROMETHYLCYCLOHEXANE) Perfluoro(methylcyclohexane),90% Perfluoro(methylcyclohexane),96% Cyclohexane, 1,1,2,2,3,3,4,4,5,5,6-undecafluoro-6-(trifluoromethyl)- PERFLUORO(METHYLCYCLOHEXANE) ISO 9001:2015 REACH 1-(Trifluoromethyl)-1,2,2,3,3,4,4,5,5,6,6-undecafluorocyclohexane Perfluoro(methylcyclohexane) technical grade, 90% 355-02-2 C6F11CF3 C7F14 Halogenated Hydrocarbons Organic Building Blocks Alkyl Building Blocks