Benzotrifluoride

- CAS No.
- 98-08-8
- Chemical Name:
- Benzotrifluoride
- Synonyms
- α,α,α-Trifluorotoluene;TRIFLUORO TOLUENE;A,A,A-TRIFLUOROTOLUENE;Benzotrifluoide;Triflorotoluene;BENZOTRIFLOURIDE;ALPHA,ALPHA,ALPHA-TRIFLUOROTOLUENE;Oxsol2000;usafma-16;USAF ma-16
- CBNumber:
- CB1292738
- Molecular Formula:
- C7H5F3
- Molecular Weight:
- 146.11
- MOL File:
- 98-08-8.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/1/27 9:38:02
Melting point | −29 °C(lit.) |
---|---|
Boiling point | 102 °C(lit.) |
Density | 1.19 g/mL at 20 °C(lit.) |
vapor density | 5.04 |
vapor pressure | 53 hPa (25 °C) |
refractive index |
n |
Flash point | 54 °F |
storage temp. | Store below +30°C. |
solubility | 0.45g/l Hydrolysis |
form | Liquid |
color | Clear colorless |
Specific Gravity | 1.199 |
Odor | aromatic odor |
explosive limit | 1.4-9.3%(V) |
Water Solubility | <0.1 g/100 mL at 21 ºC |
Merck | 14,1110 |
BRN | 1906908 |
Exposure limits |
ACGIH: TWA 2.5 mg/m3 NIOSH: IDLH 250 mg/m3 |
Dielectric constant | 39.0(20℃) |
Stability | Stable. Highly flammable. Incompatible with strong oxidizing agents, strong bases, strong reducing agents. |
InChIKey | GETTZEONDQJALK-UHFFFAOYSA-N |
LogP | 3.01 at 20℃ |
CAS DataBase Reference | 98-08-8(CAS DataBase Reference) |
NIST Chemistry Reference | Benzene, (trifluoromethyl)-(98-08-8) |
EPA Substance Registry System | Benzotrifluoride (98-08-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() GHS02,GHS07,GHS08 |
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Signal word | Danger | |||||||||
Hazard statements | H225-H304-H315-H319-H340-H350-H372-H412 | |||||||||
Precautionary statements | P210-P273-P301+P310-P303+P361+P353-P305+P351+P338-P331 | |||||||||
Hazard Codes | F,T,C,N,Xn | |||||||||
Risk Statements | 45-46-11-36/38-48/23/24/25-65-51/53-39/23/24/25-23/24/25-48/20/22-40-38-22 | |||||||||
Safety Statements | 53-26-36/37-45-62-61-23-16 | |||||||||
RIDADR | UN 2338 3/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | XT9450000 | |||||||||
Autoignition Temperature | 650 °C | |||||||||
Hazard Note | Flammable/Corrosive | |||||||||
TSCA | Yes | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29049090 | |||||||||
Hazardous Substances Data | 98-08-8(Hazardous Substances Data) | |||||||||
Toxicity | LD50 orally in Rabbit: 15000 mg/kg LD50 dermal Rat > 2000 mg/kg | |||||||||
NFPA 704 |
|
Benzotrifluoride price More Price(11)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | T63703 | α,α,α-Trifluorotoluene ≥99% | 98-08-8 | 500G | ₹4957.85 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | T63703 | α,α,α-Trifluorotoluene ≥99% | 98-08-8 | 1KG | ₹6505.83 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 8.41554 | Benzotrifluoride for synthesis | 98-08-8 | 100ML | ₹5290 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 547948 | α,α,α-Trifluorotoluene anhydrous, ≥99% | 98-08-8 | 100ML | ₹4547.05 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 547948 | α,α,α-Trifluorotoluene anhydrous, ≥99% | 98-08-8 | 1L | ₹5697 | 2022-06-14 | Buy |
Benzotrifluoride Chemical Properties,Uses,Production
Chemical Properties
Benzotrifluoride is a colorless to light yellow liquid, low viscosity liquid. Its polarity is intermediate between those of dichloromethane and ethyl acetate, and it is miscible with common organic solvents and able to dissolve many organic compounds. Benzotrifluoride is used in a wide variety of reactions including radical reactions, oxidations and reductions, phase-transfer reactions, transition metal catalyzed processes andLewis acid reactions.
Uses
Benzotrifluoride is a useful alternative solvent for organic reactions currently conducted in dichloromethane and related solvents.
Definition
ChEBI: (trifluoromethyl)benzene is a fluorohydrocarbon that is fluoroform in which the hydrogen is substituted by a phenyl group. It has a role as a solvent and an environmental contaminant. It is a fluorohydrocarbon and a member of (trifluoromethyl)benzenes. It derives from a fluoroform.
General Description
A clear colorless liquid with an aromatic odor. Flash point of 54°F. Vapors are heavier than air. Insoluble in water and slightly denser than water. May be toxic by inhalation.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
Benzotrifluoride may react with oxidizing materials, strong bases and reducing agents.
Hazard
Highly toxic by inhalation. Flammable, dangerous fire risk.
Health Hazard
Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.
Fire Hazard
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety Profile
Poison by intraperitoneal route.Moderately toxic by subcutaneous route. Dangerous fire hazard. To fight fire, usewater, foam, CO2, spray mist, dry chemical. When heatedto decomposition it emits toxic fumes of F??. Incompatiblewith oxidizing materials
Purification Methods
Purify benzotrifluoride by repeated treatment with boiling aqueous Na2CO3 (until no test for chloride ion is obtained), dry it with K2CO3, then with P2O5, and fractionally distil it. [Beilstein 5 IV 802.]
Benzotrifluoride Preparation Products And Raw materials
Raw materials
Preparation Products
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Gujarat Fluorochemicals Limited (GFL) | +91-1206149600 +91-9662527618 | Uttar Pradesh, India | 21 | 58 | Inquiry |
JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
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Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6905 | 58 | Inquiry |
Pharmaffiliates Analytics and Synthetics P. Ltd | +91-172-5066494 | Haryana, India | 6739 | 58 | Inquiry |
Unique Med Chem Laboratories | 08048372558Ext 247 | Maharashtra, India | 25 | 58 | Inquiry |
Kingchem Lifescience Private Limited | 08045849975Ext 244 | Gujarat, India | 2 | 58 | Inquiry |
Dr Prem's Molecules Pvt. Ltd. | +91 9825310038 | New Delhi, India | 544 | 50 | Inquiry |
TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6768 | 58 | Inquiry |
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