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Tau-fluvalinate

Tau-fluvalinate Structure
CAS No.
102851-06-9
Chemical Name:
Tau-fluvalinate
Synonyms
t-Fluvalinate;Mavric;MK 128;Apistan;Tau-fluvalite;τ-Fluvalinate;au-fluvalinate;tau-fluvaliate;TAO-FLUVALINATE;Tau-fluvalinate
CBNumber:
CB0498483
Molecular Formula:
C26H22ClF3N2O3
Molecular Weight:
502.91
MOL File:
102851-06-9.mol
Modify Date:
2024/6/6 16:20:44

Tau-fluvalinate Properties

Boiling point 450°C
Density 1.2900
vapor pressure 9×10-11 Pa (25 °C)
Flash point 90 °C
storage temp. Sealed in dry,Room Temperature
solubility DMF: 10 mg/ml,DMSO: 10 mg/ml,Ethanol: 10 mg/ml
Water Solubility 0.001 mg l-1 (20 °C)
pka -1.16±0.50(Predicted)
BRN 8092907
LogP 7.310 (est)
CAS DataBase Reference 102851-06-9(CAS DataBase Reference)
EPA Substance Registry System Tau-fluvalinate (102851-06-9)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07,GHS09
Signal word  Warning
Hazard statements  H302-H315-H410
Precautionary statements  P273-P501
Hazard Codes  Xn,N
Risk Statements  22-38-50/53
Safety Statements  24-59-61
RIDADR  UN2810 6.1/PG 3
WGK Germany  3
HS Code  29269090
NFPA 704
0
2 0

Tau-fluvalinate Chemical Properties,Uses,Production

Description

Fluvalinate is a viscous, yellow oil in appearance. It is very soluble in organic solvents and aromatic hydrocarbons and insoluble in water. It is a synthetic pyrethroid. It is used as a broad-spectrum insecticide against moths, beetles, fleas, turf and ornamental insects, and other insect pests on cotton, cereal, grape, potato, fruit tree, vegetable, and plantation crops. It is available in emulsifiable concentrates, suspensions, and flowable formulations. Fluvalinate is a moderately toxic compound in the U.S. EPA toxicity class II. Some formulations may have the capacity to cause corrosion of the eyes. Pesticides containing fluvalinate must bear the signal word DANGER on the product label. Fluvalinate is classified as an RUP because of its high toxicity to fish and aquatic invertebrates.

Chemical Properties

Yellow viscous liquid

Uses

Fluvalinate is used to control a wide range of insects and spider mites on fruit trees, vines, vegetables, cereals, cotton, tea, tobacco, ornamentals and other crops. It is also used for parasite control in bee hives.

Definition

ChEBI: The (2R) diastereomers of fluvalinate. A synthetic pyrethroid insecticide, it is used to control varroa mites in honey bee colonies.

Health Hazard

Exposures to fl uvalinate cause coughing, sneezing, throat irritation, itching, or burning sensations on the arms or face with or without a rash, headache, and nausea. Prolonged period of exposures to pyrethroids cause adverse effects on the CNS, liver, and kidneys. Fluvalinate is slightly toxic to birds.

Potential Exposure

Pyrethroid insecticide used as a broad spectrum insecticide to control moths, beetles and other pests on cereals, potatoes, fruit trees, vegetables, fleas, cot ton, turf and ornamentals. It is also used to control varroa mites in honey bees. Some applications may be classified as a United States Environmental Protection Agency Restricted Use Pesticide (RUP). Formerly used as an insec ticide. Production discontinued by Sandoz Agro, Inc. Incompatibilities: Corrosive to some metals. Keep away from strong oxidizers and alkaline materials. Decomposes in temperatures above 350℃ releasing toxic vapors of hydrogen chloride, nitrogen oxides, and hydrogen fluoride.

Metabolic pathway

The information reported below is derived from studies on fluvalinate, the racemic m-valinate (CASRN 69409-94-5). This has been superseded by the D-isomer. Evidence is given below to show that the results derived from fluvalinate are relevant to tau-fluvalinate. The chemical and photochemical degradation of fluvalinate and its degradation in soils have been reported. Information on metabolism in plants, rats, monkeys, cows and chickens is also published. The metabolism of fluvalinate is dominated by hydrolysis followed by oxidation and conjugation of the metabolites. Novel bile acid conjugates are highlighted. All quantitative data reported below are for the lower of usually two doses.

storage

Fluvalinate should be kept stored only in its original container at a temperature not exceeding 40°C. It should be kept away from food, drink, and animal feedstuffs.

Shipping

UN2902 Pesticides, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Waste Disposal

Incineration would be an effective disposal procedure where permitted. If an efficient incinerator is not available, the product should be mixed with large amounts of combustible material and contact with the smoke should be avoided. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

Precautions

Occupational workers should avoid contact of fl uvalinate with the skin and eyes and avoid breathing contaminated fumes. Wear suitable protective clothing, nitrile rubber gloves, and safety glasses or a face shield. Fluvalinate is an RUP and should be used, handled, and/or purchased only by certifi ed applicators.

Tau-fluvalinate Preparation Products And Raw materials

Global( 161)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Jiangsu Boquan Biotechnology Co., Ltd. +86-18168774353 China 248 58 Inquiry
Hebei Duling International Trade Co. LTD +8617333973358 China 15437 58 Inquiry
Hangzhou FandaChem Co.,Ltd. 008657128800458; +8615858145714 China 9338 55 Inquiry
ATK CHEMICAL COMPANY LIMITED +undefined-21-51877795 China 32760 60 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29900 58 Inquiry
Chongqing Chemdad Co., Ltd +86-023-6139-8061 +86-86-13650506873 China 39916 58 Inquiry
CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49391 58 Inquiry
Shaanxi Dideu Medichem Co. Ltd +86-29-87569266 15319487004 China 2417 58 Inquiry
Zhengzhou Alfa Chemical Co.,Ltd +8618530059196 China 12997 58 Inquiry
tau-fluvalinate (bsi,e-iso) Cyano-(3-phenoxyphenyl)methyl N-[2-chloro-4-(trifluoromethyl)phenyl]-D-valinate Tau-fluvalinate TAO-FLUVALINATE (RS)-alpha-Cyano-3-phenoxybenzyl N-(2-chloro-a,a,a-trifluoro-p-tolyl)-D-valinate (RS)-a-Cyano-3-phenoxybenzyl-N-(2-chloro-a.a.a-trifluoro-p-tolyl)-D-valina τ-Fluvalinate solution,100ppm Tau-fluvalite tau-fluvalinate cyano-(3-phenoxyphenyl)methyl N-[2-chloro-4-(trifluoromethyl)phenyl]-D-valinate Apistan Mavric MK 128 N-(2-chloro-4-trifluoromethylphenyl)-DL-2-valine(alpha) cyano-(3-phenoxy-phenyl) methyl ester N-[2-Chloro-4-(trifluoromethyl)phenyl]-D-valine cyano(3-phenoxyphenyl)methyl ester N-[2-Chloro-4-(trifluoromethyl)phenyl]-D-valine α-cyano-3-phenoxybenzyl ester (2R)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methyl-butyric acid [cyano-[3-(phenoxy)phenyl]methyl] ester [cyano-[3-(phenoxy)phenyl]methyl] (2R)-2-[[2-chloro-4-(trifluoromethyl)phenyl]amino]-3-methyl-butanoate [cyano-[3-(phenoxy)phenyl]methyl] (2R)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate tau-Fluvalinate 100mg [102851-06-9] Mavrik,τ-Fluvalinate, N-[2-Chloro-4-(trifluoromethyl)phenyl]-D-valine (RS)-cyano(3-phenoxyphenyl)methyl ester, TAU-FLUVALINATE 250MG TAU-FLUVALINATE PESTANAL, 250 MG MAVRIK, 100MG, NEAT (alpha-RS,2R)-Fluvalinate D-Valine, N-2-chloro-4-(trifluoromethyl)phenyl-, cyano(3-phenoxyphenyl)methyl ester n-[2-chloro-4-(trifluoromethyl)phenyl]-d-valine (rs)-cyano(3-phenoxyphenyl)methyl ester tau-fluvalinateSolution,100mg/L,1ml τ-Fluvalinate (Mixture of Diastereomers) Tau-Fluvalinate @100 μg/mL in MeOH Tau-Fluvalinate @1000 μg/mL in MeOH τ-Fluvalinate au-fluvalinate τ-Fluvalinate (Mixture of 2 Diastereomers) Fluvalinate Impurity 1 (Tau-Fluvalinate) tau-fluvaliate (2R)-Cyano(3-phenoxyphenyl)methyl 2-((2-chloro-4-(trifluoromethyl)phenyl)amino)-3-methylbutanoate tau-Fluvalinate(mixture of isomers) (2R)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoic acid [cyano-(3-phenoxyphenyl)methyl] ester tau-Fluvalinate Solution, 1000ppm t-Fluvalinate 102851-06-9 C26H22ClF3N2O3 INSECTICIDE