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1,2,3,6-Tetrahydrophthalic anhydride

1,2,3,6-Tetrahydrophthalic anhydride Structure
CAS No.
85-43-8
Chemical Name:
1,2,3,6-Tetrahydrophthalic anhydride
Synonyms
TETRAHYDROPHTHALIC ANHYDRIDE;tetrahydrophthalic;thpa[qr];rikacidth[qr];Tetrahydroftalanhydrid;1,2,3,6-TetrahydrophthaL;3,6-Cyclopropylene-ΔTetrahydrophthalsureanhydrid;anhydridetetrahydrophtalique;tetrahydrophthalicanhydrides
CBNumber:
CB0501956
Molecular Formula:
C8H8O3
Molecular Weight:
152.15
MOL File:
85-43-8.mol
Modify Date:
2024/6/6 16:20:44

1,2,3,6-Tetrahydrophthalic anhydride Properties

Melting point 101-102°C
Boiling point 195°C 5mm
Density 1,375 g/cm3
vapor pressure 0.021Pa at 20℃
refractive index 1.4810 (estimate)
Flash point 157°C
storage temp. Store below +30°C.
solubility soluble in DCM, Ethyl Acetate, Toluene
form Solid
pka 3.84[at 20 ℃]
color Off-White to Light Tan
Water Solubility 29.4g/L at 20℃
LogP 1.29 at 40℃
CAS DataBase Reference 85-43-8(CAS DataBase Reference)
EPA Substance Registry System Tetrahydrophthalic anhydride (85-43-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313-P362
Risk Statements  41-42/43-52/53
Safety Statements  26-36/37/39
RIDADR  2698
HazardClass  8
PackingGroup  III

1,2,3,6-Tetrahydrophthalic anhydride price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 8.00742 1,2,3,6-Tetrahydrophthalic anhydride for synthesis 85-43-8 100G ₹3470 2022-06-14 Buy
Sigma-Aldrich(India) 8.00742 1,2,3,6-Tetrahydrophthalic anhydride for synthesis 85-43-8 1KG ₹6200 2022-06-14 Buy
Sigma-Aldrich(India) 8.00742 1,2,3,6-Tetrahydrophthalic anhydride for synthesis 85-43-8 8007429025 ₹100640.01 2022-06-14 Buy
Product number Packaging Price Buy
8.00742 100G ₹3470 Buy
8.00742 1KG ₹6200 Buy
8.00742 8007429025 ₹100640.01 Buy

1,2,3,6-Tetrahydrophthalic anhydride Chemical Properties,Uses,Production

Chemical Properties

white flaky solid

Uses

Chemical intermediate for light-colored alkyds, polyesters, plasticizers, and adhesives; intermediate for pesticides; hardener for resins.

Definition

ChEBI: 1,2,3,6-tetrahydrophthalic anhydride is a cyclic dicarboxylic anhydride that is 1,3,3a,4,7,7a-hexahydro-2-benzofuran carrying oxo groups at positions 1 and 3. It is a cyclic dicarboxylic anhydride and a tetrahydrofurandione.

General Description

Clear colorless to light yellow slight viscous liquid. Highly toxic and a strong irritant to skin, eyes and mucous membranes. Corrosive to skin and metal. Used in making polyester, alkyd resins, and plasticizers.

Air & Water Reactions

Reacts exothermically with water to form memtetrahydrophthalic acid.

Reactivity Profile

CIS-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE; >98% is combustible. Reacts with oxidizers. Reacts exothermically with water. These reactions are usually slow, but can become violent when local heating accelerates their rate. Acids accelerate the reaction with water. Incompatible with acids, strong oxidizing agents, alcohols, amines, and bases.

Hazard

Strong irritant to eyes and skin.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Safety Profile

Moderately toxic by intraperitoneal route. Mildly toxic by ingestion. A corrosive irritant to skin, eyes, and mucous membranes. Combustible when exposed to heat or flame. Will react with water or steam to produce heat; can react with oxidizing materials. To fight fre, use water, foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ANHYDRIDES.

Global( 214)Suppliers
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Δ4-Tetrahydrophthalic anhydride 1,2,3,6-Tetrahydro phthalic anhydride (THPA) 1,3-Isobenzofurandione, 3a,4,7,7a-tetrahydro- Tetrahydrophthalsureanhydrid 1,2,3,6-tetrahydrophthalicanhydride[qr] 1,3-Isobenzofurandione, 3a,4,7,7a-tetrahydro-, cis- 1,3-isobenzofurandione,3a,4,7,7a-tetrahydro-[qr] 3a,4,7,7a-tetrahydro-1,3-benzofurandione 3a,4,7,7a-tetrahydro-3-isobenzofurandione 3-Isobenzofurandione,3a,4,7,7a-tetrahydro-1 4-Cyclohexene-1,2-dicarboxylic acid anhydride 4-Cyclohexene-1,2-dicarboxylic anhydride, cis- 4-cyclohexene-1,2-dicarboxylicacidanhydride 4-cyclohexene-1,2-dicarboxylicanhydride[qr] Anhydrid kyseliny tetrahydroftalove anhydridetetrahydrophtalique anhydridkyselinytetrahydroftalove anhydridkyselinytetrahydroftalove[czech][qr] Butadiene-maleic anhydride adduct butadiene-maleicanhydrideadduct Cyclohex-4-en-1,2-dicarbonsaeureanhydrid Cyclohex-4-en-1,2-dicarboxylic acid anhydride Cyclohex-4-ene-1,2-dicarboxylic anhydride delta(4)-tetrahydrophthalicanhydride delta(Sup4)-Tetrahydrophthalic anhydride delta(sup4)-tetrahydrophthalicanhydride delta(sup4)-tetrahydrophthalicanhydride[qr] delta-4-Tetrahydrophthalic anhydride Maleic anhydride adduct of butadiene maleicanhydrideadductofbutadiene maleicanhydrideadductofbutadiene[qr] Memtetrahydro phtalic anhydride memtetrahydrophtalicanhydride[qr] Phthalic anhydride, 1,2,3,6-tetrahydro- phthalicanhydride,1,2,3,6-tetrahydro-[qr] Tetrahydrophthalic Anhydride (THPA) 4,7-Dihydroisobenzofuran-1,3(3aH,7aH)-dione 1,2,3,6-Tetrahydrophthalic anhydride 1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE FOR cis-1,2,3,6-Tetrahydrophthalic anhydrid 1,2,3,6-Tetrahydrophthalic acid anhydride 1,2,3,6-tetrahydrophthalicacidanhydride 1,2,3,6-tetrahydro-phthalicanhydrid CIS-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE; >98% cis-cyclohex-4-ene-1,2-dicarboxylic anhydride rikacidth[qr] Tetrahydroftalanhydrid tetrahydroftalanhydrid[czech][qr] tetrahydrophthalicacidanhydride[qr] tetrahydrophthalicanhydrides thpa[qr] Δ4-Tetrahydrophthalic anhydride 1,2,3,6-TetrahydrophthaL 3,6-Cyclopropylene-&Delta tetrahydrophthalic TETRAHYDROPHTHALIC ANHYDRIDE 85-43-8 Pyridines