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Methyl-5-norbornene-2,3-dicarboxylic anhydride

Methyl-5-norbornene-2,3-dicarboxylic anhydride Structure
CAS No.
25134-21-8
Chemical Name:
Methyl-5-norbornene-2,3-dicarboxylic anhydride
Synonyms
MNA;NMA;XMNA;mea610;MEA 610;tk10524;epicurenma;Epicure NMA;kayahardmcd;Kayahard MCD
CBNumber:
CB9163814
Molecular Formula:
C10H10O3
Molecular Weight:
178.18
MOL File:
25134-21-8.mol
MSDS File:
SDS
Modify Date:
2024/7/24 17:31:20

Methyl-5-norbornene-2,3-dicarboxylic anhydride Properties

Boiling point 140°C (10 mmHg)
Density 1.232 g/mL at 25 °C(lit.)
vapor density 6.1 (20 °C, vs air)
vapor pressure 5 mm Hg ( 120 °C)
refractive index n20/D 1.506(lit.)
Flash point >230 °F
storage temp. room temp
solubility Miscible with acetone, benzene, naphtha and xylene.
form Oily Liquid
pka 4.42[at 20 ℃]
color Clear light yellow
Water Solubility REACTS
Sensitive Moisture Sensitive
BRN 162395
LogP -4.01 at 20℃
CAS DataBase Reference 25134-21-8(CAS DataBase Reference)
NIST Chemistry Reference 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-(25134-21-8)
EPA Substance Registry System 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aR,4S,7R,7aS)-rel- (25134-21-8)

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H302-H314-H317-H334
Precautionary statements  P280-P301+P312+P330-P301+P330+P331-P303+P361+P353-P305+P351+P338
Hazard Codes  Xn,C
Risk Statements  22-36/37/38-42-34
Safety Statements  39-45-36/37/39-26
RIDADR  UN 3265 8/PG 2
WGK Germany  3
RTECS  RB9100000
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29172000
Toxicity LD50 oral in rat: 914mg/kg
NFPA 704
1
3 0

Methyl-5-norbornene-2,3-dicarboxylic anhydride price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 45347 Epoxy embedding medium, hardener MNA ≥95.0% 25134-21-8 250ML ₹6191.9 2022-06-14 Buy
Sigma-Aldrich(India) 45347 Epoxy embedding medium, hardener MNA ≥95.0% 25134-21-8 1L ₹12102.35 2022-06-14 Buy
Sigma-Aldrich(India) 235431 Methyl-5-norbornene-2,3-dicarboxylic anhydride 90% 25134-21-8 250G ₹4113.5 2022-06-14 Buy
Sigma-Aldrich(India) 235431 Methyl-5-norbornene-2,3-dicarboxylic anhydride 90% 25134-21-8 1KG ₹13812.7 2022-06-14 Buy
TCI Chemicals (India) M0690 Methyl-5-norbornene-2,3-dicarboxylic Anhydride (mixture of isomers) min. 80.0 %(total of isomer) 25134-21-8 25G ₹1500 2022-05-26 Buy
Product number Packaging Price Buy
45347 250ML ₹6191.9 Buy
45347 1L ₹12102.35 Buy
235431 250G ₹4113.5 Buy
235431 1KG ₹13812.7 Buy
M0690 25G ₹1500 Buy

Methyl-5-norbornene-2,3-dicarboxylic anhydride Chemical Properties,Uses,Production

Chemical Properties

clear light yellow oily liquid

Uses

Methyl-5-norbornene-2,3-dicarboxylic anhydride is used as a curing agent in epoxy resins and in the preparation of vertically aligned and penetrated carbon nanotube/polymer film. It serves as an intermediate in polyesters, alkyd resins and plasticizers. It is also used in electrical laminating and filament-winding. Further, it is used in the preparation of methyl nadimides endcapped resins based on tris(3-aminophenyl)phosphine oxide. It is utilized in the flame retarding treatment.

General Description

additional information see 45359 Epoxy Embedding Medium kit

Purification Methods

Purify the anhydride by thin layer chromatography on Al2O3 (previously boiled in EtOAc) and eluted with hexane/*C6H6 (1:2) then recrystallise it from *C6H6/hexane. The free acid has m 118.5-119.5o. [Miranov et al. Tetrahedron 19 1939 1963, Beilstein 17/11 V 199.]

Methyl-5-norbornene-2,3-dicarboxylic anhydride Preparation Products And Raw materials

Global( 310)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
CHEMSWORTH +91-261-2397244 New Delhi, India 6707 30 Inquiry
Otto Chemie Pvt. Ltd. +91 9820041841 Mumbai, India 5873 58 Inquiry
TCI Chemicals (India) Pvt. Ltd. 1800 425 7889 New Delhi, India 6778 58 Inquiry
Puyang Huicheng Electronic Materials Co., Ltd. +86-0393-+86-0393-8910800 +8615839383373 China 524 58 Inquiry
Hebei Guanlang Biotechnology Co,.LTD +86-19930503253; +8619930503252 China 5835 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 16209 58 Inquiry
Henan Tianfu Chemical Co.,Ltd. +86-0371-55170693 +86-19937530512 China 21669 55 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29897 58 Inquiry
Shenzhen Nexconn Pharmatechs Ltd +86-755-89396905 +86-15013857715 China 10318 58 Inquiry
Hebei Guanlang Biotechnology Co., Ltd. +86-19930503282 China 8826 58 Inquiry
NADIC METHYL ANHYDRIDE NADIC(R) METHYL ANHYDRIDE NADIC(TM) METHYL ANHYDRIDE NMA MNA 3-dione,3a,4,7,7a-tetrahydromethyl-7-methanoisobenzofuran-1 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aalpha,4alpha,7alpha,7aalpha)- 4,7-methanoisobenzofuran-1,3-dione,3a,4,7,7a-tetrahydromethyl-,(3aalpha,4al 5-Norbornene-2,3-dicarboxylic anhydride, methyl- 7alpha,7aalpha)-ph 7-Methanoisobenzofuran-1,3-dione,3a,4,7,7a-tetrahydromethyl-4 endo-Methylenemethyltetrahydrophthalic anhydride endo-methylenemethyltetrahydrophthalicanhydride Epicure NMA epicurenma hardenerhy906 Kayahard MCD kayahardmcd MEA 610 mea610 Methyl-3,6-endomethylene-1,2,3,6-tetrahydrophthalicanhydride methyl-5-norbornene-2,3-dicarboxylicanhydride,mixtureofisomers methyl-5-norbornene-3-dicarboxylicanhydride Methylbicyclo(2.2.1)heptene-2,3-dicarboxylic anhydride isomers methylbicyclo(2.2.1)heptene-2,3-dicarboxylicanhydride methylbicyclo(2.2.1)heptene-2,3-dicarboxylicanhydrideisomers Methylbicyclo[2.2.1]Heptene-2,3-dicarboxylic anhydride Methylendic anhydride Methylbicyclo[2.2.1]heptene-2,3-carboxylic anhydride 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aR,4S,7R,7aS)-rel- Methyl-5-norbornene-2,3-dicarboxylic anhydride, mixture of isomers, tech maleic anhydride/ methylcyclopentadiene adduct Epon(R) MNA substitute, Methyl nadic anhydride, Methyl-5-norbornene-2,3-dicarboxylic anhydride, Methylnorbornene-2,3-dicarboxylic acid anhydride, MNA ,7-methanoisobenzofuran-1,3-dione,3a,4,7,7a-tetrahydromethyl- METHYL NADIC ANHYDRIDE (MNA) NADIC METHYL ANHYDRIDE (MNA: NMA) 3a,4,7,7a-tetrahydromethyl-4,7-Methanoisobenzofuran-1,3-dione Nadic methyl anhydride (MNA) Methyl-5-norbornene-2,3-dicarboxylic anhydride, 95%, mixture of isomers Kayahard NMA 3a,4,7,7a-tetrahydromethyl-4,7-Methanoisobenzofuran-1,3-d 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydromethyl-, (3aα,4α,7α,7aα)- Methyl-5-norbornene-2,3-dicarboxylic anhydride ,95% Methyl-5-norbornene-2,3-dicarboxylic anhydride Ⅲ Modified methyl-5-norbornene-2,3-dicarboxylic anhydride Ⅱ Epoxy embedding medium, hardener MNA,Epon MNA substitute, MNA, Methyl nadic anhydride, Methyl-5-norbornene-2,3-dicarboxylic anhydride, Methylnorbornene-2,3-dicarboxylic acid anhydride Methyl-5-norbornene-2,3-dicarboxylic anhydride, Mixture of isoMers, 95% 250GR methylendicanhydride Methylnadic acid anhydride tk10524 XMNA 1,2,3,6-tetrahydromethyl-3,6-methanophthalic anhydride Nadic Methyl Anhydride (NMA) Methyl Anhydride METHYLNORBORNENE-2,3-DICARBOXYLIC ANHY-D RIDE, MIXT. OF ISOM METHYLNORBORNENE-2,3-DICARBOXYLIC ACID ANHYDRIDE METHYLNORBORNENE-2,3-DICARBOXYLIC ANHYDRIDE METHYL NADIC ANHYDRIDE