Methanesulfonic anhydride

- CAS No.
- 7143-01-3
- Chemical Name:
- Methanesulfonic anhydride
- Synonyms
- 7143/1/3;methylsulfonyl methanesulfonate;Mesic anhydride;Mesyl anhydride;METHANESULPHONIC ANHYDRIDE;Methanesulfonyl anhydride;Methanesulfonic acid, anhydride;methanesulfonyl methanesulfonate;SKL265;7143-01-3-
- CBNumber:
- CB1109276
- Molecular Formula:
- C2H6O5S2
- Molecular Weight:
- 174.19
- MOL File:
- 7143-01-3.mol
- MSDS File:
- SDS
- Modify Date:
- 2025/1/27 9:38:02
Melting point | 64-67 °C (lit.) |
---|---|
Boiling point | 125 °C/4 mmHg (lit.) |
Density | 1,36 g/cm3 |
vapor density | 3.3 (vs air) |
refractive index | 1.5300 (estimate) |
Flash point | 125°C/4mm |
storage temp. | Store at <= 20°C. |
solubility | Soluble in organic solvents. |
form | Powder, Crystals and/or Chunks |
color | White to light brown to gray |
Sensitive | Moisture Sensitive |
BRN | 972316 |
InChIKey | IZDROVVXIHRYMH-UHFFFAOYSA-N |
CAS DataBase Reference | 7143-01-3(CAS DataBase Reference) |
NIST Chemistry Reference | Methanesulfonic anhydride(7143-01-3) |
EPA Substance Registry System | Methanesulfonic acid, anhydride (7143-01-3) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS05 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 14-35 | |||||||||
Safety Statements | 26-36/37/39-45 | |||||||||
RIDADR | UN 3261 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 3-10 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29041000 | |||||||||
NFPA 704 |
|
Methanesulfonic anhydride price More Price(9)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich(India) | 269190 | Methanesulfonic anhydride 97% | 7143-01-3 | 5G | ₹1909.55 | 2022-06-14 | Buy |
Sigma-Aldrich(India) | 269190 | Methanesulfonic anhydride 97% | 7143-01-3 | 25G | ₹4874.1 | 2022-06-14 | Buy |
ALFA India | ALF-A13328-30 | Methanesulfonic anhydride, 98% | 7143-01-3 | 250g | ₹58857 | 2022-05-26 | Buy |
ALFA India | ALF-A13328-18 | Methanesulfonic anhydride, 98% | 7143-01-3 | 50g | ₹9990 | 2022-05-26 | Buy |
ALFA India | ALF-A13328-14 | Methanesulfonic anhydride, 98% | 7143-01-3 | 25g | ₹3790 | 2022-05-26 | Buy |
Methanesulfonic anhydride Chemical Properties,Uses,Production
Chemical Properties
white to light brown to grey powder, crystals and/
Uses
Methanesulfonic anhydride is used to prepare methylsulfonyl esters called as mesylates. It finds application in the reaction of aromatic alkylation. It reacts with dimethylsulfoxide to get sulfoxonium complex, which is a useful oxidizing agent.
Preparation
Methanesulfonic anhydride may be prepared by the dehydration of methanesulfonic acid with phosphorus pentoxide.
P2O5 + 6 CH3SO3H → 3 (CH3SO2)2O + 2 H3PO4
Methanesulfonic anhydride can be purified by distillation under vacuum (distillation of a solid) or by recrystallized from Methyl tert-butyl ether/toluene.
Safety
Not only is Methanesulfonic anhydride corrosive, posing potential risks to skin, eyes, and mucous membranes, but it is also sensitive to moisture. As a hygroscopic substance, exposure to water can lead to degradation, compromising its efficacy and safety. Therefore, meticulous storage conditions are paramount to ensure the stability of the compound. To safeguard the integrity of methanesulfonic anhydride, storing it in a cool and dry environment is recommended. The storage facility should be adequately ventilated to prevent the accumulation of vapors and maintain optimal conditions for the compound. Furthermore, the storage containers must be tightly sealed to prevent moisture ingress and subsequent degradation.
Methanesulfonic anhydride Preparation Products And Raw materials
Raw materials
Preparation Products
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JSK Chemicals | +919879767970 | Gujarat, India | 3756 | 58 | Inquiry |
CLEARSYNTH LABS LTD. | +91-22-45045900 | Hyderabad, India | 6257 | 58 | Inquiry |
Supplier | Advantage |
---|---|
sheetalchemicals | 58 |
SURVIVAL TECHNOLOGIES LIMITED | 58 |
DMCC Specialty Chemical Co Ltd | 58 |
Vardhaman P Golechha | 58 |
SYNGREEN LIFESCIENCES PVT.LTD | 58 |
ALS INDIA LIFE SCIENCES | 58 |
Om Industries | 58 |
Stratechem Pvt Ltd | 58 |
JSK Chemicals | 58 |
CLEARSYNTH LABS LTD. | 58 |
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