4,4'-(Hexafluoroisopropylidene)diphthalic anhydride

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride Properties

Melting point	244-247 °C(lit.)
Boiling point	494.5±45.0 °C(Predicted)
Density	1.697±0.06 g/cm3(Predicted)
vapor pressure	7.7Pa at 20℃
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	powder to crystal
color	White to Almost white
Water Solubility	Miscible with water.
Sensitive	Moisture Sensitive
BRN	7057916
InChI	InChI=1S/C19H6F6O6/c20-18(21,22)17(19(23,24)25,7-1-3-9-11(5-7)15(28)30-13(9)26)8-2-4-10-12(6-8)16(29)31-14(10)27/h1-6H
InChIKey	QHHKLPCQTTWFSS-UHFFFAOYSA-N
SMILES	C(C1C=CC2C(=O)OC(=O)C=2C=1)(C1C=CC2C(=O)OC(=O)C=2C=1)(C(F)(F)F)C(F)(F)F
LogP	5.59 at 25℃
CAS DataBase Reference	1107-00-2(CAS DataBase Reference)
EPA Substance Registry System	1,3-Isobenzofurandione, 5,5'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]bis- (1107-00-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS07

Signal word

Danger

Hazard statements

H314-H335

Precautionary statements

P260-P271-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338

Hazard Codes

C,Xi

Risk Statements

34

Safety Statements

26-36/37/39-45

RIDADR

UN 3261 8/PG 2

WGK Germany

1

F

21

Hazard Note

Irritant

TSCA

T

HazardClass

8

PackingGroup

II

HS Code

29173990

NFPA 704

	0
3		0

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride price More Price(7)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich(India)	386448	4,4′-(Hexafluoroisopropylidene)diphthalic anhydride 99%	1107-00-2	5G	₹4178.45	2022-06-14	Buy
Sigma-Aldrich(India)	386448	4,4′-(Hexafluoroisopropylidene)diphthalic anhydride 99%	1107-00-2	25G	₹21909.8	2022-06-14	Buy
TCI Chemicals (India)	H1438	4,4'-(Hexafluoroisopropylidene)diphthalic Anhydride (purified by sublimation) min. 99.0 %	1107-00-2	1G	₹1800	2022-05-26	Buy
TCI Chemicals (India)	H0771	4,4'-(Hexafluoroisopropylidene)diphthalic Anhydride min. 98.0 %	1107-00-2	5G	₹3400	2022-05-26	Buy
TCI Chemicals (India)	H1438	4,4'-(Hexafluoroisopropylidene)diphthalic Anhydride (purified by sublimation) min. 99.0 %	1107-00-2	5G	₹4000	2022-05-26	Buy

Product number	Packaging	Price	Buy
386448	5G	₹4178.45	Buy
386448	25G	₹21909.8	Buy
H1438	1G	₹1800	Buy
H0771	5G	₹3400	Buy
H1438	5G	₹4000	Buy

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride Chemical Properties,Uses,Production

Description

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride (6FDA) is an aromatic organofluorine compound that is utilized as a dianhydride monomer. It is among the most frequently used dianhydride monomers due to its exceptional balance of mechanical and electrical properties. It is particularly prominent in the construction of colorless and transparent polyimides.

Application

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride (6FDA) can be used:
(1) With APAF as dianhydride monomer, it can be used to prepare thermally rearranged polybenzoxazole (TR-PBO) gas separation membranes by thermal rearrangement reaction at 450°C. The product TR-PBO membrane has excellent gas permeation selectivity and high permeability. the H2/CH4 separation performance of APAF-6FDA membrane is close to the Robertson upper limit of 2008^[5].
(2) Used as a raw material for the preparation of thermoplastic fluorinated polyimide resin.^[6].
(3) Polymers for electronic materials;
(4) Polyimide materials. These materials can be used as substrates for wearable devices and as multilayer insulation materials in order to protect against space dust, cosmic rays and satellite debris^[7].

General Description

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride (6FDA) consists of two phthalic anhydrides bridged with a perfluoroisopropyl group and is mainly used in the synthesis of polyimides. Polyimides from 6FDA are commonly used in hybrid matrix membranes. The polyimide matrix provides good dispersion of the filler and can be loaded with up to 50 wt% filler. These membranes have been used for highly selective gas separation (CO2/CH4) and solar cell encapsulation (power conversion efficiency of silicon-based solar cells increased from 14.67% to 15.64%).

Advantages

The 4,4'-(hexafluoroisopropylidene) diphthalic anhydride (6FDA) monomer contains rigid benzene ring groups, and so, the resulting polymer has excellent mechanical properties. 6FDA contained a stable benzene ring and fluorine atoms. Due to the strong electronegativity of the fluorine atoms and the stability of the benzene ring, the produced polycarbonate had better thermal stability[1-2].

Precautions

The storage precautions for 6FDA are as follows: The chemical must be stored in a cool and well-ventilated warehouse, away from sources of heat and fire. Proper sealing is required to prevent contact with air, and it should always be kept separate from oxidants, edible chemicals, and acids. The storage area should have explosion-proof lighting and ventilation facilities and must not allow any mechanical equipment or tools that may cause sparks to prevent accidents. Leakage emergency treatment equipment and suitable storage materials must be readily available in the storage area.

References

[1] Yile Zhang. “Poly(propylene carbonate) networks with excellent properties: Terpolymerization of carbon dioxide, propylene oxide, and 4,4?-(hexafluoroisopropylidene) diphthalic anhydride.” e-Polymers 21 1 (2021): 511–519.
[2] C. D. Simone, D. A. Scola. “Phenylethynyl End-Capped Polyimides Derived from 4,4‘-(2,2,2-Trifluoro-1-phenylethylidene)diphthalic Anhydride, 4,4‘-(Hexafluoroisopropylidene)diphthalic Anhydride, and 3,3‘,4,4‘-Biphenylene Dianhydride: Structure?Viscosity Relationship.” Macromolecules 36 18 (2003): 6780–6790.
[3] MARYANNE MORES Patrick E C. Polyimidines. XI. Polyimidines from 3,3′,4,4′-benzophenonetetracarboxylic dianhydride and 4,4′-(hexafluoroisopropylidene) diphthalic anhydride[J]. Journal of Polymer Science Part A: Polymer Chemistry, 1990, 28 4: 811-823. DOI:10.1002/pola.1990.080280410.
[4] HUI WU Hezhou L Hua Li. Synthesis and Properties of a High-Molecular-Weight Polyimide Based on 4, 4’-(hexafluoroisopropylidene) Diphthalic Anhydride[J]. Advanced Materials Research, 2012, 35 1: 742-746. DOI:10.4028/www.scientific.net/AMR.550-553.742.
[5] XU LIU. Molecular design of free volume structure in thermally rearranged polybenzoxazole membranes for gas separation studied by positron annihilation[J]. Journal of Polymer Science, 2024. DOI:10.1002/pol.20240229.
[6] GAOJIE WU. Design and preparation of thermoplastic polyimides with high transmittance based on 4,4′-(4,4′-isopropyldiphenoxy)bis(phthalic anhydride) (BPADA)[J]. European Polymer Journal, 2023. DOI:10.1016/j.eurpolymj.2022.111798.
[7] YOUNG NAM KIM, YONG CHAE JUNG* Challenge for Trade-Off Relationship between the Mechanical Property and Healing Efficiency of Self-Healable Polyimide[J]. ACS Applied Materials & Interfaces, 2023. DOI:10.1021/acsami.3c12594.

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride Preparation Products And Raw materials

Raw materials

4,4'-(HEXAFLUOROISOPROPYLIDENE)DIPHTHALIC ACID 2,2-Bis(3,4-dimethylphenyl)hexafluoropropane

Preparation Products

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride Suppliers

Global( 432)Suppliers

Supplier	Tel	Country	ProdList	Advantage	Inquiry
TCI Chemicals (India) Pvt. Ltd.	1800 425 7889	New Delhi, India	6778	58	Inquiry
Clearsynth Labs	91-22-45045900	Maharashtra, India	3889	58	Inquiry
Gharda Chemicals Limited	08048372602Ext 584	Maharashtra, India	31	58	Inquiry
A.J Chemicals	91-9810153283	New Delhi, India	6124	58	Inquiry
Pharmaffiliates Analytics and Synthetics P. Ltd	+91-172-5066494	Haryana, India	6773	58	Inquiry
Pharma Affiliates	172-5066494	Haryana, India	6761	58	Inquiry
Shanghai Z&T Chemical Co., Ltd	+86-021-33561011 +8613818804961	China	402	58	Inquiry
Heynova (Shanghai) New Material Technology CO., Ltd	+86-17821320848; +8617821320848	China	179	58	Inquiry
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.	+86-18222270857 +86-18222265956	China	64	58	Inquiry
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	China	7232	58	Inquiry

Supplier	Advantage
TCI Chemicals (India) Pvt. Ltd.	58
Clearsynth Labs	58
Gharda Chemicals Limited	58
A.J Chemicals	58
Pharmaffiliates Analytics and Synthetics P. Ltd	58
Pharma Affiliates	58
Shanghai Z&T Chemical Co., Ltd	58
Heynova (Shanghai) New Material Technology CO., Ltd	58
CHINATECH(TIANJIN) CHEMICAL CO.,LTD.	58
Shanghai UCHEM Inc.	58

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride Spectrum

4,4'-(Hexafluoroisopropylidene)diphthalic anhydride(1107-00-2)MS 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride(1107-00-2)¹HNMR 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride(1107-00-2)IR1 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride(1107-00-2)IR2 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride(1107-00-2)Raman

1107-00-2(4,4'-(Hexafluoroisopropylidene)diphthalic anhydride)Related Search:

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2,2-BIS(4-CARBOXYPHENYL)HEXAFLUOROPROPANE 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride 4-Ethylbenzoic acid Methyl 4-tert-butylbenzoate 2,5-Dimethylbenzoic acid

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4,4'-(Hexafluoroisop [2,2,2-Trifluoro-1-(trifluoroMethyl)ethylidene]diphthalic anhydride 2,2-Bis(3,4-anhydrodicarboxyphenyl)-hexafluoropropane(6FDA) 2,2-Bis(1,3-dihydro-1,3-dioxobenzo[c]furan-5-yl)hexafluoropropane 99% 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride, 5,5'-(1,1,1,3,3,3-Hexafluoropropane-2,2-diyl)bis(2-benzofuran-1,3-dione) 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride SynonyMs 2,2-Bis(3,4-anhydrodicarboxyphenyl)hexafluoropropane 5,5'-(Perfluoropropane-2,2-diyl)bis(isobenzofuran-1,3-dione) 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride(6FDA) 4,4'-(Hexafluoroisopropylidene)diphthalic Anhydride (purified by sublimation) 4,4,4'-(Hexafluoroisopropylidene)diphthalic anhydride (6FDA) 5-[2-(1,3-Dioxo-2-benzofuran-5-yl)-1,1,1,3,3,3-hexafluoropropan-2-yl]-2-benzofuran-1,3-dione 1,1,1,3,3,3-Hexafluoro-2,2-bis(1,3-dihydro-1,3-dioxoisobenzofuran-5-yl)propane 2,2-Bis(1,3-dihydro-1,3-dioxoisobenzofuran-5-yl)-1,1,1,3,3,3-hexafluoropropane 4,4'-(Hexafluoroisopropylidene)bisphthalic acid-1,2:1',2'-dianhydride 5,5'-(1,1,1,3,3,3-Hexafluoropropane-2,2-diyl)bis(1,3-isobenzofurandione) 5,5'-[2,2,2-Trifluoro-1-(trifluoromethyl)ethylidene]bis(1,3-isobenzofurandione) 2,2-Bis(1,3-dihydro-1,3-dioxobenzo[c]furan-5-yl)hex 2,2'-BIS(3,4-ANHYDRODICARBOXYLPHENYL)HEXAFLUOROPROPANE 2,2-BIS(3,4-ANHYDRODICARBOXYPHENYL)HEXAFLUOROPROPANE 5-[1-(1,3-dioxoisobenzofuran-5-yl)-2,2,2-trifluoro-1-(trifluoromethyl)ethyl]isobenzofuran-1,3-dione 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride 1107-00-2 6FDA 2,2-Bis(3,4-anhydrodicarboxyphenyl)hexafluoropropane 1107-00-2 6FDA HFDA 2,2-BIS(3,4-DICARBOXYPHENYL)-1,1,1,3,3,3-HEXAFLUOROPROPANE DIANHYDRIDE 2,2'-BIS-(3,4-DICARBOXYPHENYL)HEXAFLUOROPROPANE DIANHYDRIDE 4,4'-(HEXAFLUOROISOPROPYLIDENE)BIS-PHTHALIC ANHYDRIDE 4,4'-(HEXAFLUOROISOPROPYLIDENE)DIPHTHALIC ANHYDRIDE 6f-dianhydride 6FDA DAIKIN YZ0002 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride 99% 4,4'-(Hexafluoroisopropylidene)diphthalicanhydride99% 4,4′-(2,2,2-Trifluor-1-(trifluormethyl)ethyliden)diphthalsureanhydrid 4,4'-(Hexafluoroisopropylidene)diphthalic 4,4''-(Hexafluoroisopropylidene)-2,2-bis-(phthalic anhydride) 4,4'-[2,2,2-trifluoro-1-(trifluoromethyl)ethylidene]diphthalic anhydride HEXAFLUOROISOPROPYLIDENE-2,2-BISPHTHALIC ANHYDRIDE 2,2'-Bis(3,4-dicarboxyphenyL uoropropane dianhydride 4,4’(Hexafluoroisopropylidene)Bisphthalic Dianhydride （6Fda） 4,4'-(Hexafluoroisopropylidene)diphthalicAnhydride> 4,4'-(Hexafluoroisopropylidene)diphthalicAnhydride(purifiedbysublimation)> 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride, 99%, for synthesis High purity 6FDA 4,4'-(Hexafluoroisopropylidene)diphthalicanhydride，98% 2,2-bis(3,4- ,4'-(Hexafluoroisopropylidene)diphthalic anhydride ,5'-(Hexafluoroisopropylidene)diphthalic anhydride Hexafluorodianhydride (6FDA) 6f-dianhydride(6FDA) 2,2-Bis(3,4-anhydrodicarboxyphenyl) 6f-dianhydride,4，4，-（Hexafluoroisopropylidene）diphthalic anhydride Hexafluorodianhydride 4,4'-(Hexafluoroisopropylidene 4,4'-(Hexafluoroisopropylidene) diphthalic anhydride(6FDA) 5,5'-(Perfluoropropane-2,2-diyl)bis(isobenzofuran-1,3-dione) 4,4'-(Hexafluoroisopropylidene)diphthalic anhydride 1107-00-2