4-Ethylbenzoic acid
- CAS No.
- 619-64-7
- Chemical Name:
- 4-Ethylbenzoic acid
- Synonyms
- 4-ethylbenzoate;The ethyl benzoate;4-ETHYLBENZOIC ACID;P-ETHYLBENZOIC ACID;RARECHEM AL BO 1281;4-Ethylbenzoesaeure;4-EthylbenzoicAcid97%;4-EthylbenzoicAcid>Benzoic acid, p-ethyl-;Benzoic acid, 4-ethyl-
- CBNumber:
- CB3153435
- Molecular Formula:
- C9H10O2
- Molecular Weight:
- 150.17
- MOL File:
- 619-64-7.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/4/24 17:21:45
| Melting point | 112-113 °C(lit.) |
|---|---|
| Boiling point | 271.51°C (estimate) |
| Density | 1.0937 (estimate) |
| refractive index | 1.5188 (estimate) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Chloroform (Sparingly), Methanol (Slightly) |
| form | Powder |
| pka | pK1:4.35 (25°C) |
| color | White to beige |
| BRN | 2041840 |
| InChIKey | ZQVKTHRQIXSMGY-UHFFFAOYSA-N |
| CAS DataBase Reference | 619-64-7(CAS DataBase Reference) |
| NIST Chemistry Reference | 4-Ethylbenzoic acid(619-64-7) |
| EPA Substance Registry System | Benzoic acid, 4-ethyl- (619-64-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H319 | |||||||||
| Precautionary statements | P264-P280-P305+P351+P338-P337+P313 | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 22-36/37 | |||||||||
| Safety Statements | 22-24/25-37/39-26 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| HS Code | 29163900 | |||||||||
| NFPA 704 |
|
4-Ethylbenzoic acid price More Price(6)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 191280 | 4-Ethylbenzoic acid 99% | 619-64-7 | 5G | ₹1634.58 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 191280 | 4-Ethylbenzoic acid 99% | 619-64-7 | 25G | ₹3669.68 | 2022-06-14 | Buy |
| ALFA India | ALF-A10235-30 | 4-Ethylbenzoic acid, 99% | 619-64-7 | 250g | ₹16194 | 2022-05-26 | Buy |
| ALFA India | ALF-A10235-18 | 4-Ethylbenzoic acid, 99% | 619-64-7 | 50g | ₹7720 | 2022-05-26 | Buy |
| ALFA India | ALF-A10235-09 | 4-Ethylbenzoic acid, 99% | 619-64-7 | 10g | ₹2613 | 2022-05-26 | Buy |
4-Ethylbenzoic acid Chemical Properties,Uses,Production
Chemical Properties
It is a white to beige powder with a melting point of 112-113℃. It is not soluble in water, but can be dissolved in benzene and toluene.
Uses
4-Ethylbenzoic acid was used in the synthesis of ethyl 4-vinyl-α-cyano-β-phenylcinnamate. It was also used to functionalize the edge of “pristine” graphite in the presence of polyphosphoric acid/phosphorus pentoxide.
Application
4-Ethylbenzoic acid has various applications such as being used as an intermediate in the production of pesticide insecticides, including tebufenozide and methoxyfenozide, as well as an initiator of carbon nanotube materials. Additionally, it can also use as an intermediate in the production of liquid crystals.
Preparation
The preparation of 4-ethylbenzoic acid can be done in the following steps:
1. Add ethylbenzene and trichloroacetaldehyde in the reaction kettle.
2. Add anhydrous aluminum trichloride in batches at 0 °C.
3. Stir and react at -10 ~ 0 °C for 2 hours after the addition.
4. Add dilute hydrochloric acid to the mixed solution to decompose the remaining aluminum trichloride.
5. Wash with NaHCO3 and water.
6. Distill the organic layer to recover ethylbenzene.
7. Distill to obtain p-ethylbenzene-2,2,2-trichloroethanol.
8. Dissolve the trichloroethanol in methanol.
9. Add NaOH solution and stir.
10. Add dropwise 30% hydrogen peroxide aqueous solution to the mixture.
11. Stir until the trichloroethanol disappears.
12. Acidify with HCl to obtain crystalline 4-ethylbenzoic acid.
General Description
4-Ethylbenzoic acid reacts with lanthanum nitrate in aqueous solution to yield the polymer catena-poly[[aqua(4-ethylbenzoic acid-κO)lanthanum(III)]-tri-μ-4-ethylbenzoato].
4-Ethylbenzoic acid Preparation Products And Raw materials
Raw materials
1of2
chevron_rightPreparation Products
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| SYNOVA CHEMICALS | +91-9920741772 +91-9920741772 | Mumbai, India | 428 | 58 | Inquiry |
| BASR Fine Chemicals Pvt. Ltd. | +91-9848230391 +91-9848230391 | Telangana, India | 908 | 58 | Inquiry |
| CHEMSWORTH | +91-261-2397244 | New Delhi, India | 6707 | 30 | Inquiry |
| A.J Chemicals | 91-9810153283 | New Delhi, India | 6124 | 58 | Inquiry |
| TCI Chemicals (India) Pvt. Ltd. | 1800 425 7889 | New Delhi, India | 6778 | 58 | Inquiry |
| Alfa Aesar | 1 800 209 7001 | Maharashtra, India | 6913 | 58 | Inquiry |
| Reax Chemicals | 08048372701Ext 416 | Hyderabad, India | 4223 | 58 | Inquiry |
| Basr Fine Chemicals Private Limited | 08068442227Ext 547 | Hyderabad, India | 632 | 58 | Inquiry |
| QINGDAO HONG JIN CHEMCIAL CO.,LTD. | 532-83657313 | China | 228 | 58 | Inquiry |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | China | 12459 | 58 | Inquiry |
| Supplier | Advantage |
|---|---|
| SYNOVA CHEMICALS | 58 |
| BASR Fine Chemicals Pvt. Ltd. | 58 |
| CHEMSWORTH | 30 |
| A.J Chemicals | 58 |
| TCI Chemicals (India) Pvt. Ltd. | 58 |
| Alfa Aesar | 58 |
| Reax Chemicals | 58 |
| Basr Fine Chemicals Private Limited | 58 |
| QINGDAO HONG JIN CHEMCIAL CO.,LTD. | 58 |
| Hebei Mojin Biotechnology Co., Ltd | 58 |