EPhos Pd G4

EPhos Pd G4 Structure
CAS No.
2132978-44-8
Chemical Name:
EPhos Pd G4
Synonyms
EPhos Pd G4;EPhos Catalyst;dicyclohexyl-[2-isopropoxy-6-(2,4,6-triisopropylphenyl)phenyl]phosphane (N-methyl-2-phenyl-anilino)-methylsulfonyloxy-palladium;Methanesulfonato{Dicyclohexyl[3-(1-methylethoxy)-2',4',6'-tris(1-methylethyl)-1,1'-biphenyl-2-yl]phosphine}(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);Dicyclohexyl[3-(1-methylethoxy)-2′,4′,6′-tris(1-methylethyl)[1,1′-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium;Methanesulfonato{Dicyclohexyl[3-(1-methylethoxy)-2',4',6'-tris(1-methylethyl)-1,1'-biphenyl-2-yl]phosphine}(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) (Ephos Pd G4)
CBNumber:
CB13375823
Molecular Formula:
C50H70NO4PPdS
Molecular Weight:
918.57
MOL File:
2132978-44-8.mol
Modify Date:
2024/4/24 19:16:04

EPhos Pd G4 Properties

form powder or crystals

EPhos Pd G4 price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 901220 EPhos Pd G4 2132978-44-8 250MG ₹13697.4 2022-06-14 Buy
Sigma-Aldrich(India) 901220 EPhos Pd G4 2132978-44-8 1G ₹32822.7 2022-06-14 Buy
Product number Packaging Price Buy
901220 250MG ₹13697.4 Buy
901220 1G ₹32822.7 Buy

EPhos Pd G4 Chemical Properties,Uses,Production

Uses

Buchwald palladacycle precatalyst with EPhos ligand for Pd-catalyzed C–N cross-coupling between primary amines and aryl halides to form 2-arylaminooxazoles. Catalyst system was reported with NaOPh (CDS001581).
It is a fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations of using the third generation precatalysts. It is air, moisture and thermally-stable and shows good solubility in common organic solvents. BrettPhos Pd G4 is highly useful in cross-coupling reactions. Some of its excellent features include lower catalyst loadings, shorter reaction time, and efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

EPhos Pd G4 Preparation Products And Raw materials

Raw materials

Preparation Products

EPhos Pd G4 Suppliers

Global( 32)Suppliers
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SHANGHAI T&W PHARMACEUTICAL CO., LTD. +86-021-61551413 +8618813727289 China 5738 58 Inquiry
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Wuhan hongde yuexin pharmaceutical technology co. LTD 027-83855391 13657260109 China 3356 58 Inquiry
Henan Shengxiang Pharmatech LTD 15515658315 China 348 58 Inquiry
EPhos Pd G4 Methanesulfonato{Dicyclohexyl[3-(1-methylethoxy)-2',4',6'-tris(1-methylethyl)-1,1'-biphenyl-2-yl]phosphine}(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) (Ephos Pd G4) Dicyclohexyl[3-(1-methylethoxy)-2′,4′,6′-tris(1-methylethyl)[1,1′-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)[2′-(methylamino-κN)[1,1′-biphenyl]-2-yl-κC]palladium EPhos Catalyst Methanesulfonato{Dicyclohexyl[3-(1-methylethoxy)-2',4',6'-tris(1-methylethyl)-1,1'-biphenyl-2-yl]phosphine}(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dicyclohexyl-[2-isopropoxy-6-(2,4,6-triisopropylphenyl)phenyl]phosphane (N-methyl-2-phenyl-anilino)-methylsulfonyloxy-palladium 2132978-44-8