t-BuBrettPhos Palladacycle Gen. 3
- CAS No.
- 1536473-72-9
- Chemical Name:
- t-BuBrettPhos Palladacycle Gen. 3
- Synonyms
- P](methane;N)[1,1’-(Amino-κtbuttphos Pd G3;-biphenyl]-2-yl-κC][[3,6-dimethoxy-2’-tris(1-methylethyl)[1,1’t-BuBrettPhos Palladacycle Gen. 3;t-butylBrettPhos Palladacycle Gen. 3;t-BuBrettPhos Palladacycle Gen. 3 ISO 9001：2015 REACH
- CBNumber:
- CB33052898
- Molecular Formula:
- C44H63NO5PPdS-
- Molecular Weight:
- 855.433481
- MOL File:
- 1536473-72-9.mol
- MSDS File:
- SDS
- Modify Date:
- 2024/3/18 16:05:02
| Melting point | 119-131°C |
|---|---|
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | solid |
| color | brown-green |
| InChIKey | VKLHIPFGYVFUGT-UHFFFAOYSA-N |
| CAS DataBase Reference | 1536473-72-9 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS08 |
|---|---|
| Signal word | Danger |
| Hazard statements | H350i |
| Precautionary statements | P201-P202-P280-P308+P313-P405-P501 |
| WGK Germany | 3 |
t-BuBrettPhos Palladacycle Gen. 3 price More Price(5)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich(India) | 745979 | tBuBrettPhos Pd G3 96% | 1536473-72-9 | 100MG | ₹5783.1 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 745979 | tBuBrettPhos Pd G3 96% | 1536473-72-9 | 500MG | ₹14818.5 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 745979 | tBuBrettPhos Pd G3 96% | 1536473-72-9 | 1G | ₹34570 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 745979 | tBuBrettPhos Pd G3 96% | 1536473-72-9 | 2G | ₹41935.8 | 2022-06-14 | Buy |
| Sigma-Aldrich(India) | 745979 | tBuBrettPhos Pd G3 96% | 1536473-72-9 | 5G | ₹85403.4 | 2022-06-14 | Buy |
t-BuBrettPhos Palladacycle Gen. 3 Chemical Properties,Uses,Production
Uses
tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.
General Description
tBuBrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
t-BuBrettPhos Palladacycle Gen. 3 Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 122)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | Inquiry |
|---|---|---|---|---|---|
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | China | 434 | 58 | Inquiry |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | China | 18656 | 58 | Inquiry |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | China | 1807 | 55 | Inquiry |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | China | 32835 | 60 | Inquiry |
| Accela ChemBio Inc. | +1-858-6993322 | United States | 19751 | 58 | Inquiry |
| career henan chemical co | +86-0371-86658258 +8613203830695 | China | 29820 | 58 | Inquiry |
| SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | China | 5738 | 58 | Inquiry |
| QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD. | +86-0532-8699-9256 +8615254267723 | China | 1410 | 58 | Inquiry |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | China | 13484 | 58 | Inquiry |
| Dideu Industries Group Limited | +86-29-89586680 +86-15129568250 | China | 23430 | 58 | Inquiry |
1536473-72-9(t-BuBrettPhos Palladacycle Gen. 3)Related Search:
Methanesulfonato 2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),DICHLOROMETHANEADDUCT,MIN.98%[T-BUBRETTPHOSPALLADACYCLEGEN.3]
t-BuBrettPhos Palladacycle Gen. 3
Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[t-BuBrettPhos Palladacycle Gen. 3]
Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), dichloromethane adduct, min. 98%[t-BuBrettPhos Palladacycle Gen.
Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II)
[2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethyle
t-butylBrettPhos Palladacycle Gen. 3
Methanesulfonate[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) tBuBrettPhos Pd G3
Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) /
t-BuBrettPhos Pd G3
2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-κP](methanesulfonato-κO)palladium
-(Amino-&kappa
-biphenyl]-2-yl-&kappa
C][[3,6-dimethoxy-2&rsquo
-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-&kappa
P](methane
N)[1,1&rsquo
-tris(1-methylethyl)[1,1&rsquo
t-BuBrettPhos Palladacycle Gen. 3 ISO 9001：2015 REACH
2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-κP](methanesulfonato-κO)palladium (tBuBrettPhos Pd G3)
Methanesulfonato(2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
(tBuBrettPhos Pd G3)
t-ButylXPhos Pd G4 / Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)
tbuttphos Pd G3
methanesulfonato 2-di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(ii)
(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate
ditert-butyl-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane methylsulfonyloxy-(2-phenylanilino)palladium
Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[t-BuBrettPhos Palladacycle Gen. 3]
Methanesulfonato(2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
(tBuBrettPhos Pd G3)
1536473-72-9
C44H62NO5PPdS
C31H49O2PC13H13NO3PdS
Buchwald Ligands&Precatalysts
Buchwald Precatalysts Series
Pd