BrettPhosPalladacycle

BrettPhosPalladacycle Structure
CAS No.
1148148-01-9
Chemical Name:
BrettPhosPalladacycle
Synonyms
BrettPhos Pd G1;BrettPhos precatalyst;BrettPhos Palladacycle;BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct;BrettPhos Pd G1 MTBE adduct;BrettPhos Palladacycle Gen. 1;chloro-(2-phenylethylamino)palladium;[2-(2-aminoethyl)phenyl]palladium(1+);(BrettPhos) palladium(II) phenethylamine chloride;Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-...
CBNumber:
CB52614378
Molecular Formula:
C43H63ClNO2PPd
Molecular Weight:
798.83
MOL File:
1148148-01-9.mol
Modify Date:
2023/4/23 13:52:06

BrettPhosPalladacycle Properties

Melting point 198-204 °C
form Powder
color white

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26

BrettPhosPalladacycle price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 718750 BrettPhos Pd G1, Methyl t-Butyl Ether Adduct may contain up to 1 mole equivalent of MTBE, 97% 100MG ₹8469.3 2022-06-14 Buy
Sigma-Aldrich(India) 718750 BrettPhos Pd G1, Methyl t-Butyl Ether Adduct may contain up to 1 mole equivalent of MTBE, 97% 1148148-01-9 100MG ₹8469.3 2022-06-14 Buy
Sigma-Aldrich(India) 718750 BrettPhos Pd G1, Methyl t-Butyl Ether Adduct may contain up to 1 mole equivalent of MTBE, 97% 1148148-01-9 1G ₹33211.2 2022-06-14 Buy
Sigma-Aldrich 718750 BrettPhos Pd G1, Methyl t-Butyl Ether Adduct may contain up to 1 mole equivalent of MTBE, 97% 5G ₹97469.1 2022-06-14 Buy
Sigma-Aldrich(India) 718750 BrettPhos Pd G1, Methyl t-Butyl Ether Adduct may contain up to 1 mole equivalent of MTBE, 97% 1148148-01-9 5G ₹97469.1 2022-06-14 Buy
Product number Packaging Price Buy
718750 100MG ₹8469.3 Buy
718750 100MG ₹8469.3 Buy
718750 1G ₹33211.2 Buy
718750 5G ₹97469.1 Buy
718750 5G ₹97469.1 Buy

BrettPhosPalladacycle Chemical Properties,Uses,Production

Uses

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyst for:

  • C,N-cross coupling of unprotected 3-halo-2-aminopyridines with primary and secondary amines
  • Amination reaction
  • N-arylation of aminophenols

General Description

BrettPhos Pd G1 is a Buchwald first generation (G1) palladacycle precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The formation of the active Pd(0) species in the G1 precatalyst is easy to generate, requiring merely a deprotonation with a base. The resulting catalyst is very active, even at temperatures down to ?40 °C, and can be used in a variety of cross-coupling protocols.

BrettPhosPalladacycle Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 87)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
ATK CHEMICAL COMPANY LIMITED +undefined-21-51877795 China 32835 60 Inquiry
Accela ChemBio Inc. +1-858-6993322 United States 19751 58 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29820 58 Inquiry
Shaanxi Dideu Medichem Co. Ltd +86-029-81138252 +86-18789408387 China 3958 58 Inquiry
QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD. +86-0532-8699-9256 +8615254267723 China 1410 58 Inquiry
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd +8613580539051 CHINA 21149 58 Inquiry
Shanghai UCHEM Inc. +862156762820 +86-13564624040 China 7255 58 Inquiry
Baoji Guokang Healthchem co.,ltd +8615604608665 15604608665 CHINA 9427 58 Inquiry
Zhuoer Chemical Co., Ltd 02120970332; +8613524231522 China 2905 58 Inquiry
Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II),98% Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II), Min. 98% [BrettPhos Palladacycle] Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoeth Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-Minoethyl)phenyl]palladiuM(II),Min.98%[BrettPhosPalladacycle] (BrettPhos) palladium(II) phenethylamine chloride Dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine-(2-(2-aminoethyl)phenyl)palladium(II) chloride Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(ii) Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-amino CHLORO[2-(DICYCLOHEXYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL][2-(2-AMINOETHYL)PHENYL]PALLADIUM(II),MIN.98%[BRETTPHOSPALLADACYCLEGEN.1] BrettPhos Palladacycle Gen. 1 Chloride (2-dicyclohexylphosphino-3,6-dimethoxy-2 ', 4', 6 '- triisopropyl-1,1' - biphenyl) [2 - (2-aminoethyl phenyl)] palladium (II) Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) / BrettPhos Pd G1 Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]-, (SP-4-4)- Chloro[2-(dicyclohexylphosphino)-2',4',6'-triisopropyl-3,6-dimethoxybiphenyl][2-(2-aminoethyl)phenyl]palladium(II) Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-... BrettPhos Pd G1 / Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) (SP-4-4)-[2-[2-(Amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]palladium Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II) [BrettPhos Palladacycle] [2-(2-aminoethyl)phenyl]palladium(1+) dicyclohexyl-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct BrettPhos Palladacycle BrettPhos precatalyst BrettPhos Pd G1 Dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine-(2-(2-aminoethyl)phenyl)palladium(II) chloride chloro-(2-phenylethylamino)palladium Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) BrettPhos Pd G1 MTBE adduct Chloro[2-(dicyclohexylphosphino)-2’,4’,6’-triisopropyl-3,6-dimethoxybiphenyl][2-(2-aminoethyl)phenyl]palladium(II) Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]-, (SP-4-4)- 1148148-01-9 C43H63ClNO2PPd C48H74ClNO3PPd Buchwald Ligands&Precatalysts Buchwald Precatalysts Series Pd