SPhos Pd G2

SPhos Pd G2 Structure
CAS No.
1375325-64-6
Chemical Name:
SPhos Pd G2
Synonyms
RK1001022;SPhos Pd G2;SPhos Pd G2 catalyst;SPhos Palladacycle Gen.2;SPhos Pd G2 ISO 9001:2015 REACH;2nd Generation SPhos Precatalyst;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl...;chloropalladium(1+),dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane,2-phenylaniline;Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II);Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II)
CBNumber:
CB52686111
Molecular Formula:
C38H45ClNO2PPd
Molecular Weight:
720.63
MOL File:
1375325-64-6.mol
MSDS File:
SDS
Modify Date:
2024/7/26 15:15:06

SPhos Pd G2 Properties

Melting point 218°C (dec.)
form Powder
color white
InChIKey PYMQIHHZINPLDV-UHFFFAOYSA-N
SMILES P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-]

SAFETY

Risk and Safety Statements

WGK Germany  3

SPhos Pd G2 price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 753009 SPhos Pd G2 1375325-64-6 250MG ₹4551 2022-06-14 Buy
Sigma-Aldrich(India) 753009 SPhos Pd G2 1375325-64-6 1G ₹12450 2022-06-14 Buy
Sigma-Aldrich(India) 753009 SPhos Pd G2 1375325-64-6 5G ₹34565.4 2022-06-14 Buy
Product number Packaging Price Buy
753009 250MG ₹4551 Buy
753009 1G ₹12450 Buy
753009 5G ₹34565.4 Buy

SPhos Pd G2 Chemical Properties,Uses,Production

Uses

Application in Suzuki-Miyaura coupling:

  • Self-arylation of 1-alkyl-3-bromo-2-phenyl-2,1-borazaronaphthalenes to form 2,1-borazaronaphthols.
  • Suzuki–Miyaura coupling of [Ru(bpy)2]+ with 4-carboxyphenylboronic acid.
  • Suzuki–Miyaura coupling of β-borylated porphyrins with 2-iodoaniline.

General Description

SPhos Pd G2 is a second generation (G2) precatalyst in which phenethylamine based backbone of the (G1) complex is substituted with a biphenyl-based ligand. This improvement on the previous generation allows creating the active palladium species at room temperature with weak phosphate or carbonate bases. The catalyst proves remarkably adept at achieving a variety of Suzuki-Miyaura couplings among other cross-coupling reactions.

SPhos Pd G2 Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 101)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
XINXIANG RUNYU MATERIAL CO., LTD. +86-13592593621; +8613592593621 China 431 58 Inquiry
Hebei Guanlang Biotechnology Co,.LTD +86-19930503253; +8619930503252 China 5835 58 Inquiry
Shanghai Daken Advanced Materials Co.,Ltd +86-371-66670886 China 16209 58 Inquiry
ATK CHEMICAL COMPANY LIMITED +undefined-21-51877795 China 32760 60 Inquiry
career henan chemical co +86-0371-86658258 +8613203830695 China 29898 58 Inquiry
CONIER CHEM AND PHARMA LIMITED +8618523575427 China 49391 58 Inquiry
SHANGHAI T&W PHARMACEUTICAL CO., LTD. +86-021-61551413 +8618813727289 China 5738 58 Inquiry
QINGDAO KAIENSI INTERNATIONAL TRADE CO.,LTD. +86-0532-8699-9256 +8615254267723 China 1410 58 Inquiry
Shanghai UCHEM Inc. +862156762820 +86-13564624040 China 6990 58 Inquiry
Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) CHLORO(2-DICYCLOHEXYLPHOSPHINO-2',6'-DIMETHOXY-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)MIN.98%[SPHOSPALLADACYCLEGEN.2] SPhos Pd G2 2nd Generation SPhos Precatalyst Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) Chloro(2-dicyclohexylphosphino-2',6'-diMethoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl) palladiuM(II), Min. 98% [SPhos Palladacycle] SPhos Palladacycle Gen.2 SPhos Pd G2 catalyst Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / SPhos Pd G2 SPhos Pd G2 ISO 9001:2015 REACH Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl... SPhos Pd G2 / Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) chloropalladium(1+),dicyclohexyl-[2-(2,6-dimethoxyphenyl)phenyl]phosphane,2-phenylaniline RK1001022 Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) (SPhos Pd G2) Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) min. Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl) palladium(II) Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) 1375325-64-6 C38H45ClNO2PPd C26H35O2PC12H10ClNPd Buchwald Ligands&Precatalysts Buchwald Precatalysts Series Pd