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RuPhos Pd G3

RuPhos Pd G3 Structure
CAS No.
1445085-77-7
Chemical Name:
RuPhos Pd G3
Synonyms
RuPhos-Pd-G3;RuPhos Palladacycle Gen.3;Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);RuPhos Pd G3;RuPhos Pd G3 95%;RuPhos-G3-Palladacycle;RuPhos Pd G3 ISO 9001:2015 REACH;Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-...;Methanesulfonato(2-Dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II);(2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
CBNumber:
CB02686116
Molecular Formula:
C43H57NO5PPdS-
Molecular Weight:
837.375141
MOL File:
1445085-77-7.mol
MSDS File:
SDS
Modify Date:
2024/3/18 16:04:41

RuPhos Pd G3 Properties

Melting point 188-196°C (decomposition)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form Powder
color white
InChIKey GYTUQNMMIUJBSP-UHFFFAOYSA-N
CAS DataBase Reference 1445085-77-7

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335-H412
Precautionary statements  P273-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38-52/53
Safety Statements  26-61
WGK Germany  3

RuPhos Pd G3 price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 763403 RuPhos Pd G3 98% 1445085-77-7 250MG ₹7936.5 2022-06-14 Buy
Sigma-Aldrich(India) 763403 RuPhos Pd G3 98% 1445085-77-7 1G ₹26690 2022-06-14 Buy
Sigma-Aldrich(India) 763403 RuPhos Pd G3 98% 1445085-77-7 5G ₹87046.2 2022-06-14 Buy
Product number Packaging Price Buy
763403 250MG ₹7936.5 Buy
763403 1G ₹26690 Buy
763403 5G ₹87046.2 Buy

RuPhos Pd G3 Chemical Properties,Uses,Production

Uses

RuPhos Pd G3 can be used as a pre-catalyst in the following protocols:

  • Palladium-catalyzed Suzuki coupling of 5-p-toluenesulfonyltetrazoles with arylboronic acids to synthesize 1,5-disubstituted tetrazoles.
  • Suzuki-Miyaura catalyst-transfer polycondensation (SCTP) of 3-alkylthiophenes in the presence of N-methylimidodiacetic (MIDA)-boronate monomers.
  • Suzuki-Miyaura-cross-coupling of aminothiophenes.

General Description

RuPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

RuPhos Pd G3 Preparation Products And Raw materials

Global( 136)Suppliers
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Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [RuPhos Palladacycle] Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% RuPhos Pd G3 95% (2-Dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate RuPhos Pd G3 RuPhos-G3-Palladacycle Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) OMS-RuPhos [2'-(Amino)[1,1'-biphenyl]-2-yl][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine](methanesulfonato)palladium Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [RuPhos Palladacycle Gen. 3] [2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine-κP](methanesulfonato-κO)palladium Methanesulfonic acid (2-dicyclohexylphosphino-2 ', 6' - diisopropoxy-1,1 '- biphenyl) (2-amino-1,1' - biphenyl-2-yl) palladium (II) ruphos PD G3 Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / RuPhos Pd G3 Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][[2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexylphosphine-κP](methanesulfonato-κO)- RuPhos Pd G3 ISO 9001:2015 REACH Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-... RuPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (2'-Amino-2-biphenylyl)(methanesulfonato-κO)palladium - dicyclohexyl(2',6'-diisopropoxy-2-biphenylyl)phosphine (1:1) Methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) RuPhos-Pd-G3 RuPhos Palladacycle Gen.3 Methanesulfonato(2-Dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)]palladium(II) Mesylate (2 - dicyclohexyl phosphonic base - 2 ', 6 '- diisopropyl oxygen radicals - 1, 1' - al phenyl) (2 - amino - 1, 1 '- biphenyl - 2 - base) palladium (II) methanesulfonato(2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(ii) 1445085-77-7 C43H56NO5PPdS C30H43O2PC13H13NO3PdS Buchwald Ligands&Precatalysts Buchwald Precatalysts Series Pd