BrettPhos Pd G3

BrettPhos Pd G3 Structure
CAS No.
1470372-59-8
Chemical Name:
BrettPhos Pd G3
Synonyms
BuBrettPhos Pd G3;BrettPhos-G3-Pd;BrettPhos Pd G3;BrettPhos Pd G3 95%;BrettPhos Palladacycle Gen.3;BrettPhosPdG3 BrettPhos Pd G3;BrettPhos Pd G3 ISO 9001:2015 REACH;BrettPhosPalladacycle3rdGeneration,98%;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4'...;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu
CBNumber:
CB62686118
Molecular Formula:
C48H66NO5PPdS
Molecular Weight:
906.51
MOL File:
1470372-59-8.mol
MSDS File:
SDS
Modify Date:
2024/3/18 16:05:02

BrettPhos Pd G3 Properties

Melting point 150-193°C (decomposition)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form Powder
color yellow to beige
InChIKey ASZHREKEHVNFFW-UHFFFAOYSA-N
SMILES P(C1CCCCC1)(C1CCCCC1)(C1C(=CC=C(OC)C=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
WGK Germany  3
HS Code  2843909000

BrettPhos Pd G3 price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 761605 BrettPhos Pd G3 98% 1470372-59-8 250MG ₹11521.8 2022-06-14 Buy
Sigma-Aldrich(India) 761605 BrettPhos Pd G3 98% 1470372-59-8 1G ₹26300 2022-06-14 Buy
Sigma-Aldrich(India) 761605 BrettPhos Pd G3 98% 1470372-59-8 5G ₹78699 2022-06-14 Buy
Sigma-Aldrich(India) 761605 BrettPhos Pd G3 98% 1470372-59-8 10G ₹125130.3 2022-06-14 Buy
Product number Packaging Price Buy
761605 250MG ₹11521.8 Buy
761605 1G ₹26300 Buy
761605 5G ₹78699 Buy
761605 10G ₹125130.3 Buy

BrettPhos Pd G3 Chemical Properties,Uses,Production

Uses

BrettPhos Pd G3 may be used for the C-N coupling reaction between monosubstituted ureas and 1,2 dihaloaromatic system to form benzimidazolones.
It may be used in the synthesis of following compounds:

  • [Pd(cinnamyl)(BrettPhos)]OTf by reacting with [(cinnamyl)PdCl]2 and AgOTf.
  • [Pd(crotyl)(BrettPhos)]OTf by reacting with [(crotyl)PdCl]2 and AgOTf.
  • [Pd(allyl)(BrettPhos)]OTf by reacting with [(allyl)PdCl]2 and AgOTf.
  • Pd(allyl)(BrettPhos)Cl by reacting with [(allyl)PdCl]2.

General Description

BrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. BrettPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.


BrettPhos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 143)Suppliers
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CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
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Methanesulfonato2-Dicyclohexylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) BrettPhos Pd G3 95% [2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu [2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle] Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% BrettPhos Pd G3 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′- triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′ -biphenyl)]palladium(II) methanesulfonate [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-triisopropyl-1,1’- biphenyl)-2-(2’-amino-1,1’-biphenyl)]palladium(II) methanesulfonate methanesulfonate Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 3] BrettPhos Palladacycle Gen.3 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G3 Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)- BrettPhosPalladacycle3rdGeneration,98% BrettPhos Pd G3 ISO 9001:2015 REACH 2-(2-aminophenyl)phenyl]palladio methanesulfonate, dicyclohexyl({3,6-dimethoxy-2-[2,4,6-tris(propan-2-yl)phenyl]phenyl})phosphane Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4'... BrettPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) BuBrettPhos Pd G3 BrettPhos-G3-Pd BrettPhosPdG3 BrettPhos Pd G3 (2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′- triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′ -biphenyl)]palladium(II) methanesulfonate[BrettPhos Pd G3] Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) 1470372-59-8 C48H66NO5PPdS Buchwald Ligands&Precatalysts Buchwald Precatalysts Series Pd