BrettPhos Pd G4

BrettPhos Pd G4 Structure
CAS No.
1599466-83-7
Chemical Name:
BrettPhos Pd G4
Synonyms
BrettPhos Palladacycle Gen. 4;BrettPhos Pd G4;BrettPhos Pd G4c;Gingerol Impurity 5;dicyclohexyl[3,6-dimethoxy-2,4,6-tris(propan-2-yl)-[1,1-;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II);[2'-(Methylamino)-2-biphenylyl]palladium(1+) methanesulfonate-dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-2-biphenylyl)phosphine (1:1:1);Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min
CBNumber:
CB83148149
Molecular Formula:
C49H68NO5PPds
Molecular Weight:
920.53
MOL File:
1599466-83-7.mol
Modify Date:
2024/3/18 16:05:02

BrettPhos Pd G4 Properties

form Powder
color off-white to beige
InChIKey ZTBOMOZSCNBFNQ-UHFFFAOYSA-L

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H319-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
HS Code  2843909000

BrettPhos Pd G4 price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 804355 BrettPhos Pd G4 1599466-83-7 250MG ₹6549 2022-06-14 Buy
Sigma-Aldrich(India) 804355 BrettPhos Pd G4 1599466-83-7 1G ₹20845.8 2022-06-14 Buy
Product number Packaging Price Buy
804355 250MG ₹6549 Buy
804355 1G ₹20845.8 Buy

BrettPhos Pd G4 Chemical Properties,Uses,Production

General Description

BrettPhos Pd G4 is an N-substituted 2-aminobiphenylpalladium methanesulfonate precatalyst. It is a fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations of using the third generation precatalysts. It is air, moisture and thermally-stable and shows good solubility in common organic solvents. BrettPhos Pd G4 is highly useful in cross-coupling reactions. Some of its excellent features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

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Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II), min METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-METHYLAMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[BRETTPHOSPALLADACYCLEGEN.4] BrettPhos Pd G4 / Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G4 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II),[BrettPhos Palladacycle Gen. 4] dicyclohexyl[3,6-dimethoxy-2,4,6-tris(propan-2-yl)-[1,1- BrettPhos Palladacycle Gen. 4 BrettPhos Pd G4c Gingerol Impurity 5 BrettPhos Pd G4 [2'-(Methylamino)-2-biphenylyl]palladium(1+) methanesulfonate-dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-2-biphenylyl)phosphine (1:1:1) Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) 1599466-83-7 C49H68NO5PPdS Buchwald Ligands&Precatalysts Buchwald Precatalysts Series Pd