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Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Structure
CAS No.
887919-35-9
Chemical Name:
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
Synonyms
Pd132;Pd(amphos)Cl2;Pd(Amphos)2Cl2;PdCl2(Amphos)2;(A-taPhos)2PdCl2;PdAMPHOS;BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II);pall;Bis[4-[bis(1,1-diMethylethyl)phosphino-κ…;Dichlorobis[di-tert-butyl(p-dimethylaminophenyl)phosphino]palladium(II)
CBNumber:
CB8972714
Molecular Formula:
C32H58Cl2N2P2Pd
Molecular Weight:
710.1
MOL File:
887919-35-9.mol
Modify Date:
2024/1/23 10:25:42

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Properties

storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Powder
color yellow
Water Solubility Insoluble in water.
InChI InChI=1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;
InChIKey AWOFSUFKCXRJMV-UHFFFAOYSA-N
SMILES P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)(C(C)(C)C)[Pd+2]([Cl-])([Cl-])P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)C(C)(C)C

SAFETY

Risk and Safety Statements

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3
TSCA  No
HS Code  28439000
NFPA 704
1
2 0

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich(India) 678740 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) 887919-35-9 1G ₹19870 2022-06-14 Buy
Sigma-Aldrich(India) 678740 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) 887919-35-9 5G ₹45987.3 2022-06-14 Buy
Sigma-Aldrich(India) 678740 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) 887919-35-9 50G ₹303363 2022-06-14 Buy
Product number Packaging Price Buy
678740 1G ₹19870 Buy
678740 5G ₹45987.3 Buy
678740 50G ₹303363 Buy

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Chemical Properties,Uses,Production

Chemical Properties

Yellow powder

Uses

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium is useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.

Synthesis

To a 500 mL reaction was added 10 g (1,5-cyclooctadiene) palladium dichloride, the reaction flask was replaced with a nitrogen atmosphere,19.6 g of di-tert-butyl-4-dimethylaminophenylphosphine and 200 mL of anhydrous tetrahydrofuran were added. The mixture was stirred at room temperature for 16 hours; There was a solid precipitation; filtration and drying gave a pale yellow powder product bis (di-tert-butyl-4-dimethylaminophenylphosphine) palladium chloride. The yield was 97 percent.

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Preparation Products And Raw materials

Global( 309)Suppliers
Supplier Tel Country ProdList Advantage Inquiry
Omkar Lab +91-9130062553 +91-9326135973 Maharashtra, India 47 58 Inquiry
Johnson Matthey Chemicals India Pvt Ltd +91-9820622275 +91-9711869003 Maharashtra, India 69 58 Inquiry
A.J Chemicals 91-9810153283 New Delhi, India 6124 58 Inquiry
CLEARSYNTH LABS LTD. +91-22-45045900 Hyderabad, India 6351 58 Inquiry
Johnson Matthey Chemicals India Pvt., Ltd. 91-22-27415601 Ext 675 Maharashtra, India 47 58 Inquiry
Satyam Noble Metal Pvt., Ltd. 91-33-25432698 Kolkata, India 34 58 Inquiry
Grr Fine Chem/Grr Exports 91-79-40031771 Gujarat, India 405 58 Inquiry
Clearsynth Labs 91-22-45045900 Maharashtra, India 3889 58 Inquiry
Reax Chemicals 08048372701Ext 416 Hyderabad, India 4223 58 Inquiry
XINXIANG RUNYU MATERIAL CO., LTD. +86-13592593621; +8613592593621 China 431 58 Inquiry
Pd(aMphos)Cl2, 15% Pd, Product of UMicore Palladium,bis[4-[bis(1,1-dimethylethyl)phosphino-kP]-N,N-dimethylbenzenamine]dichloro-, (SP-4-1)- palladium(2+) ion bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) dichloride Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]palladiuM(II) Bis(4-(di-tert-Butylphosphanyl)-N,N-dimethylaniline) Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% Dichlorobis(di-tert-butyl-4-dimethylaminophenylphosphine)palladium(11) (SP-4-1)-Palladium dichloro-bis[4-[bis(1,1-dimethylethyl)phosphino-P]-N,N-dimethylbenzenamine] BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) PdCl2(AMphos)2 Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladiuM(II), Pd 15% Bis(di-tert-butyl(4-diMethyl Bis[(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine] palladiuM(II) chloride Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]palladiuM(II), Pd 15% Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}dichloropalladium(II), Bis{4-[bis(tert-butyl)phosphanyl]-N,N-dimethylaniline}dichloropalladium(II) Bis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]dichloropalladiuM, 95% Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride 95+% Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos Pd(amphos)Cl2 / Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) palladium(2+) io Bis[4-[bis(1,1-diMethylethyl)phosphino-Palladium,bis[4-[bis(1,1-dimethylethyl)phosphino-kP]-N,N-dimethylbenzenamine]dichloro-, (SP-4-1)- Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II) Dichlorobis[di-t-butyl(p-dimethylaminophenyl)phosphino]palladium(Ⅱ) Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) adium Bis[di-tert-butyL BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM ISO 9001:2015 REACH Bis(di-tert-butyl(4-methylaminophenyl)phosphine)dichloropalladium(II) Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphino]pa... Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride (Pd-132) TIANFU-CHEM -BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) Bis[4-[bis(1,1-diMethylethyl)phosphino-κ… BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) (A-taPhos)2PdCl2 PdCl2(Amphos)2 Pd(amphos)Cl2 Pd132 PdAMPHOS pall Pd(Amphos)2Cl2 Dichlorobis[di-tert-butyl(p-dimethylaminophenyl)phosphino]palladium(II) 4-lsopropylaniline(99-88-7) bis[4- [bis(1,1-dimethylethyl)phosphino-kP]-N,N- dimethylbenzenamine]dichloro-palladium(II) Dichlorodi-tert-butyl - (4-dimethylaminophenyl) phosphopalladium (II) Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphino]palladium(II) (AMPHOS)2PDCL2 (SP-4-1)-Bis[4-[bis(1,1-dimethylethyl)phosphino-κP]-N,N-dimethylbenzenamine]dichloropalladium (SP-4-1)-Bis[4-[bis(1,1-dimethylethyl)phosphino-κP]-N,N-dimethylbenzenamine]dichloropalladium (ACI) 887919-35-9 C32H56Cl2N2P2Pd Pd